GB942947A - Improvements in or relating to petrol-resistant coating compositions - Google Patents

Improvements in or relating to petrol-resistant coating compositions

Info

Publication number
GB942947A
GB942947A GB5135/60A GB513560A GB942947A GB 942947 A GB942947 A GB 942947A GB 5135/60 A GB5135/60 A GB 5135/60A GB 513560 A GB513560 A GB 513560A GB 942947 A GB942947 A GB 942947A
Authority
GB
United Kingdom
Prior art keywords
ethyl acrylate
hydrogen atom
terpolymer
replaced
methyl methacrylate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB5135/60A
Inventor
John Edwin Oakley Mayne
Warson Geoffrey Ernest J Henry
Arthur Frederick Moyles
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Celanese Emulsions Ltd
Original Assignee
Vinyl Products Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Vinyl Products Ltd filed Critical Vinyl Products Ltd
Priority to GB5135/60A priority Critical patent/GB942947A/en
Publication of GB942947A publication Critical patent/GB942947A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04—Homopolymers or copolymers of esters
    • C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C09D133/10—Homopolymers or copolymers of methacrylic acid esters
    • C09D133/12—Homopolymers or copolymers of methyl methacrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C08F220/1802—C2-(meth)acrylate, e.g. ethyl (meth)acrylate

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

A liquid surface-coating composition comprises a solution of a terpolymer of methyl methacrylate with from 8 to 40% of ethyl acrylate and from 0.2 to 5% of an unsaturated acid, or anhydride thereof, of the formula RCX=CY.COOH wherein R represents a hydrogen atom or a methyl group, X represents a hydrogen atom or a carboxyl group and Y represents a hydrogen atom of the group CH2. COOH, the percentages being calculated on the weight of the final terpolymer. In a modification of the composition the ethyl acrylate is replaced wholly or in part by a percentage H of another acrylic ester of an aliphatic or alkoxyaliphatic monohydric alcohol containing up to 10 carbon atoms and having a maximum chain length of 6 carbon, or carbon and oxygen, atoms, calculated from the formula <FORM:0942947/C3/1> in which A is the percentage of ethyl acrylate to be replaced and M is the molecular weight of the alcohol of the replacement ester. In the terpolymer, up to 10% by weight of the methyl methacrylate may be replaced by an equal amount of a monomer such as styrene, acrylonitrile or ethyl methacrylate. The compositions are obtained by polymerising the monomers in solution in toluene in the presence of benzoyl peroxide as a catalyst. Half the quantity of catalyst is used initially, and the remainder half way through the reaction time. Specified copolymers are those of methyl methacrylate and ethyl acrylate with acrylic acid, itaconic acid and maleic anhydride.
GB5135/60A 1960-02-12 1960-02-12 Improvements in or relating to petrol-resistant coating compositions Expired GB942947A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB5135/60A GB942947A (en) 1960-02-12 1960-02-12 Improvements in or relating to petrol-resistant coating compositions

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB5135/60A GB942947A (en) 1960-02-12 1960-02-12 Improvements in or relating to petrol-resistant coating compositions

Publications (1)

Publication Number Publication Date
GB942947A true GB942947A (en) 1963-11-27

Family

ID=9790367

Family Applications (1)

Application Number Title Priority Date Filing Date
GB5135/60A Expired GB942947A (en) 1960-02-12 1960-02-12 Improvements in or relating to petrol-resistant coating compositions

Country Status (1)

Country Link
GB (1) GB942947A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4559162A (en) * 1981-03-10 1985-12-17 Ciba-Geigy Corporation Compositions of polymers based on acrylic acid, solvents, surfactants and, if appropriate, silicone oils, their preparation and their use as anti-foams and deaerating agents
CN117659255A (en) * 2023-12-11 2024-03-08 英德市捷成化工有限公司 Water-based acrylic resin for printing ink and preparation method thereof

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4559162A (en) * 1981-03-10 1985-12-17 Ciba-Geigy Corporation Compositions of polymers based on acrylic acid, solvents, surfactants and, if appropriate, silicone oils, their preparation and their use as anti-foams and deaerating agents
CN117659255A (en) * 2023-12-11 2024-03-08 英德市捷成化工有限公司 Water-based acrylic resin for printing ink and preparation method thereof
CN117659255B (en) * 2023-12-11 2024-05-31 英德市捷成化工有限公司 Water-based acrylic resin for printing ink and preparation method thereof

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