GB897726A - A process for the manufacture of hardened artificial resin materials and compositions therefor - Google Patents
A process for the manufacture of hardened artificial resin materials and compositions thereforInfo
- Publication number
- GB897726A GB897726A GB27256/58A GB2725658A GB897726A GB 897726 A GB897726 A GB 897726A GB 27256/58 A GB27256/58 A GB 27256/58A GB 2725658 A GB2725658 A GB 2725658A GB 897726 A GB897726 A GB 897726A
- Authority
- GB
- United Kingdom
- Prior art keywords
- acrylamide
- acid
- copolymerization
- cyclohexyl
- butyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
- C08F20/62—Monocarboxylic acids having ten or more carbon atoms; Derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L57/00—Compositions of unspecified polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2363/00—Characterised by the use of epoxy resins; Derivatives of epoxy resins
Abstract
A hardenable composition comprises an epoxy resin which is substantially free from carboxyl groups and contains n epoxide groups calculated on the molecular weight, where n represents a whole or fractional number greater than 1, and a copolymerization product obtained by polymerizing at least one compound containing at least one polymerizable carbon-to-carbon double bond and at least one tertiary amino group of the formula -NR1R2 in which R1 and R2 each represent a hydrocarbon radical of 1 to 6 carbon atoms which may be substituted or may be linked together to form with the nitrogen atom a heterocyclic ring, jointly with at least one non-basic amide of a copolymerizable acid, and the content of the component containing a tertiary amino group in the copolymerization product being less than 40% by weight. As materials containing basic tertiary amino groups there are suitable such compounds as are specified for the copolymer curing agents of Specification 897,985. As copolymerizable non-basic amides there are specified amides of acryl, methacrylic fumaric and crotonic acids, e.g. N-methyl ethyl butyl ter. octyl- and cyclohexyl acrylamides, N,N-dimethyl or dibutyl acrylamides or methacrylamides, N;N-di(b -hydroxyethyl)acrylamide, N-cyclohexyl-N-2-hydroxypropylacrylamide and hexamethylolmelamine triacrylic acid amide. The copolymers may also contain a third copolymerization component such as a vinyl ester, vinyl halide, vinyl alkyl ketone, vinylaryl compound, esters of acrylic acid, methacrylic, a -chloracrylic, crotonic, itaconic, maleic or fumaric acids, acrylic acid itself or polymerizable olefins. The copolymers may be used together with such compounds as triethylene tetramine, N:N-diethylpropylene diamine, tris-(dimethylaminomethyl)phenol, 4,41-diaminodiphenylmethane, phthalic, tetrahydrophthalic or hexahydrophthalic anhydride, methylendomethylenetetrahydrophthalic anhydride or hexachloroendomethylene-tetrahydrophthalic anhydride. As modifiers there can be added to the compositions epoxy-dodecane, hexadecane or octadecane or epoxidized fatty acids or fatty acid esters. Plasticizers such as dibutyl phthalate and extenders such as quartz powder, kaolin, stone powder, glass or asbestos fibres may be added. For use in treating leather, paper or textiles the compositions may be used in the form of an emulsion, for example, with hydrolyzed PVA, propylene glycol alginate and a nonyl-phenol/ethylene oxide reaction product. In the examples the copolymerization products obtained from (1) N-diethylaminopropylacrylamide, N-tertiary butyl acrylamide and ethyl acrylate; (2) N-tert.-octylacrylamide and N-diethylaminophenyl acrylamide; (3) N-dimethylaminoethyl vinyl ether; (4) N-diethylaminoethyl crotonate, butyl methacrylate and di-butyl acrylamide; (5) N-diethylaminopropyl acrylamide, N-cyclohexyl-N-(2-hydroxypropyl)-acrylamide, and isobutyl acrylate; (6) diethylaminopropyl acrylamide and hexamethylolmelamine triacrylic acid amide. Epoxy resins employed are the polyglycidyl ethers of 4,41-dihydroxydiphenyl dimethyl methane, ethylene glycol, butylene glycol; reaction products of epichlorhydrin with terephthalic acid, a phenolformaldehyde novolak or aniline. Specification 816,630 also is referred to.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CH4975557 | 1957-08-23 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB897726A true GB897726A (en) | 1962-05-30 |
