GB926308A - Detergent compositions and process for treating textiles therewith - Google Patents
Detergent compositions and process for treating textiles therewithInfo
- Publication number
- GB926308A GB926308A GB7866/61A GB786661A GB926308A GB 926308 A GB926308 A GB 926308A GB 7866/61 A GB7866/61 A GB 7866/61A GB 786661 A GB786661 A GB 786661A GB 926308 A GB926308 A GB 926308A
- Authority
- GB
- United Kingdom
- Prior art keywords
- sodium
- sulphonate
- acid
- fatty
- sulphate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Detergent Compositions (AREA)
Abstract
A detergent composition comprises (a) a water soluble condensation product of an aryl sulphonic acid, which may be substituted by amino, hydroxy, nitro, halo, or further sulphonic acid groups in the aryl nucleus, with an aldehyde or ketone, most suitably diphenyl-, dinaphthyl-, or dicresyl-methane disulphonic acids or water soluble, e.g. the sodium, potassium or ammonium salts thereof; (b) a further additional noncationic detergent to (a); and (c) a water soluble organic carboxylic acid having a molecular weight below 300 and being present in sufficient amount to impart a pH of 2-5 to an 0,5% aqueous solution of the composition. The additional detergent (b) may be a sodium or potassium alkyl-benzene sulphonate or the free acid thereof sodium dialkyl sulphosuccinate, sodium sulphoethylphthalate, sodium-N-oleoyl-p-anisidine sulphonate, sodium alkane sulphonate, sodium diisopropylnaphthalene sulphonate, sodium alkyl sulphate, sodium octylphenoxydiethenoxy sulphate; an ethylene oxide condensates with an alkylphenol, with a fatty alcohol, or with a fatty sorbitan ester; or a fatty monoester of sorbitan or polyglycerol, or a fatty diester of glycol. Acid (c) should have a pKa value of 5 X 10-2-1 X 10-8, preferably 1 X 10-3-1 X 10-6, and may suitably be acetic, formic, mono- or di-chloracetic, hydroxyacetic, lactic, tartaric, gluconic, oxalic, or (most preferably) citric acid. In general the proportion by weight of (a) to (c) is 1 : 100 to 6 : 1. Sodium sulphate, sodium and potassium chloride, mono-, di- and tri-sodium phosphate, hexametaphosphate and pyrophosphate, sodium chlorite, lignin sulphonic acid, methylcellulose and those fluorescent brighteners referred to on pages 2909-2922 (Vol. 2) and 3341-3342 (Vol. 3) of the "Colour Index" (1957 Edn.) may also be included. The compositions are stated to be particularly suitable for use with textiles (see Group IV(c)).ALSO:A detergent composition which is stated to improve the "hand", tensile and tear strength, warmth, flex abrasion resistance and elasticity of textiles washed therewith comprises (a) a water-soluble condensation product of an aryl sulphonic acid which may be substituted by amino, hydroxy, nitro, halo, or further sulphonic acid groups in the aryl nucleus, with an aldehyde or ketone, most suitably diphenyl-, dinaphthyl-, or p dicresyl-methane disulphonic acids or water-soluble, e.g. the sodium, potassium or ammonium, salts thereof; (b) a further additional non-cationic detergent to (a); and (c) a water-soluble organic carboxylic acid having a molecular weight below 300 and being present in sufficient amount to impart a pH of 2-5 to an 0,5% aqueous solution of the composition. The additional detergent (b) may be a sodium or potassium alkyl-benzene sulphonate or the free acid thereof, sodium dialkyl sulphosuccinate, sodium sulphoethylphthalate, sodium-N-oleoyl-p-anisidine sulphonate, sodium alkane sulphonate, sodium diisopropylnaphthalene sulphonate, sodium alkyl sulphate, sodium octylphenoxydiethenoxy sulphate; an ethylene oxide condensates with an alkylphenol, with a fatty alcohol, or with a fatty sorbitan ester; or a fatty monoester of sorbitan or polyglycerol, or a fatty diester of glycol. Acid (c) should have a pKa value of 5 X 10-2-1 X 10-8, preferably 1 X 10-3-1 X 10-6, and may suitably be acetic, formic, mono- or di-chloracetic, hydroxyacetic, lactic tartaric, gluconic, oxalic, or (most preferably) citric acid. In general the proportion by weight of (a) to (c) is 1:100 to 6:1. Sodium sulphate, sodium and potassium chloride, mono-, di- and tri-sodium phosphate, hexametaphosphate and