GB942931A - Photographic silver halide emulsions of increased sensitivity - Google Patents
Photographic silver halide emulsions of increased sensitivityInfo
- Publication number
- GB942931A GB942931A GB42124/59A GB4212459A GB942931A GB 942931 A GB942931 A GB 942931A GB 42124/59 A GB42124/59 A GB 42124/59A GB 4212459 A GB4212459 A GB 4212459A GB 942931 A GB942931 A GB 942931A
- Authority
- GB
- United Kingdom
- Prior art keywords
- groups
- alkylmercapto
- ethylmercapto
- acid
- bis
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/005—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein
- G03C1/04—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein with macromolecular additives; with layer-forming substances
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/68—Polyesters containing atoms other than carbon, hydrogen and oxygen
- C08G63/688—Polyesters containing atoms other than carbon, hydrogen and oxygen containing sulfur
- C08G63/6884—Polyesters containing atoms other than carbon, hydrogen and oxygen containing sulfur derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/6886—Dicarboxylic acids and dihydroxy compounds
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/005—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein
- G03C1/04—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein with macromolecular additives; with layer-forming substances
- G03C1/043—Polyalkylene oxides; Polyalkylene sulfides; Polyalkylene selenides; Polyalkylene tellurides
Landscapes
- Chemical & Material Sciences (AREA)
- Physics & Mathematics (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- General Physics & Mathematics (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polyesters Or Polycarbonates (AREA)
Abstract
Linear polyesters containing alkylmercapto groups as substituents attached to the linear chain and having a molecular weight of at least 350 are derived from glycols and dicarboxylic acids, anhydrides, esters or acid halides, at least one of the reactants containing an alkymercapto substituent. The polyesters may comprise units of either formula I or II: <FORM:0942931/C2/1> wherein R is an alkyl group, R1, R2 and R3 ar alkylene groups or alkylene groups interrupted by single sulphur or oxygen atoms, m is 0 or 1 and p is 1, 2 or 3, at least one of R2 and R3 in formula II containing an alkylmercapto substituent. Examples are given of the reaction of ethylene glycol with methylmercapto-succinic acid, a , a 1-bis (ethylmercapto) apidic acid or a , a 1-bis(ethylmercapto) sebacic acid, and of succinic anhydride with 1, 2-dihydroxy-3-ethylmercapto-propane or the corresponding 3-butylmercapto or 3-hexylmercapto compound, or with 1,10-dihydroxy-2, 9-bis(ethylmercapto) decane. These reactions are carried out by fusing the reactants together and passing dry nitrogen through the melt. Reference also is made to the use of ethylene glycol, propylene glycol, 1, 2-propylene glycol, butylene glycol or hexamethylene glycol with dicarboxylic acids containing one or more alkylmercapto groups, such as those referred to above, and of the use of oxalic, succinic, glutaric, 2; 2-dimethyl-glutaric, adipic, pimelic or sebacic acids or their anhydrides, esters or acid halides, with glycols containing one or more alkylmercapto groups, such as those referred to above. The polyesters may have some or all of their thioether groups converted to ternary sulphonium salt groups by reaction with dimethyl sulphate, diethyl sulphate, methyl benzene sulphonate, or methyl p-toluene sulphonate. Specifications 235,211, 541,589, 636,140, 719,920, 791,219, 942,932, 942,935 and U.S.A. Specification 2,948,614 are referred to.ALSO:Linear polyesters containing alkylmercapto groups as substituents attached to the linear chain and having a molecular weight of at least 350 are derived from glycols and dicarboxylic acids, anhydrides, esters or acid halides, at least one of the reactants containing an alkylmercapto substituent. The polyesters may comprise units of either formula I or II: <FORM:0942931/C3/1> <FORM:0942931/C3/2> wherein R is an alkyl group, R1, R2 and R3 are alkylene groups or alkylene groups interrupted by single sulphur or oxygen atoms, m is 0 or 1 and p is 1, 2, or 3, at least one of R2 and R3 in formula II containing an alkylmercapto substituent. Examples are given