GB933663A - Hydrofining catalyst and process - Google Patents

Hydrofining catalyst and process

Info

Publication number
GB933663A
GB933663A GB824561A GB824561A GB933663A GB 933663 A GB933663 A GB 933663A GB 824561 A GB824561 A GB 824561A GB 824561 A GB824561 A GB 824561A GB 933663 A GB933663 A GB 933663A
Authority
GB
United Kingdom
Prior art keywords
catalyst
hydrofining
surface area
pore diameter
weight
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB824561A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Technology and Engineering Co
Original Assignee
Exxon Research and Engineering Co
Esso Research and Engineering Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Exxon Research and Engineering Co, Esso Research and Engineering Co filed Critical Exxon Research and Engineering Co
Publication of GB933663A publication Critical patent/GB933663A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
    • C10G45/04—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
    • C10G45/06—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof
    • C10G45/08—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof in combination with chromium, molybdenum, or tungsten metals, or compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/882—Molybdenum and cobalt

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Materials Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

Gas oils boiling in the range 600 DEG -1100 DEG F. and hydrogen are passed to a reaction zone containing a fixed bed of a hydrofining catalyst, the hydrofining conditions in the zone being a temperature of 500 DEG -1000 DEG F. and a pressure of 50 p.s.i.g.-3,000 p.s.i.g. The hydrogen rate is 50-10,000 SCF/Bbl and the feed rate is 0,1-5 V./V./Hr. The catalyst comprises 1,15%-5,5% by weight of cobalt expressed as cobalt oxide and 8,5%-16,5% by weight of molybdenum expressed as molybdena on a gamma type alumina, said alumina having a surface area of 200 m2/gm.-240 m2/gm. and an average pore diameter of 70-100 , having been prepared by calcining at 1050 DEG -1250 DEG F. under such conditions, including time, that the desired surface area and pore diameter are obtained. The catalyst is essentially free of other elements.
GB824561A 1960-04-15 1961-03-07 Hydrofining catalyst and process Expired GB933663A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US2254360A 1960-04-15 1960-04-15
US2248260A 1960-04-15 1960-04-15

Publications (1)

Publication Number Publication Date
GB933663A true GB933663A (en) 1963-08-08

Family

ID=26695975

Family Applications (1)

Application Number Title Priority Date Filing Date
GB824561A Expired GB933663A (en) 1960-04-15 1961-03-07 Hydrofining catalyst and process

Country Status (2)

Country Link
GB (1) GB933663A (en)
NL (1) NL262698A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1545397A1 (en) * 1965-11-30 1970-01-29 Standard Oil Co A catalyst and a process for the hydrogenation processing of petroleum
NL9301235A (en) * 1992-07-14 1994-02-01 Cosmo Research Inst En Cosmo O ALUMINUM OXIDE-CONTAINING CARRIER AND HYDROFINING CATALYST FOR CARBON OILS.

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1545397A1 (en) * 1965-11-30 1970-01-29 Standard Oil Co A catalyst and a process for the hydrogenation processing of petroleum
NL9301235A (en) * 1992-07-14 1994-02-01 Cosmo Research Inst En Cosmo O ALUMINUM OXIDE-CONTAINING CARRIER AND HYDROFINING CATALYST FOR CARBON OILS.

Also Published As

Publication number Publication date
NL262698A (en)

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