GB925038A - Water-soluble coating compositions - Google Patents

Water-soluble coating compositions

Info

Publication number
GB925038A
GB925038A GB2932661A GB2932661A GB925038A GB 925038 A GB925038 A GB 925038A GB 2932661 A GB2932661 A GB 2932661A GB 2932661 A GB2932661 A GB 2932661A GB 925038 A GB925038 A GB 925038A
Authority
GB
United Kingdom
Prior art keywords
drying
water
reaction product
maleic anhydride
air
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB2932661A
Inventor
Louis Joseph Lombardi
Howard James Wright
Paul Francis Westfall
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
VARNISH Co
Cook Paint and Varnish Co
Original Assignee
VARNISH Co
Cook Paint and Varnish Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by VARNISH Co, Cook Paint and Varnish Co filed Critical VARNISH Co
Priority to GB2932661A priority Critical patent/GB925038A/en
Publication of GB925038A publication Critical patent/GB925038A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F242/00—Copolymers of drying oils with other monomers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • C08F20/62—Monocarboxylic acids having ten or more carbon atoms; Derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F212/02—Monomers containing only one unsaturated aliphatic radical
    • C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F212/06—Hydrocarbons
    • C08F212/12—Monomers containing a branched unsaturated aliphatic radical or a ring substituted by an alkyl radical
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F222/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides, or nitriles thereof
    • C08F222/04—Anhydrides, e.g. cyclic anhydrides
    • C08F222/06—Maleic anhydride

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Paints Or Removers (AREA)

Abstract

A water-soluble resinous composition capable of air-drying into water-insoluble form comprises a water-soluble salt of the reaction product of a drying oil, maleic anhydride, acrylic and/or methacrylic acid and at least one ethylenically unsaturated monomer which is free from carboxylic acid and anhydride groups. The salts may be formed from an alkali metal or ammonium hydroxide or an amine e.g. diethylamine, dimethylamine, triethanolamine, ethylene diamine, triethylamine, morpholine, 2-amino-gamma-methyl-1-propanol and di-isopropylamine. Drying oils specified are linseed, soya, dehydrated castor, safflower and tall oils. Specified monomers are vinyl toluene, styrene, alpha C1-4 alkyl styrenes, alkyl acrylates and methacrylates and mixtures thereof. The preferred procedure is to react the oil and maleic anhydride and then to add the acid and monomer, preferably incrementally. The formation of the reaction product may be catalysed by benzoyl or di-t-butyl peroxide or cumene hydroperoxide. Neutralisation is usually effected by adding the base in aqueous solution which may also include glycol monoethyl ether or ethyl, butyl or amyl alcohol. The resulting aqueous composition may include an air-drying catalyst e.g. cobalt or lead naphthenate, which is usually added with a wetting agent, and may be used to coat wood, paper, metals and alloys e.g. steel, aluminium and tinplate, fabrics, and films of synthetic thermo-plastic or setting material e.g. polyethylene glycol terephthalate.ALSO:A water-soluble resinous composition capable of air-drying into water-insoluble form comprises a water-soluble salt of the reaction product of a drying oil, maleic anhydride, acrylic and/or methacrylic acid and at least one ethylenically unsaturated monomer which is free from carboxylic acid and anhydride groups. The salts may be formed from an alkali metal or ammonium hydroxide or an amine, e.g. diethylamine, dimethylamine, triethanolamine, ethylene diamine, triethylamine, morpholine, 2-amino-gamma-methyl-1-propanol and di-isopropylamine. Drying oils specified are linseed, soya, dehydrated castor, safflower and tall oils. Specified monomers are vinyl toluene, styrene, alpha C1-4 alkyl styrenes, alkyl acrylates and methacrylates and mixtures thereof. The preferred procedure is to react the oil and maleic anhydride and then to add the acid and monomer, preferably incrementally. The formation of the reaction product may be catalysed by benzoyl or di-t-butyl peroxide or cumene hydroperoxide. Neutralization is usually effected by adding the base in aqueous solution which may also include glycol monoethyl ether or ethyl, butyl or amyl alcohol. The resulting aqueous composition may include an air-drying catalyst, e.g. cobalt or lead naphthenate, which is usually added with a wetting agent, and may be used to coat wood, paper, metals and alloys, e.g. steel, aluminium and tinplate, fabrics, and films of synthetic thermoplastic or setting material, e.g. polyethylene glycol terephthalate.
GB2932661A 1961-08-14 1961-08-14 Water-soluble coating compositions Expired GB925038A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB2932661A GB925038A (en) 1961-08-14 1961-08-14 Water-soluble coating compositions

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB2932661A GB925038A (en) 1961-08-14 1961-08-14 Water-soluble coating compositions

Publications (1)

Publication Number Publication Date
GB925038A true GB925038A (en) 1963-05-01

Family

ID=10289787

Family Applications (1)

Application Number Title Priority Date Filing Date
GB2932661A Expired GB925038A (en) 1961-08-14 1961-08-14 Water-soluble coating compositions

Country Status (1)

Country Link
GB (1) GB925038A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1267363B (en) * 1964-06-08 1968-05-02 Reichhold Chemie Ag Binder for aqueous coating compounds for the electrophoretic application process
DE1298669B (en) * 1964-05-29 1969-07-03 Reichhold Albert Chemie Ag Water-thinnable stoving enamels

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1298669B (en) * 1964-05-29 1969-07-03 Reichhold Albert Chemie Ag Water-thinnable stoving enamels
DE1267363B (en) * 1964-06-08 1968-05-02 Reichhold Chemie Ag Binder for aqueous coating compounds for the electrophoretic application process

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