Family
ID=4516795
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB27256/58A Expired GB897726A (en) | 1957-08-23 | 1958-08-25 | A process for the manufacture of hardened artificial resin materials and compositions therefor |
GB27255/58A Expired GB897985A (en) | 1957-08-23 | 1958-08-25 | A process for the manufacture of hardened artificial resin materials and compositions therefor |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB27255/58A Expired GB897985A (en) | 1957-08-23 | 1958-08-25 | A process for the manufacture of hardened artificial resin materials and compositions therefor |
Country Status (6)
Country | Link |
---|---|
BE (2) | BE570570A (en) |
CH (1) | CH49755A (en) |
DE (2) | DE1085667B (en) |
FR (2) | FR1211575A (en) |
GB (2) | GB897726A (en) |
NL (5) | NL6408445A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3385809A (en) * | 1965-09-03 | 1968-05-28 | Richardson Co | Fat acid amides of nu, nu-dialkyl (alkylene diamines) as curing agents for epoxy resi |
US3538185A (en) * | 1967-08-10 | 1970-11-03 | Dow Chemical Co | Coating compositions containing vinyl polymers with pendant alkylenimine group and epoxy resins |
Families Citing this family (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1120133B (en) * | 1959-01-23 | 1961-12-21 | Ciba Geigy | Process for accelerating the hardening of polyepoxy compounds by means of anhydride polybasic carboxylic acids |
US3467611A (en) * | 1966-01-07 | 1969-09-16 | Du Pont | Mixture of aqueous emulsions |
JPS5428960B1 (en) * | 1968-01-22 | 1979-09-20 | ||
GB1555781A (en) * | 1975-08-27 | 1979-11-14 | Pollution Preventing Res | Methods for producing dibasic fatty acid |
CA1086445A (en) * | 1976-02-23 | 1980-09-23 | Changkiu K. Riew | Thermoplastic, thermosetting elastomeric compositions and methods for making the same |
US4889890A (en) * | 1987-12-30 | 1989-12-26 | Ppg Industries, Inc. | Powder coating curing system containing a beta-hydroxyalkylamide |
US5013791A (en) * | 1987-12-30 | 1991-05-07 | Ppg Industries, Inc. | Beta-hydroxyalkylamide cured acid polymer/polyepoxide powder coating |
EP3118234A1 (en) | 2015-07-15 | 2017-01-18 | ALLNEX AUSTRIA GmbH | Coating compositions |
-
0
- NL NL110443D patent/NL110443C/xx active
- NL NL110442D patent/NL110442C/xx active
- BE BE570571D patent/BE570571A/xx unknown
- BE BE570570D patent/BE570570A/xx unknown
- NL NL230770D patent/NL230770A/xx unknown
-
1909
- 1909-10-25 CH CH49755A patent/CH49755A/en unknown
-
1958
- 1958-08-21 FR FR1211575D patent/FR1211575A/en not_active Expired
- 1958-08-21 FR FR1211576D patent/FR1211576A/en not_active Expired
- 1958-08-22 DE DEC17390A patent/DE1085667B/en active Pending
- 1958-08-22 DE DEC17391A patent/DE1106492B/en active Pending
- 1958-08-25 GB GB27256/58A patent/GB897726A/en not_active Expired
- 1958-08-25 GB GB27255/58A patent/GB897985A/en not_active Expired
-
1964
- 1964-07-23 NL NL6408445A patent/NL6408445A/xx unknown
- 1964-07-23 NL NL6408449A patent/NL6408449A/xx unknown
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3385809A (en) * | 1965-09-03 | 1968-05-28 | Richardson Co | Fat acid amides of nu, nu-dialkyl (alkylene diamines) as curing agents for epoxy resi |
US3538185A (en) * | 1967-08-10 | 1970-11-03 | Dow Chemical Co | Coating compositions containing vinyl polymers with pendant alkylenimine group and epoxy resins |
Also Published As
Publication number | Publication date |
---|---|
NL6408449A (en) | 1964-10-12 |
NL230770A (en) | |
BE570570A (en) | |
FR1211576A (en) | 1960-03-17 |
DE1106492B (en) | 1961-05-10 |
FR1211575A (en) | 1960-03-17 |
NL6408445A (en) | 1964-10-12 |
NL110442C (en) | |
CH49755A (en) | 1911-03-16 |
BE570571A (en) | |
NL110443C (en) | |
DE1085667B (en) | 1960-07-21 |
GB897985A (en) | 1962-06-06 |
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