GB961054A - Vinyl chloride resin compositions - Google Patents

Vinyl chloride resin compositions

Info

Publication number
GB961054A
GB961054A GB27675/61A GB2767561A GB961054A GB 961054 A GB961054 A GB 961054A GB 27675/61 A GB27675/61 A GB 27675/61A GB 2767561 A GB2767561 A GB 2767561A GB 961054 A GB961054 A GB 961054A
Authority
GB
United Kingdom
Prior art keywords
vinyl chloride
chlorinated
polymer
anhydride
epoxy resin
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB27675/61A
Inventor
Michael Robin Day
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Imperial Chemical Industries Ltd
Original Assignee
Imperial Chemical Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to BE620925D priority Critical patent/BE620925A/xx
Application filed by Imperial Chemical Industries Ltd filed Critical Imperial Chemical Industries Ltd
Priority to GB27675/61A priority patent/GB961054A/en
Priority to ES279637A priority patent/ES279637A1/en
Priority to FR905699A priority patent/FR1330084A/en
Publication of GB961054A publication Critical patent/GB961054A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D127/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
    • C09D127/02—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
    • C09D127/04—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C09D127/06—Homopolymers or copolymers of vinyl chloride
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
    • C08K5/0025—Crosslinking or vulcanising agents; including accelerators
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L101/00—Compositions of unspecified macromolecular compounds
    • C08L101/02—Compositions of unspecified macromolecular compounds characterised by the presence of specified groups, e.g. terminal or pendant functional groups
    • C08L101/06—Compositions of unspecified macromolecular compounds characterised by the presence of specified groups, e.g. terminal or pendant functional groups containing oxygen atoms
    • C08L101/08—Carboxyl groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08L27/06—Homopolymers or copolymers of vinyl chloride
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/22—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers modified by chemical after-treatment
    • C08L27/24—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers modified by chemical after-treatment halogenated
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Medicinal Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Laminated Bodies (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

