GB929328A - Water soluble binders - Google Patents

Water soluble binders

Info

Publication number
GB929328A
GB929328A GB4487/62A GB448762A GB929328A GB 929328 A GB929328 A GB 929328A GB 4487/62 A GB4487/62 A GB 4487/62A GB 448762 A GB448762 A GB 448762A GB 929328 A GB929328 A GB 929328A
Authority
GB
United Kingdom
Prior art keywords
weight
vinyl
water
parts
esters
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB4487/62A
Inventor
Hans Wilhelm
Eberhard Wegner
Karl Kohl
Kurt Demmler
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Badische Anilin and Sodafabrik AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE, Badische Anilin and Sodafabrik AG filed Critical BASF SE
Publication of GB929328A publication Critical patent/GB929328A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
    • C09J133/04—Homopolymers or copolymers of esters
    • C09J133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C09J133/062—Copolymers with monomers not covered by C09J133/06
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04—Homopolymers or copolymers of esters
    • C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C09D133/062—Copolymers with monomers not covered by C09D133/06
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/24—Homopolymers or copolymers of amides or imides
    • C09D133/26—Homopolymers or copolymers of acrylamide or methacrylamide
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D161/00—Coating compositions based on condensation polymers of aldehydes or ketones; Coating compositions based on derivatives of such polymers
    • C09D161/20—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
    • C09J133/24—Homopolymers or copolymers of amides or imides
    • C09J133/26—Homopolymers or copolymers of acrylamide or methacrylamide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
    • C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials
    • C08L2666/14—Macromolecular compounds according to C08L59/00 - C08L87/00; Derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L61/00—Compositions of condensation polymers of aldehydes or ketones; Compositions of derivatives of such polymers
    • C08L61/04—Condensation polymers of aldehydes or ketones with phenols only
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L61/00—Compositions of condensation polymers of aldehydes or ketones; Compositions of derivatives of such polymers
    • C08L61/20—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Paints Or Removers (AREA)
  • Phenolic Resins Or Amino Resins (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

Water-soluble binders comprise (1) 40 to 90% by weight of a water-soluble copolymer and (2) 10 to 60% by weight of water-soluble phenoplasts and/or aminoplasts, said percentages relating to the total weight of (1) and (2), and said copolymer being a copolymer of (a) 35 to 64 parts by weight of acrylamide and/or methacrylamide, (b) 35 to 64 parts by weight of one or more esters of acrylic or methacrylic acid with saturated monohydric alcohols containing 1 to 20 carbon atoms, (c) 1 to 15 parts by weight of one or more monoesters of acrylic or methacrylic acid with saturated polyhydric alcohols, and optionally (d) 0,01 to 10 parts by weight of other copolymerizable monomers, the sum of the parts by weight of components (a) to (c) amounting to 100. Specified esters (b) are those of methanol, ethanol, n-propanol, isopropanol, n-butanol, isobutanol and t. butanol. The ester (c) may be of ethanediol, propanediol-1,2, propanediol-1,3, butanediol-1,2, pentanediol-1,2, hexanediol-1,2, glycerol, 1,1,1-trimethylolpropane and pentaerythritol. The monomers (d) may be unsaturated carboxylic acids, or esters, nitriles, amides or salts thereof; vinyl esters; vinyl aromatic hydrocarbons; vinyl and vinylidene halides; vinyl lactams; vinyl amines; vinyl sulphamides and vinyl sulphones. The phenoplast may be a condensate of phenol or cresol with formaldehyde. The aminoplast may be a condensate of formaldehyde with urea, thiourea, melamine, ammeline, guanidine, dicyandiamide, glyoxalureides or ethylene urea. The binders may be dissolved in water, optionally with the addition of water-miscible organic solvents, e.g. alcohols, ethers or ketones; dyes and pigments; and levelling aids such as glycol ethers, acetals, glycols, dimethyl formamide, sulphones and sulphoxides. Examples describe the preparation of copolymers of (I) acrylamide, ethyl acrylate, t-butyl acrylate and butanediol-1,4-monoacrylate and (II) acrylamide, methacrylamide, ethyl acrylate, 2-ethylhexyl methacrylate and butanediol-1,4-monoacrylate by polymerization in n-butanol in the presence of benzoyl peroxide and sodium hydroxymethanesulphinate; and the formation of binders by dissolving these copolymers in aqueous solutions of phenolformaldehyde condensate and tetramethylolglyoxaldiureine. The compositions may be used for coating wood, metal and plastics; impregnating fabrics and paper; and laminating; and may be cured by heating, optionally in the presence of acid reacting substances such as carboxylic acids and ammonium nitrate or chloride.
GB4487/62A 1961-02-07 1962-02-06 Water soluble binders Expired GB929328A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DEB61162A DE1228357B (en) 1961-02-07 1961-02-07 Aqueous stoving enamels

Publications (1)

Publication Number Publication Date
GB929328A true GB929328A (en) 1963-06-19

Family

ID=6973094

Family Applications (1)

Application Number Title Priority Date Filing Date
GB4487/62A Expired GB929328A (en) 1961-02-07 1962-02-06 Water soluble binders

Country Status (3)

Country Link
BE (1) BE613544A (en)
DE (1) DE1228357B (en)
GB (1) GB929328A (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3914463A (en) * 1972-12-15 1975-10-21 Rohm & Haas Method of protecting substrates with light-stable varnish or lacquer

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2862901A (en) * 1958-12-02 Aqueous solution of amino-aldehyde

Also Published As

Publication number Publication date
BE613544A (en) 1900-01-01
DE1228357B (en) 1966-11-10

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