GB924645A - Improvements in the production of vinyl chloride polymers - Google Patents

Improvements in the production of vinyl chloride polymers

Info

Publication number
GB924645A
GB924645A GB3795060A GB3795060A GB924645A GB 924645 A GB924645 A GB 924645A GB 3795060 A GB3795060 A GB 3795060A GB 3795060 A GB3795060 A GB 3795060A GB 924645 A GB924645 A GB 924645A
Authority
GB
United Kingdom
Prior art keywords
water
acid
solvents
peroxide
weight
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB3795060A
Inventor
Lyle Eugene Perrins
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Imperial Chemical Industries Ltd
Original Assignee
Imperial Chemical Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Imperial Chemical Industries Ltd filed Critical Imperial Chemical Industries Ltd
Priority to US148045A priority Critical patent/US3166534A/en
Priority to SE10888/61A priority patent/SE308208B/xx
Priority to ES0271727A priority patent/ES271727A1/en
Publication of GB924645A publication Critical patent/GB924645A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D10/00—Compositions of detergents, not provided for by one single preceding group
    • C11D10/04—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
    • C11D10/042—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap based on anionic surface-active compounds and soap
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D19/00—Degasification of liquids
    • B01D19/02—Foam dispersion or prevention
    • B01D19/04—Foam dispersion or prevention by addition of chemical substances
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D19/00—Degasification of liquids
    • B01D19/02—Foam dispersion or prevention
    • B01D19/04—Foam dispersion or prevention by addition of chemical substances
    • B01D19/0404—Foam dispersion or prevention by addition of chemical substances characterised by the nature of the chemical substance
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F214/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F214/02—Monomers containing chlorine
    • C08F214/04—Monomers containing two carbon atoms
    • C08F214/06—Vinyl chloride
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F22/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides or nitriles thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/04—Carboxylic acids or salts thereof
    • C11D1/06—Ether- or thioether carboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/04—Carboxylic acids or salts thereof
    • C11D1/10—Amino carboxylic acids; Imino carboxylic acids; Fatty acid condensates thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/88—Ampholytes; Electroneutral compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/0026—Low foaming or foam regulating compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/72—Ethers of polyoxyalkylene glycols

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Dispersion Chemistry (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Detergent Compositions (AREA)
  • Paints Or Removers (AREA)

Abstract

Vinyl chloride polymers containing free carboxyl groups are prepared by copolymerizing vinyl chloride and a monoethylenically unsaturated carboxylic acid, or an anhydride or acid chloride of such an acid, or a partial ester of a monoethylenically unsaturated polycarboxylic acid, alone or together with other copolymerizable monomers in the presence of a dispersing agent and a polymerization catalyst and in an aqueous medium containing from 5 to 25% by weight of a water-miscible organic solvent or mixture of solvents based on the weight of water. Suitable monoethylenically unsaturated carboxylic acids include maleic, fumaric, acrylic, methacrylic, crotonic, itaconic and aconitic acids and the proportion of said acid, acid anhydride, acid chloride or partial ester is preferably between 0,3% and 10% of the total weight of polymerizable compounds employed. Suitable water-miscible organic solvents are low molecular weight alcohols, glycols, esters of low molecular weight, e.g. methyl acetate, and ketones, e.g. acetone methyl ethyl ketone. Mixtures of two or more of these solvents may be used and other organic solvents which are normally substantially immiscible with water may also be added in small quantities to the water-miscible solvent or solvents. Dispersion agents mentioned are gelatine, polyvinyl alcohol, starch, methyl cellulose, glycol cellulose and other high molecular weight water-soluble polymers such as polyalkylene oxides. Polymerization catalysts which may be used include organic peroxides and hydroperoxides, e.g. acetyl peroxide, tertiary butyl peroxide, lauroyl peroxide and succinyl peroxide, hyponitrous esters, e.g. benzyl hyponitrile and azo compounds having molecules containing the group >C-N=N-C< in which the two carbon atoms are non-aromatic in character, e.g. a , a 1-bis-(a , g -dimethyl valeronitrile) and azo di-isobutyronitrile. The catalyst may be added to the monomeric materials as a solution in an organic solvent. Chain-transfer agents, e.g. chloroform and tetrachloroethylene, may be added. Small proportions of other polymerizable compounds may be included, e.g. vinyl esters of saturated monocarboxylic acids, acrylonitrile and methacrylonitrile; the proportion employed should not exceed 40% of the total weight of polymerizable compounds employed. The products of the invention may be used as heat-sealable coatings on aluminium foil, lacquers for beer cans and for coating glass and wood surfaces.
GB3795060A 1960-11-04 1960-11-04 Improvements in the production of vinyl chloride polymers Expired GB924645A (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
US148045A US3166534A (en) 1960-11-04 1961-10-27 Process for production in aqueous medium of copolymers of vinyl chloride with monomers containing free carboxylic acid groups
SE10888/61A SE308208B (en) 1960-11-04 1961-11-01
ES0271727A ES271727A1 (en) 1960-11-04 1961-11-03 Procedure for obtaining vinyl chloride polymers containing carboxyl free groups (Machine-translation by Google Translate, not legally binding)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
LU53379A LU53379A1 (en) 1967-04-07 1967-04-07

