GB960661A - Process for production of organic dibasic acid anhydrides by catalytic oxidation andcatalysts for use in such a process - Google Patents

Process for production of organic dibasic acid anhydrides by catalytic oxidation andcatalysts for use in such a process

Info

Publication number
GB960661A
GB960661A GB589862A GB589862A GB960661A GB 960661 A GB960661 A GB 960661A GB 589862 A GB589862 A GB 589862A GB 589862 A GB589862 A GB 589862A GB 960661 A GB960661 A GB 960661A
Authority
GB
United Kingdom
Prior art keywords
mols
oxidation
catalyst
preparation
maleic anhydride
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB589862A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Societe dElectro Chimie dElectro Metallurgie et des Acieries Electriques Dugine SA SECEMAU
Original Assignee
Societe dElectro Chimie dElectro Metallurgie et des Acieries Electriques Dugine SA SECEMAU
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from FR855696A external-priority patent/FR1291659A/en
Priority claimed from FR881772A external-priority patent/FR80783E/en
Application filed by Societe dElectro Chimie dElectro Metallurgie et des Acieries Electriques Dugine SA SECEMAU filed Critical Societe dElectro Chimie dElectro Metallurgie et des Acieries Electriques Dugine SA SECEMAU
Publication of GB960661A publication Critical patent/GB960661A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/31—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation of cyclic compounds with ring-splitting
    • C07C51/313—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation of cyclic compounds with ring-splitting with molecular oxygen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
    • C07C51/252—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring of propene, butenes, acrolein or methacrolein
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/255—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of compounds containing six-membered aromatic rings without ring-splitting
    • C07C51/265—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of compounds containing six-membered aromatic rings without ring-splitting having alkyl side chains which are oxidised to carboxyl groups

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Furan Compounds (AREA)

Abstract

A process for the preparation of anhydrides of dicarboxylic acids comprises the oxidation of unsaturated hydrocarbons containing at least 4 carbon atoms, e.g. preparation of maleic anhydride by the oxidation of an unsaturated hydrocarbon having at least 4 carbon atoms or of an aromatic hydrocarbon or preparation of phthalic anhydride by oxidation of an alkyl benzene or a naphthalene hydrocarbon, in a gaseous phase in a medium containing molar oxygen, between 300-650 DEG C. in the presence of an oxidising catalyst having the formula P2O5x.V2O5y. Ni3PO4z where x=0.2 and 2 mols, y=0.5 and 1.1 mols and z=0.002 and 0.2 mols. Examples describe the catalytic oxidation of butene and butadiene to maleic anhydride and acetic acid, benzene to maleic anhydride, and naphthalene and o-xylene to phthalic anhydride.ALSO:Oxidation catalysts are prepared by adding H3PO4 to finely powdered V2O5 and Li3PO4 to form a paste of putty consistency, allowing the paste to set and drying at 120-150 DEG C. for 1-3 hours. Thereafter the catalyst may be roasted between 750 and 1100 DEG C. The catalyst may have the formula P2O5x, V2O5y, Li3PO4z where x=0,2-2 mols., y=0,5-1,1 mols. and z=0,002-0,2 mols. The catalyst may be used in a fluidized bed.
GB589862A 1961-03-15 1962-02-15 Process for production of organic dibasic acid anhydrides by catalytic oxidation andcatalysts for use in such a process Expired GB960661A (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
FR855696A FR1291659A (en) 1961-03-15 1961-03-15 Process for the manufacture of maleic anhydride by catalytic oxidation
FR872092 1961-09-01
FR881772A FR80783E (en) 1961-12-13 1961-12-13 Process for the manufacture of maleic anhydride by catalytic oxidation

Publications (1)

Publication Number Publication Date
GB960661A true GB960661A (en) 1964-06-10

Family

ID=27245910

Family Applications (1)

Application Number Title Priority Date Filing Date
GB589862A Expired GB960661A (en) 1961-03-15 1962-02-15 Process for production of organic dibasic acid anhydrides by catalytic oxidation andcatalysts for use in such a process

Country Status (2)

Country Link
DE (1) DE1302116B (en)
GB (1) GB960661A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2453677A1 (en) * 1973-12-10 1975-06-12 Standard Oil Co Ohio METHOD FOR PRODUCING MALEIC ACID ANHYDRIDE
GB2145010A (en) * 1983-08-17 1985-03-20 Lummus Crest Inc Improvements in or relating to catalysts containing mixed oxides of vanadium and phosphorus

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE791294A (en) * 1972-01-03 1973-05-14 Chem Systems BUTANE OXIDATION PROCESS TO FORM MALEIC ANHYDRIDE

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2453677A1 (en) * 1973-12-10 1975-06-12 Standard Oil Co Ohio METHOD FOR PRODUCING MALEIC ACID ANHYDRIDE
GB2145010A (en) * 1983-08-17 1985-03-20 Lummus Crest Inc Improvements in or relating to catalysts containing mixed oxides of vanadium and phosphorus

Also Published As

Publication number Publication date
DE1302116B (en) 1970-01-15

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