of the reaction of ethylene glycol with methylmercapto -succinic acid, a , a 1- bis (ethylmercapto) adipic acid or a , a 1- bis (ethylmercapto) sebacic acid, and of succinic anhydride with 1, 2-dihydroxy-3-ethylmercaptopropane or the corresponding 3-butylmercapto or 3-hexylmercapto compound, or with 1,10-dihydroxy -2,9-bis (ethylmercapto) decane. These reactions are carried out by fusing the reactants together and passing dry nitrogen through the melt. Reference also is made to the use of ethylene glycol, propylene glycol, 1,2-propylene glycol, butylene glycol or hexamethylene glycol with dicarboxylic acids containing one or more alkylmercapto groups, such as those referred to above, and of the use of oxalic, succinic, glutaric, 2;2-dimethyl-glutaric, adipic, pimetic or sebacic acids or their anhydrides, esters or acid halides, with glycols containing one or more alkylmercapto groups, such as those referred to above. The polyesters may have some or all of their thioether groups converted to ternary sulphonium salt groups by reaction with dimethyl sulphate, diethyl sulphate, methyl benzene sulphonate, or methyl p-toluene sulphonate. Specifications 235,211, 541,589, 636,140, 719,920, 791,219, 942,932, 942,935 and U.S.A. Specification 2,948,614 are referred to.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US779852A US3046133A (en) | 1958-12-12 | 1958-12-12 | Sensitization of photographic silver halide emulsions with polyester compounds containing thioether-sulfur atoms in the side chain |
Publications (1)
Publication Number | Publication Date |
---|---|
GB942931A true GB942931A (en) | 1963-11-27 |
Family
ID=25117774
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB42124/59A Expired GB942931A (en) | 1958-12-12 | 1959-12-11 | Photographic silver halide emulsions of increased sensitivity |
Country Status (2)
Country | Link |
---|---|
US (1) | US3046133A (en) |
GB (1) | GB942931A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0005200A2 (en) * | 1978-04-27 | 1979-11-14 | Agfa-Gevaert AG | Silver halide photographic material and method of preparation |
Families Citing this family (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3536677A (en) * | 1968-01-29 | 1970-10-27 | Eastman Kodak Co | Polythiaalkyl acrylates and acrylamides and copolymers containing same |
GB1455413A (en) * | 1972-12-07 | 1976-11-10 | Agfa Gevaert | Development of photographic silver halide elements |
DE2748430A1 (en) * | 1977-10-28 | 1979-05-03 | Agfa Gevaert Ag | PHOTOGRAPHIC BLEACHING COMPOSITIONS WITH BLADE ACCELERATING COMPOUNDS |
JPS59188641A (en) | 1983-04-11 | 1984-10-26 | Fuji Photo Film Co Ltd | Silver halide photographic emulsion |
FR2682498A1 (en) * | 1991-10-15 | 1993-04-16 | Kodak Pathe | Colouring agents containing thioether macrocycles |
US5468588A (en) | 1994-10-18 | 1995-11-21 | Minnesota Mining And Manufacturing Company | Process for manufacturing diffusion transfer printing plates |
JPH08190199A (en) | 1994-10-18 | 1996-07-23 | Minnesota Mining & Mfg Co <3M> | Photosensitive element |
GB9423266D0 (en) * | 1994-11-18 | 1995-01-11 | Minnesota Mining & Mfg | Chemical sensitisation of silver halide emulsions |
US5691130A (en) * | 1995-11-28 | 1997-11-25 | Eastman Kodak Company | Color recording photographic elements exhibiting an increased density range, sensitivity and contrast |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
BE347196A (en) * | 1927-01-07 | |||
US2176074A (en) * | 1936-08-12 | 1939-10-17 | Du Pont | Polyamides |
NL55385C (en) * | 1940-06-14 | 1900-01-01 | ||
US2813086A (en) * | 1954-05-04 | 1957-11-12 | Hooker Electrochemical Co | Sulfur-containing crosslinked polyester elastomers |
DE1048476B (en) * | 1955-12-01 |
-
1958
- 1958-12-12 US US779852A patent/US3046133A/en not_active Expired - Lifetime
-
1959
- 1959-12-11 GB GB42124/59A patent/GB942931A/en not_active Expired
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0005200A2 (en) * | 1978-04-27 | 1979-11-14 | Agfa-Gevaert AG | Silver halide photographic material and method of preparation |
EP0005200A3 (en) * | 1978-04-27 | 1979-12-12 | Agfa-Gevaert Aktiengesellschaft | Silver halide photographic material and method of preparation |
Also Published As
Publication number | Publication date |
---|---|
US3046133A (en) | 1962-07-24 |
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