GB963604A - Vinyl coating compositions - Google Patents

Vinyl coating compositions

Info

Publication number
GB963604A
GB963604A GB28/62A GB2862A GB963604A GB 963604 A GB963604 A GB 963604A GB 28/62 A GB28/62 A GB 28/62A GB 2862 A GB2862 A GB 2862A GB 963604 A GB963604 A GB 963604A
Authority
GB
United Kingdom
Prior art keywords
polymer
vinyl chloride
compositions
copolymer
maleic anhydride
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB28/62A
Inventor
John Norman Shearwood Davis
Michael Robin Day
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Imperial Chemical Industries Ltd
Original Assignee
Imperial Chemical Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to NL287266D priority Critical patent/NL287266A/xx
Priority to BE626717D priority patent/BE626717A/xx
Application filed by Imperial Chemical Industries Ltd filed Critical Imperial Chemical Industries Ltd
Priority to GB28/62A priority patent/GB963604A/en
Priority to FR920089A priority patent/FR1351589A/en
Priority to DK565762AA priority patent/DK106191C/en
Priority to ES283824A priority patent/ES283824A1/en
Publication of GB963604A publication Critical patent/GB963604A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F259/00—Macromolecular compounds obtained by polymerising monomers on to polymers of halogen containing monomers as defined in group C08F14/00
    • C08F259/02—Macromolecular compounds obtained by polymerising monomers on to polymers of halogen containing monomers as defined in group C08F14/00 on to polymers containing chlorine
    • C08F259/04—Macromolecular compounds obtained by polymerising monomers on to polymers of halogen containing monomers as defined in group C08F14/00 on to polymers containing chlorine on to polymers of vinyl chloride
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
    • C08K5/0025—Crosslinking or vulcanising agents; including accelerators
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/10—Esters; Ether-esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08L27/06—Homopolymers or copolymers of vinyl chloride
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/22—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers modified by chemical after-treatment
    • C08L27/24—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers modified by chemical after-treatment halogenated
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D127/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
    • C09D127/02—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
    • C09D127/04—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C09D127/06—Homopolymers or copolymers of vinyl chloride
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Paints Or Removers (AREA)

