GB938206A - Process for the production of purest indium - Google Patents
Process for the production of purest indiumInfo
- Publication number
- GB938206A GB938206A GB2022061A GB2022061A GB938206A GB 938206 A GB938206 A GB 938206A GB 2022061 A GB2022061 A GB 2022061A GB 2022061 A GB2022061 A GB 2022061A GB 938206 A GB938206 A GB 938206A
- Authority
- GB
- United Kingdom
- Prior art keywords
- indium
- electrolyte
- amalgam
- stage
- mercury
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C1/00—Electrolytic production, recovery or refining of metals by electrolysis of solutions
- C25C1/22—Electrolytic production, recovery or refining of metals by electrolysis of solutions of metals not provided for in groups C25C1/02 - C25C1/20
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
- Electrolytic Production Of Metals (AREA)
Abstract
938,206. Preparing pure indium. DUISBURGER - KUPFERHUTTE. June 5, 1961 [July 12, 1960], No. 20220/61. Class 41. Pure indium is prepared by electrolysis of an aqueous indium salt solution using a flowing mercury cathode, with which the deposited indium forms an amalgam, in several stages wherein the indium amalgam formed in stage 1 is used as anode in stage 2 to form a purified indium electrolyte from which indium is again deposited on mercury to form an amalgam. Impurity metals are removed from both electrolyte and amalgam by counter flowing mercury from the last cell to the first, and also introducing a second electrolyte, e.g. HCl, in counter-flow with the depleted indium salt electrolytes. In a final stage the purified indium amalgam is used as anode, with a water-free molten pure indium salt, e.g. halide, as electrolyte, preferably in admixture with LiCl and other alkali metal or alkaline earth metal halides, the temperature being maintained above the melting-point of indium metal and the electrolyte, e.g. 200‹ to 250‹ C. The pure liquid indium is drawn off from the cathode area. In the Figure, indium chloride solution is fed at a line 5 into three cells la, 1b, 1c, in series, through which mercury flows in reverse and is drawn off by a pump 13. A level overflow regulator 34 is provided. Chlorine is evolved at carbon anodes 9, 10, 11 and the depleted electrolyte flows out to discharge at 12. The indium amalgam is pumped into cell 2 provided with a partition 19, and the indium dissolves in the electrolyte 16 from the amalgam anode 15, and reforms an amalgam 17. A second similar process is effected in stage 3. HC] is injected at line 28 and flows through stages 3 and 2 to stage 1a by-passing the stages 1b 1c. The acid removes noble metals, zinc and iron, and the rate of flow is adjusted to equal that of the electrolyte flow out at 12. Mercury is added through at line 31, and enters the cathode zone of stage 3. In the final zone 4 the purified indium amalgam 24 is decomposed via the electrolyte 25 and pure liquid indium metal is drawn off at 27. Preferably a large anode surface is used relative to the cathode. Any traces of mercury are removed by heating to 800‹ C. in vacuo, in hydrogen or an inert gas.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DED33767A DE1132342B (en) | 1960-07-12 | 1960-07-12 | Electrolytic process for the continuous production of very pure indium |
Publications (1)
Publication Number | Publication Date |
---|---|
GB938206A true GB938206A (en) | 1963-10-02 |
Family
ID=7041878
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB2022061A Expired GB938206A (en) | 1960-07-12 | 1961-06-05 | Process for the production of purest indium |
Country Status (3)
Country | Link |
---|---|
BE (1) | BE596095A (en) |
DE (1) | DE1132342B (en) |
GB (1) | GB938206A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101892495A (en) * | 2010-06-29 | 2010-11-24 | 葫芦岛锌业股份有限公司 | Method for producing 4N5 pure indium by electrolyzing high impurity crude indium once |
CN101748433B (en) * | 2008-12-18 | 2011-04-20 | 北京有色金属研究总院 | Purification method of electrolyte in indium electrolysis process |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102016104237A1 (en) * | 2016-03-09 | 2017-09-14 | Thorsten Koras | Electrolytic refining of crude gold |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CH331606A (en) * | 1954-01-11 | 1958-07-31 | Stiftung Seltene Metalle | Process for the electrolytic deposition of pure indium |
-
1960
- 1960-07-12 DE DED33767A patent/DE1132342B/en active Pending
- 1960-10-17 BE BE596095A patent/BE596095A/en unknown
-
1961
- 1961-06-05 GB GB2022061A patent/GB938206A/en not_active Expired
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101748433B (en) * | 2008-12-18 | 2011-04-20 | 北京有色金属研究总院 | Purification method of electrolyte in indium electrolysis process |
CN101892495A (en) * | 2010-06-29 | 2010-11-24 | 葫芦岛锌业股份有限公司 | Method for producing 4N5 pure indium by electrolyzing high impurity crude indium once |
CN101892495B (en) * | 2010-06-29 | 2012-02-22 | 葫芦岛锌业股份有限公司 | Method for producing 4N5 pure indium by electrolyzing high impurity crude indium once |
Also Published As
Publication number | Publication date |
---|---|
DE1132342B (en) | 1962-06-28 |
BE596095A (en) | 1961-02-15 |
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