Coating compositions comprise (a) a thermoplastic material comprising a vinyl chloride polymer containing carboxylic acid or carboxylic anhydride groups or a mixture of a major proportion of a vinyl chloride polymer together with a minor proportion of (i) a polymer containing carboxylic acid or carboxylic acid anhydride groups or (ii) an after-chlorinated vinyl chloride polymer, (b) an epoxy resin and (c) a hardener for the epoxy resin. Specified vinyl chloride polymers containing carboxyl groups are copolymers of vinyl chloride with maleic, fumaric, itaconic, aconitic, crotonic, acrylic, methacrylic and a -chloracrylic acids. The carboxyl containing polymer may be an ethylene-maleic anhydride copolymer. The after-chlorinated polymer may be chlorinated polyvinyl chloride or a chlorinated copolymer of vinyl chloride with minor proportions of vinyl acetate, ethylene, propylene, styrene, methyl methacrylate or acrylonitrile. Preferred epoxy resins are condensation products of an epihalohydrin or dihalohydrin and a polyhydric compound, preferably a diphenylol alkane such as diphenylol propane. Specified hardeners for the epoxy resins are phthalic anhydride, maleic anhydride, caustic soda, calcium oxide, sodium amide, guanidine, diphenyl guanidine, piperidine, triethanolamine, piperazine, hexamethylene tetramine, hydrazodicarbonimide, cyanamide, dicyanamide, melamine, mixtures of phthalic anhydride and diphthalyl, and polyalkylene polyamines such as triethylene tetramine, tetraethylene pentamine and pentaethylene hexamine. Amine hardeners which are also cross-linking agents for vinyl chloride polymers are preferred. The compositions may also comprise plasticizers, e.g. di-2-ethylhexyl phthalates, terephthalates and isophthalates, tricresyl phosphate, adipates and sebacates; fillers; pigments; and stabilizers; and may be used for coating metals, fabrics, glass and glass fibres, ceramics and thermoplastic films, the coatings being gelled and cured by heating. Examples describe compositions comprising polyvinyl chloride, epoxy resin, hardener and dinonyl phthalate with (1) a copolymer of vinyl chloride, vinyl acetate and maleic anhydride and (2) chlorinated polyvinyl chloride.ALSO:Substrates are coated with compositions comprising (a) a thermoplastic material comprising a vinyl chloride polymer containing carboxylic acid or carboxylic anhydride groups or a mixture of a major proportion of a vinyl chloride polymer together with a minor proportion of (i) a polymer containing carboxylic acid or carboxylic anhydride groups or (ii) an after-chlorinated vinyl chloride polymer, (b) an epoxy resin and (c) a hardener for the epoxy resin, and the coatings gelled and cross-linked by heating. The substrates are preferably metals, such as steels, iron, zinc and aluminium, but may be fabrics, glass, glass fibres, ceramics or thermoplastic films. Specified vinyl chloride polymers containing carboxyl groups are copolymers of vinyl chloride with maleic, fumaric, itaconic, aconitic, crotonic, acrylic, methacrylic and a -chloracrylic acids. The carboxylic polymer may be an ethylene-maleic anhydride copolymer. The chlorinated vinyl chloride polymer may be chlorinated polyvinyl chloride, or a chlorinated copolymer of vinyl chloride with minor proportions of vinyl acetate, ethylene, propylene, styrene, methyl acrylate, methyl methacrylate or acrylonitrile. Preferred epoxy resins are condensates of epihalohydrins or dihalohydrins with polyhydric compounds, particularly diphenylol propane. Specified hardeners are phthalic anhydride, maleic anhydride, caustic soda, calcium oxide, sodium amide, guanidine, diphenyl guanidine, piperidine, triethanolamine, piperazine, hexamethylene tetramine, hydrazodicarbonimide, cyanamide, dicyanamide, melamine, mixtures of phthalic anhydride and diphthalyl, triethylene tetramine, tetraethylene pentamine and pentaethylene hexamine. The compositions may also comprise plasticizers, e.g. di-2-ethylhexyl phthalate, terephthalate and isophthalate, dinonyl phthalate, tricresyl phosphate, adipates and sebacates; fillers; pigments and stabilizers. In examples mild steel plates shot-blasted and degreased with trichlorethylene are coated with compositions comprising polyvinyl chloride, epoxy resin, hardener, dinonyl phthalate, stabilizers, pigments and fillers and (1) a copolymer of vinyl chloride, vinyl acetate and maleic anhydride and (2) chlorinated polyvinyl chloride.
GB27675/61A 1961-07-31 1961-07-31 Vinyl chloride resin compositions Expired GB961054A (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
BE620925D BE620925A (en) 1961-07-31
GB27675/61A GB961054A (en) 1961-07-31 1961-07-31 Vinyl chloride resin compositions
ES279637A ES279637A1 (en) 1961-07-31 1962-07-30 A procedure for obtaining a composition of vinyl chloride resin (Machine-translation by Google Translate, not legally binding)
FR905699A FR1330084A (en) 1961-07-31 1962-07-31 Compositions of vinyl chloride resins

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB27675/61A GB961054A (en) 1961-07-31 1961-07-31 Vinyl chloride resin compositions

Publications (1)

Publication Number Publication Date
GB961054A true GB961054A (en) 1964-06-17

Family

ID=10263452

Family Applications (1)

Application Number Title Priority Date Filing Date
GB27675/61A Expired GB961054A (en) 1961-07-31 1961-07-31 Vinyl chloride resin compositions

Country Status (3)

Country Link
BE (1) BE620925A (en)
ES (1) ES279637A1 (en)
GB (1) GB961054A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3466347A (en) * 1966-02-23 1969-09-09 Mobil Oil Corp Coating compositions comprising dispersion grade vinyl resin,solution grade vinyl resin,carboxyl containing acrylic resin and epoxidized novolac resin for adherently coating metal
US3988493A (en) * 1975-01-23 1976-10-26 E. I. Du Pont De Nemours And Company Polymer powder coating composition

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3466347A (en) * 1966-02-23 1969-09-09 Mobil Oil Corp Coating compositions comprising dispersion grade vinyl resin,solution grade vinyl resin,carboxyl containing acrylic resin and epoxidized novolac resin for adherently coating metal
US3988493A (en) * 1975-01-23 1976-10-26 E. I. Du Pont De Nemours And Company Polymer powder coating composition

Also Published As

Publication number Publication date
BE620925A (en) 1900-01-01
ES279637A1 (en) 1963-01-16

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