Abstract

Compositions comprising a thermoplastic paste-forming polymer of vinyl chloride, an epoxy resin, a hardener for the epoxy resin and a monoethylenically unsaturated ester or partial polymer thereof are characterised by the presence of a polymeric material containing free carboxylic acid or carboxylic acid anhydride groups. The compositions preferably contain an after-chlorinated polyvinyl chloride. Preferred epoxy resins are halogen-free condensation products of an epihalogenhydrin or dihalogen hydrin and a polyhydric compound, particularly a polyhydric phenol, e.g. condensation products of epichlorhydrin or dichlorhydrin with diphenylolpropane; and epoxidised linseed oil. Specified hardeners are phthalic anhydride, maleic anhydride and Diels-Alder adducts thereof, caustic soda, calcium oxide, sodium amide, guanidine, diphenyl guanidine, piperidine, triethanolamine, piperazine, hexamethylene tetramine, hydrazodicarbonimide, cyanamide, dicyanamide, melamine, and agents which are also cross-linking agents for the vinyl chloride polymer, e.g. triethylene tetramine, tetraethylene pentamine, pentaethylene hexamine and N-(2-hydroxypropyl)-triethylene tetramine. The unsaturated ester may be an ester of acrylic or methacrylic acid with butanol, pentanols, hexanols, heptanols, octanols or nonanols, or esters of 1-vinyl cyclohexane-3, 4-diol. The carboxyl containing polymer may be a polymer of acrylic, methacrylic, b -chloracrylic, maleic, fumaric, itaconic, aconitic or crotanic acid, maleic anhydride or a partial ester of a polycarboxylic acid, e.g. monoethyl maleate, or copolymer thereof, e.g. with ethylene, styrene or with vinyl chloride when the acidic polymer may function as paste-forming polymer. The after-chlorinated polymer may be polyvinyl chloride or a copolymer of vinyl chloride with vinyl acetate, methyl methacrylate, styrene, acrylonitrile, methyl acrylate, ethylene or propylene. The compositions may comprise conventional plasticisers, e.g. dioctyl phthalates, terephthalates or isophthalates, tricresyl phosphates, adipates and sebacates; diluents, e.g. white spirit, xylene or hydroxyethyl butyl ether; and fillers, pigments and stabilizers. The compositions may be used for coating metals, fabrics, glass fibres, ceramics and thermoplastic films, for bonding metals and for floor-coverings. An example describes a composition comprising a vinyl chloride polymer, a copolymer of vinyl chloride, vinyl acetate and maleic anhydride, the diglycidyl ether of diphenylol propane, N-(2-hydroxy-propyl)-triethylene tetramine, 2-ethyl hexyl acrylate, dinonyl phthalate, an organotin stabilizer and white spirit. The acrylate may be replaced by butyl methacrylate or undecyl acrylate, and the glycidyl ether by epoxidised linseed oil.ALSO:Substrates, e.g. of metal, glass or ceramic, may be coated with compositions comprising a thermoplastic paste-forming polymer of vinyl chloride, an epoxy resin, a hardener for the epoxy resin and a monoethylenically unsaturated ester or partial polymer thereof and characterized by the presence of a polymeric material containing free carboxylic acid or carboxylic acid anhydride groups. Specified metal substrates are iron, steel, zinc and aluminium, and the compositions may be applied by spraying, painting, doctor knife coating, roller coating, centrifugal casting or curtain coating. Specified epoxy resins are condensates of epichlorhydrin and diphenylolpropane, and epoxidized linseed oil. Specified hardeners are dicarboxylic acid anhydrides, organic and inorganic bases, hydrazodicarbonimide, cyanamide, dicyanamide melamine and agents which are also crosslinking agents for the vinyl chloride polymer, e.g. polyalkylene polyamines. The unsaturated ester may be an acrylic or methacrylic ester of C4-9 alkanols, or an ester of 1-vinyl cyclohexane-3,4-diol. The carboxyl containing polymer may be an ethylene-maleic anhydride copolymer, styrene-maleic anhydride copolymer, vinyl chloride-vinyl acetate-maleic anhydride terpolymer or polyacrylic acid. The compositions may also contain an after-chlorinated polyvinyl chloride or copolymer of vinyl chloride with vinyl acetate, styrene, ethylene, propylene, methyl acrylate, methyl methacrylate or acrylonitrile; plasticizers, e.g. dioctyl phthalates, tricresyl phosphate, adipates and sebacates; diluents, e.g. white spirit, xylene and hydroxyethyl butyl ether; fillers; pigments and stabilizers. An example describes the coating of shot-blasted mild steel with a composition comprising a vinyl chloride polymer, a copolymer of vinyl chloride, vinyl acetate and maleic anhydride, the diglycidyl ether of diphenylolpropane, N-(2-hydroxypropyl)-triethylene tetramine, 2-ethyl hexyl acrylate, dinonyl phthalate, an organo tin stabilizer and white spirit, and the curing of the coating at elevated temperature. Similar coatings are obtained when the acrylate is replaced by butyl methacrylate or undecyl acrylate, and the glycidyl ether by epoxidized linseed oil.
GB28/62A 1962-01-01 1962-01-01 Vinyl coating compositions Expired GB963604A (en)

Priority Applications (6)

Application Number Priority Date Filing Date Title
NL287266D NL287266A (en) 1962-01-01
BE626717D BE626717A (en) 1962-01-01
GB28/62A GB963604A (en) 1962-01-01 1962-01-01 Vinyl coating compositions
FR920089A FR1351589A (en) 1962-01-01 1962-12-28 Vinyl coating compositions
DK565762AA DK106191C (en) 1962-01-01 1962-12-28 Vinyl chloride coating material.
ES283824A ES283824A1 (en) 1962-01-01 1962-12-31 Procedure for obtaining thermoplastic compositions (Machine-translation by Google Translate, not legally binding)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB28/62A GB963604A (en) 1962-01-01 1962-01-01 Vinyl coating compositions

Publications (1)

Publication Number Publication Date
GB963604A true GB963604A (en) 1964-07-15

Family

ID=9697095

Family Applications (1)

Application Number Title Priority Date Filing Date
GB28/62A Expired GB963604A (en) 1962-01-01 1962-01-01 Vinyl coating compositions

Country Status (6)

Country Link
BE (1) BE626717A (en)
DK (1) DK106191C (en)
ES (1) ES283824A1 (en)
FR (1) FR1351589A (en)
GB (1) GB963604A (en)
NL (1) NL287266A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2825594A4 (en) * 2012-04-24 2016-03-23 Dow Global Technologies Llc Epoxy resin composition for marine maintenance and repair coatings with improved overcoatability

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2825594A4 (en) * 2012-04-24 2016-03-23 Dow Global Technologies Llc Epoxy resin composition for marine maintenance and repair coatings with improved overcoatability

Also Published As

Publication number Publication date
NL287266A (en) 1900-01-01
DK106191C (en) 1967-01-02
FR1351589A (en) 1964-02-07
BE626717A (en) 1900-01-01
ES283824A1 (en) 1963-03-01

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