GB940272A - Aminoplast compositions for the treatment of textile materials, the textile materials obtained and the process for the treatment thereof - Google Patents

Aminoplast compositions for the treatment of textile materials, the textile materials obtained and the process for the treatment thereof

Info

Publication number
GB940272A
GB940272A GB4574/60A GB457460A GB940272A GB 940272 A GB940272 A GB 940272A GB 4574/60 A GB4574/60 A GB 4574/60A GB 457460 A GB457460 A GB 457460A GB 940272 A GB940272 A GB 940272A
Authority
GB
United Kingdom
Prior art keywords
oxetane
methyl
aminoplast
composition
treatment
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB4574/60A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Rohm and Haas Co
Original Assignee
Rohm and Haas Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Rohm and Haas Co filed Critical Rohm and Haas Co
Publication of GB940272A publication Critical patent/GB940272A/en
Expired legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/53—Polyethers
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D305/00—Heterocyclic compounds containing four-membered rings having one oxygen atom as the only ring hetero atoms
    • C07D305/02—Heterocyclic compounds containing four-membered rings having one oxygen atom as the only ring hetero atoms not condensed with other rings
    • C07D305/04—Heterocyclic compounds containing four-membered rings having one oxygen atom as the only ring hetero atoms not condensed with other rings having no double bonds between ring members or between ring members and non-ring members
    • C07D305/06—Heterocyclic compounds containing four-membered rings having one oxygen atom as the only ring hetero atoms not condensed with other rings having no double bonds between ring members or between ring members and non-ring members with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to the ring atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/15—Heterocyclic compounds having oxygen in the ring
    • C08K5/151—Heterocyclic compounds having oxygen in the ring having one oxygen atom in the ring
    • C08K5/1525—Four-membered rings
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/39—Aldehyde resins; Ketone resins; Polyacetals
    • D06M15/423—Amino-aldehyde resins

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

Oxetane derivatives for use in textile treating compositions are prepared as follows:-(a) 3-ethyl-3-hydroxy methyl oxetane is prepared by reacting together 1,1,1,-trimethylol propane, diethyl carbonate and potassium hydroxide dissolved in ethanol; the corresponding 3-methyl derivative is obtained by using 1,1,1-trimethylolethane instead of 1,1,1-trimethylol propanes and a similar method is used for preparing the C3-C8 alkyl derivatives: and (b) 3-(hydroxyethoxyethoxy-methyl)-3-methyl oxetane, <FORM:0940272/C2/1> is prepared by heating 3-methyl-3-chloromethyl oxetane with a solution of sodium in diethylene glycol and 3,3-di-(hydroxyethoxyethoxymethyl)-oxetane is obtained similarly starting from 3,3-dichloromethyl oxetane; reference is also made to the preparation of 3-(n-octyl)-3-[hydroxy (ethoxy)10 methyl] oxetane.ALSO:Cellulosic or proteinaceous textile fibres (e.g. cotton, rayon or wool) are given crease-resistance crush-resistance, wrinkle-resistance and shrinkage stabilization by treating them with an aqueous solution or dispersion of a mixture of (A) 60-95% of an aminoplast comprising a condensate of formaldehyde with (i) N, N1-ethyleneurea, (ii) N, N1-trimethyleneurea, (iii) a tetrahydro-s-triazone-2 substituted in the 5-position with a b -hydroxyethyl, b -hydroxypropyl or a C1-C4 alkyl group or (iv) an aminotriazine (e.g. melamine) and (B) 5-40% of an oxetane compound of formula <FORM:0940272/D1-D2/1> in which R DEG is -H, -CH2(CnH2n)x-1 OH, -CH2Cl or an alkyl group containing 1-8 carbon atoms, n is 2 or 3 and x is 1 to 11. The aminoplast may be etherified with a C1-C4 alcohol. The composition may be applied to the fibres, filaments or yarn before fabrication but is preferably applied to the preformed fabric. Application may be by spraying, brushing, dipping, padding or roller coating. An aminoplast curing agent (many specified) is applied to the fibres before, simultaneously with or after the composition is applied, the preferred curing agents being zinc fluoborate and zinc nitrate. After application excess of the aqueous composition is removed, the treated material is dried and the aminoplast composition is used by heating it to 220 DEG -450 DEG F. (e.g. by heated air currents, infra-red radiation or high frequency electric induction). Examples describe the treatment of a white cotton fabric.
GB4574/60A 1959-02-13 1960-02-09 Aminoplast compositions for the treatment of textile materials, the textile materials obtained and the process for the treatment thereof Expired GB940272A (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US79299159A 1959-02-13 1959-02-13
US847103A US3074898A (en) 1959-02-13 1959-10-19 Composition comprising aqueous dispersion of aminoplast condensate and an oxetane
US200308A US3239303A (en) 1959-02-13 1962-06-06 Process for the treatment of textiles and the textiles obtained

Publications (1)

Publication Number Publication Date
GB940272A true GB940272A (en) 1963-10-30

Family

ID=27394143

Family Applications (1)

Application Number Title Priority Date Filing Date
GB4574/60A Expired GB940272A (en) 1959-02-13 1960-02-09 Aminoplast compositions for the treatment of textile materials, the textile materials obtained and the process for the treatment thereof

Country Status (4)

Country Link
US (2) US3074898A (en)
DE (1) DE1127863B (en)
FR (1) FR1249582A (en)
GB (1) GB940272A (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3310856A (en) * 1962-10-12 1967-03-28 Deering Milliken Res Corp Method of producing a dimensional stable fabric

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2242484A (en) * 1939-02-28 1941-05-20 American Cyanamid Co Stabilization of resin sirups
US2234889A (en) * 1939-04-04 1941-03-11 Courtaulds Ltd Dyeing of cellulosic textile materials
US2355265A (en) * 1941-04-09 1944-08-08 Rohm & Haas Textile materials
US2451867A (en) * 1944-07-06 1948-10-19 Du Pont Melamine-formaldehyde resin dispersion in a nonbasic water-soluble alcohol medium
US2917468A (en) * 1956-01-18 1959-12-15 Bayer Ag Surface active polymeric trimethylene oxide derivatives with polyether sidechains, and process for producing same
US2794754A (en) * 1956-04-30 1957-06-04 Shell Dev Treatment of textile materials
US3024080A (en) * 1957-10-14 1962-03-06 Rohm & Haas 2, 6-dioxaspiro (3, 3)heptane treated cellulose fabric and the production thereof
US2917412A (en) * 1958-05-12 1959-12-15 Robert M Reinhardt Process for the production of cellulosic textiles with permanent creases and improved soil and abrasion resistance
US2923645A (en) * 1959-01-19 1960-02-02 Du Pont Novel formyloxetanes and process of preparing same

Also Published As

Publication number Publication date
US3074898A (en) 1963-01-22
FR1249582A (en) 1960-12-30
US3239303A (en) 1966-03-08
DE1127863B (en) 1962-04-19

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