Publications (1)

Publication Number Publication Date
GB924645A true GB924645A (en) 1963-04-24

Family

ID=19725174

Family Applications (2)

Application Number Title Priority Date Filing Date
GB3795060A Expired GB924645A (en) 1960-11-04 1960-11-04 Improvements in the production of vinyl chloride polymers
GB1628868A Expired GB1169496A (en) 1967-04-07 1968-04-04 Detergent Compositions.

Family Applications After (1)

Application Number Title Priority Date Filing Date
GB1628868A Expired GB1169496A (en) 1967-04-07 1968-04-04 Detergent Compositions.

Country Status (14)

Country Link
AT (1) AT282783B (en)
BE (2) BE713270A (en)
CH (1) CH499617A (en)
DE (1) DE1767143B2 (en)
DK (2) DK125431B (en)
ES (1) ES352465A1 (en)
FI (1) FI49834C (en)
FR (1) FR1577358A (en)
GB (2) GB924645A (en)
IE (1) IE32003B1 (en)
LU (1) LU53379A1 (en)
NL (3) NL153270B (en)
NO (1) NO124882B (en)
SE (1) SE348219B (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5719243A (en) * 1994-05-06 1998-02-17 Akzo Nobel Nv Use of peroxyacids as molecular weight regulators

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3819538A (en) * 1972-05-15 1974-06-25 Dow Chemical Co Environmentally compatible laundry detergent
GB1432137A (en) 1972-06-13 1976-04-14 Chem Y Detergent compositions
GB1564507A (en) * 1976-01-16 1980-04-10 Unilever Ltd Detergent composition
NL8203257A (en) * 1982-08-19 1984-03-16 Chem Y NEW POLYETHERCARBONIC ACID DERIVATIVES AND THEIR APPLICATIONS.
NL8301389A (en) * 1983-04-20 1984-11-16 Chem Y NEW LIQUID IODOPHORS.
DE3703258A1 (en) 1987-02-04 1988-08-18 Eau De Cologne & Parfuemerie Fabrik 4711 Soap-based personal care products
US4877544A (en) * 1987-04-17 1989-10-31 Lever Brothers Company Oxidation stable surfactants
FR2617862B1 (en) * 1987-07-09 1994-01-07 Sandoz Sa BUILDER FREE DETERGENT COMPOSITIONS
DE3905939A1 (en) * 1989-02-25 1990-08-30 Huels Chemische Werke Ag TENSIDE COMBINATION
US5298195A (en) * 1992-03-09 1994-03-29 Amway Corporation Liquid dishwashing detergent
EP4392512A1 (en) 2021-08-25 2024-07-03 Unilever IP Holdings B.V. Detergent composition
WO2023025739A1 (en) 2021-08-25 2023-03-02 Unilever Ip Holdings B.V. Detergent composition

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5719243A (en) * 1994-05-06 1998-02-17 Akzo Nobel Nv Use of peroxyacids as molecular weight regulators

Also Published As

Publication number Publication date
BE713270A (en) 1968-10-04
GB1169496A (en) 1969-11-05
DE1767143B2 (en) 1976-12-23
NL124882C (en)
NL270987A (en)
NL153270B (en) 1977-05-16
DK125431A (en)
NL6804638A (en) 1968-10-08
CH499617A (en) 1970-11-30
AT282783B (en) 1970-07-10
ES352465A1 (en) 1969-09-16
FI49834C (en) 1975-10-10
NO124882B (en) 1972-06-19
BE609934A (en)
FI49834B (en) 1975-06-30
IE32003L (en) 1968-10-07
DK125431B (en) 1973-02-19
IE32003B1 (en) 1973-03-07
SE348219B (en) 1972-08-28
DE1767143A1 (en) 1971-08-19
LU53379A1 (en) 1968-11-27
FR1577358A (en) 1969-08-08

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