pyrophosphate, sodium chlorite, lignin sulphonic acid, methylcellulose and those fluorescent brighteners referred to on pages 2909-2922 (Vol. 2) and 3341-3342 (Vol. 3) of the "Colour Index" (1957 Edn.) may also be included. The compositions are of application to textiles of natural or regenerated cellulose, cellulose acetates and ethers, nylon, polyacrylonitrile, polyvinylidene chloride, and polyesters, and particularly to materials containing 40% or more of wool. In the case of wool it is preferred to use compositions having a pH below the isoelectric point of the wool. The compositions are generally employed at above 60 DEG C. at a liquor ratio of 10-50:1, condensate (a) comprising 0,01-5% by weight of the dry fabric.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US13727A US3083166A (en) | 1960-03-09 | 1960-03-09 | Detergent composition |
Publications (1)
Publication Number | Publication Date |
---|---|
GB926308A true GB926308A (en) | 1963-05-15 |
Family
ID=21761416
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB7866/61A Expired GB926308A (en) | 1960-03-09 | 1961-03-03 | Detergent compositions and process for treating textiles therewith |
Country Status (5)
Country | Link |
---|---|
US (1) | US3083166A (en) |
BE (1) | BE601054A (en) |
CH (1) | CH377310A (en) |
GB (1) | GB926308A (en) |
NL (1) | NL262189A (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4445901A (en) * | 1981-10-09 | 1984-05-01 | Lever Brothers Company | Fabric conditioning composition |
US5538648A (en) * | 1991-03-20 | 1996-07-23 | Sandoz Ltd. | Process for pretreating a textile material |
EP2804938B1 (en) | 2012-01-18 | 2018-02-28 | The Procter and Gamble Company | Acidic laundry detergent compositions |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3216932A (en) * | 1962-11-08 | 1965-11-09 | Diamond Crystal Salt Co | Salt product and method of making and using same |
US4614612A (en) * | 1977-12-22 | 1986-09-30 | Lever Brothers Company | Liquid detergent composition |
US4404040A (en) * | 1981-07-01 | 1983-09-13 | Economics Laboratory, Inc. | Short chain fatty acid sanitizing composition and methods |
US4737314A (en) * | 1985-02-08 | 1988-04-12 | Nippon Shokubai Kagaku Kogyo Co., Ltd. | Stabilized alkylene oxide adduct containing lactic acid or a lactate |
GB8508010D0 (en) * | 1985-03-27 | 1985-05-01 | Unilever Plc | Liquid bleaching compositions |
JPH08503209A (en) * | 1992-11-09 | 1996-04-09 | ウエスト・アグロ・インコーポレーテッド | Improved acid disinfectant composition |
US20060111261A1 (en) * | 2004-11-19 | 2006-05-25 | The Procter & Gamble Company | Acidic laundry detergent compositions |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2555285A (en) * | 1951-05-29 | Detergent composition | ||
GB459039A (en) * | 1934-03-24 | 1936-12-28 | Ig Farbenindustrie Ag | Manufacture of washing agents and detergents |
US2692238A (en) * | 1954-03-09 | 1954-10-19 | Pro Nyl Chemicals Inc | Wash and rinse composition for whitening and brightening nylon |
US2913416A (en) * | 1955-03-04 | 1959-11-17 | Rohm & Haas | Liquid detergent composition |
US2844539A (en) * | 1955-05-06 | 1958-07-22 | American Cyanamid Co | Water soluble brightener composition |
US2947702A (en) * | 1957-01-23 | 1960-08-02 | Procter & Gamble | Liquid detergent compositions |
-
0
- BE BE601054D patent/BE601054A/xx unknown
- NL NL262189D patent/NL262189A/xx unknown
-
1960
- 1960-03-09 US US13727A patent/US3083166A/en not_active Expired - Lifetime
-
1961
- 1961-02-24 CH CH222861A patent/CH377310A/en unknown
- 1961-03-03 GB GB7866/61A patent/GB926308A/en not_active Expired
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4445901A (en) * | 1981-10-09 | 1984-05-01 | Lever Brothers Company | Fabric conditioning composition |
US5538648A (en) * | 1991-03-20 | 1996-07-23 | Sandoz Ltd. | Process for pretreating a textile material |
EP2804938B1 (en) | 2012-01-18 | 2018-02-28 | The Procter and Gamble Company | Acidic laundry detergent compositions |
Also Published As
Publication number | Publication date |
---|---|
NL262189A (en) | |
BE601054A (en) | |
CH377310A (en) | 1964-06-30 |
CH222861A4 (en) | 1964-01-31 |
US3083166A (en) | 1963-03-26 |
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