GB925998A - New vat dyestuffs containing halopyrimidine residues and process for their manufacture - Google Patents

New vat dyestuffs containing halopyrimidine residues and process for their manufacture

Info

Publication number
GB925998A
GB925998A GB4002160A GB4002160A GB925998A GB 925998 A GB925998 A GB 925998A GB 4002160 A GB4002160 A GB 4002160A GB 4002160 A GB4002160 A GB 4002160A GB 925998 A GB925998 A GB 925998A
Authority
GB
United Kingdom
Prior art keywords
vattable
dyes
series
formula
compound
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB4002160A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF Schweiz AG
Original Assignee
Ciba AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from CH8084159A external-priority patent/CH434525A/en
Application filed by Ciba AG filed Critical Ciba AG
Publication of GB925998A publication Critical patent/GB925998A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09BORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B62/00Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves
    • C09B62/02Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves with the reactive group directly attached to a heterocyclic ring
    • C09B62/20Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves with the reactive group directly attached to a heterocyclic ring to a pyrimidine ring
    • C09B62/22Anthracene dyes

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Nitrogen And Oxygen Or Sulfur-Condensed Heterocyclic Ring Systems (AREA)

Abstract

2-(31- or 41-carboxyphenylamino)-4,6-di- or -4,5,6-tri-chloropyrimidines are prepared by condensing 3- or 4-aminobenzoic acid with 2,4,6-trichloropyrimidine or 2,4,5,6-tetrachloropyrimidine. The preparation of the corresponding acid chlorides by reaction with thionyl chloride is also specified.ALSO:The invention comprises vat dyes of formula <FORM:0925998/IV(a)/1> wherein A is the residue of a vattable compound free from sulphonic and carboxylic acid groups, as hereinafter defined, which contains 3 to 8 condensed rings, X is a chlorine atom or a methyl group, Z is a hydrogen or chlorine atom and n is 1 or 2. A "vattable compound" is a compound which can be converted by reduction into a leuco-form or vat having a better affinity for natural or regenerated cellulose fibres than in the non-reduced and can be reconverted by oxidation into the original chromophoric system. Suitable vattable compounds are dyes of the anthraquinone series which contain 3-8 condensed carbocyclic or heterocyclic rings or a plurality of anthraquinone units, perylene tetracarboxylic acid series and thioindigoid series. The dyes are prepared by condensing a suitable vattable compound containing at least one acylatable amino group with a pyrimidine derivative of formula:- <FORM:0925998/IV(a)/2> (see Group IV(b)). In an example 5:51-diamino-1:11-dianthrimidecarbazole is condensed with the acid chloride of 2-(31-carboxyphenylamino)-4:6-dichloropyrimidine to give the dye of probable formula:- <FORM:0925998/IV(a)/3> Further examples are given.
GB4002160A 1959-11-20 1960-11-21 New vat dyestuffs containing halopyrimidine residues and process for their manufacture Expired GB925998A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CH8084159A CH434525A (en) 1959-11-20 1959-11-20 Process for the production of new anthraquinone vat dyes
CH1148660 1960-10-13

Publications (1)

Publication Number Publication Date
GB925998A true GB925998A (en) 1963-05-15

Family

ID=25708390

Family Applications (1)

Application Number Title Priority Date Filing Date
GB4002160A Expired GB925998A (en) 1959-11-20 1960-11-21 New vat dyestuffs containing halopyrimidine residues and process for their manufacture

Country Status (1)

Country Link
GB (1) GB925998A (en)

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