GB940252A - The process of manufacturing oxidation derivatives of decahydronaphthalene - Google Patents

The process of manufacturing oxidation derivatives of decahydronaphthalene

Info

Publication number
GB940252A
GB940252A GB19669/61A GB1966961A GB940252A GB 940252 A GB940252 A GB 940252A GB 19669/61 A GB19669/61 A GB 19669/61A GB 1966961 A GB1966961 A GB 1966961A GB 940252 A GB940252 A GB 940252A
Authority
GB
United Kingdom
Prior art keywords
decahydronaphthalene
cis
pure
ketones
trans
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB19669/61A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Inventa AG fuer Forschung und Patentverwertung
Original Assignee
Inventa AG fuer Forschung und Patentverwertung
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Inventa AG fuer Forschung und Patentverwertung filed Critical Inventa AG fuer Forschung und Patentverwertung
Publication of GB940252A publication Critical patent/GB940252A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C409/00—Peroxy compounds
    • C07C409/16—Peroxy compounds the —O—O— group being bound between two carbon atoms not further substituted by oxygen atoms, i.e. peroxides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C407/00—Preparation of peroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C407/00—Preparation of peroxy compounds
    • C07C407/003—Separation; Purification; Stabilisation; Use of additives
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C409/00—Peroxy compounds
    • C07C409/02—Peroxy compounds the —O—O— group being bound between a carbon atom, not further substituted by oxygen atoms, and hydrogen, i.e. hydroperoxides
    • C07C409/14—Peroxy compounds the —O—O— group being bound between a carbon atom, not further substituted by oxygen atoms, and hydrogen, i.e. hydroperoxides the carbon atom belonging to a ring other than a six-membered aromatic ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2602/00—Systems containing two condensed rings
    • C07C2602/02—Systems containing two condensed rings the rings having only two atoms in common
    • C07C2602/14—All rings being cycloaliphatic
    • C07C2602/26—All rings being cycloaliphatic the ring system containing ten carbon atoms
    • C07C2602/28—Hydrogenated naphthalenes

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Trans-9-decahydronaphthalene peroxide and cis-a - and cis-b -decahydronaphthalene ketones and alcohols are produced by reacting pure decahydronaphthalene (as defined) with O2 or an O2-containing gas at 80 to 170 DEG C. "Pure decahydronaphthalene" is defined as decahydronaphthalene, consisting of at least 90% of cisdecahydronaphthalene, from which other substances contained in technically pure decahydronaphthalene have been removed. When the process is carried out at 80 to 110 DEG C. for 24 to 72 hours, the conversion kept below 30%, and water produced by secondary reactions immediately removed from the reaction zone, a product rich in trans-9-decahydronaphthalene peroxide is formed. When the process is carried out at 130 DEG to 170 DEG C. for 4 to 24 hours, the main reaction products are cis-a - and cis-b - decahydronaphthalene ketones and alcohols.
GB19669/61A 1960-07-16 1961-05-31 The process of manufacturing oxidation derivatives of decahydronaphthalene Expired GB940252A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CH811360A CH392494A (en) 1960-07-16 1960-07-16 Process for the preparation of a mixture containing trans-9-decahydronaphthalene hydroperoxide, cis-a- and cis-B-decalydronaphthol and cis-a- and cis-B-decahydronaphthalene ketone

Publications (1)

Publication Number Publication Date
GB940252A true GB940252A (en) 1963-10-30

Family

ID=4335366

Family Applications (1)

Application Number Title Priority Date Filing Date
GB19669/61A Expired GB940252A (en) 1960-07-16 1961-05-31 The process of manufacturing oxidation derivatives of decahydronaphthalene

Country Status (5)

Country Link
BE (1) BE605718A (en)
CH (1) CH392494A (en)
DK (1) DK120187B (en)
ES (1) ES267037A1 (en)
GB (1) GB940252A (en)

Also Published As

Publication number Publication date
BE605718A (en) 1961-11-03
ES267037A1 (en) 1961-11-01
DK120187B (en) 1971-04-26
CH392494A (en) 1965-05-31

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