GB918880A - Improvements in carbon products and in their production - Google Patents

Improvements in carbon products and in their production

Info

Publication number
GB918880A
GB918880A GB4394660A GB4394660A GB918880A GB 918880 A GB918880 A GB 918880A GB 4394660 A GB4394660 A GB 4394660A GB 4394660 A GB4394660 A GB 4394660A GB 918880 A GB918880 A GB 918880A
Authority
GB
United Kingdom
Prior art keywords
graphite
explosive
tube
round
water
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB4394660A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
EIDP Inc
Original Assignee
EI Du Pont de Nemours and Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by EI Du Pont de Nemours and Co filed Critical EI Du Pont de Nemours and Co
Publication of GB918880A publication Critical patent/GB918880A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/515Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics
    • C04B35/52Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics based on carbon, e.g. graphite
    • C04B35/522Graphite
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/64Burning or sintering processes
    • C04B35/645Pressure sintering
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D303/00Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
    • C07D303/02Compounds containing oxirane rings
    • C07D303/48Compounds containing oxirane rings with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, directly attached to ring carbon atoms, e.g. ester or nitrile radicals
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F22/00Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides or nitriles thereof
    • C08F22/30Nitriles
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/02Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
    • C08G63/06Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from hydroxycarboxylic acids
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/70Aspects relating to sintered or melt-casted ceramic products
    • C04B2235/74Physical characteristics
    • C04B2235/77Density
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/70Aspects relating to sintered or melt-casted ceramic products
    • C04B2235/74Physical characteristics
    • C04B2235/78Grain sizes and shapes, product microstructures, e.g. acicular grains, equiaxed grains, platelet-structures
    • C04B2235/787Oriented grains
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/70Aspects relating to sintered or melt-casted ceramic products
    • C04B2235/96Properties of ceramic products, e.g. mechanical properties such as strength, toughness, wear resistance

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Structural Engineering (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Inorganic Chemistry (AREA)
  • Ceramic Products (AREA)

Abstract

Compacted graphite having a density of at least 1,9 g/cc. and a relative crystallite alignment not exceeding 70% is produced by initiating a <PICT:0918880/III/1> <PICT:0918880/III/2> detonating explosive round a mass of graphite. In the Figures, 1 is a mass of graphite powder in a seamless steel tube 2 closed with stoppers 3, 4. 5 is a wrap of detonating explosive around tube 2, and 6 is a layer of detonating explosive around inert cone 7. 8 is an electric blasting cap. In Fig. 2, explosive 5 surrounds a retainer element, e.g. cardboard tube 10, maintaining an annulus of water 11 between tube 2 and explosive 5. One or more line wave generators 14 are attached to explosive 5 by taping around its periphery. The whole assembly may be submerged in water as shown. When blasting cap 8 is actuated, either explosive 6 or line wave generator 14 is initiated, which initiates explosive 5, the detonation then proceeding down the whole length of explosive 5. This constricts tube 2 and compresses the graphite. Explosives having detonation velocities of 4000 to 5000 metres per sec. are preferred, e.g. TNT, HMX, PETN, or nitroglycerine based explosives. In place of the annulus of water (Fig. 2), cardboard or foamed polystyrene may be used. To prevent the formation of cracks, the tube containing the compacted graphite may be heated to 400 DEG -500 DEG C. before removal. Graphite may be produced in the form of rods, slabs, sheets, or tubes. The tubes are made round a steel mandrel which is removed by hand, or round a low melting alloy mandrel which is removed by melting. Specifications 863,194, 876,951 and 878,196 are referred to.ALSO:Graphite articles having a density of at least 1,9 g/c.c. and a relative crystallite alignment not exceeding 70% are produced by initiating explosion in a detonating explosive surrounding a mass of graphite powder. The explosive surrounding the powder is preferably initiated at one end and substantially simultaneously at all points on the periphery of that end. For uniform compression the graphite may be enclosed in a steel tube. A liquid, e.g. water, may be interposed between the explosive and the tube containing the graphite, and the whole assembly may be submerged in water. Graphite articles may be obtained in the form of rods, slabs, sheets or tubes. The tubes are obtained by compressing the graphite round a steel mandrel which is removed by hand, or round a low melting alloy mandrel which is removed by melting. Specifications 863,194, 876,951 and 878,196 are referred to.
GB4394660A 1959-12-23 1960-12-21 Improvements in carbon products and in their production Expired GB918880A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US86164959A 1959-12-23 1959-12-23
US6755960A 1960-11-07 1960-11-07

Publications (1)

Publication Number Publication Date
GB918880A true GB918880A (en) 1963-02-20

Family

ID=26748010

Family Applications (1)

Application Number Title Priority Date Filing Date
GB4394660A Expired GB918880A (en) 1959-12-23 1960-12-21 Improvements in carbon products and in their production

Country Status (2)

Country Link
GB (1) GB918880A (en)
NL (1) NL259428A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3248592A (en) * 1963-09-10 1966-04-26 Varian Associates Anisotropic arc-spark emission electrodes
US3307063A (en) * 1962-03-02 1967-02-28 Thomson Houston Comp Francaise Grid electrode made of pyrolytic graphite
US4039145A (en) * 1974-09-06 1977-08-02 Air-Industrie Electrostatic powdering nozzle
GB2170489A (en) * 1984-12-21 1986-08-06 Leslie James Mayne An apparatus for crystallising carbon

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3307063A (en) * 1962-03-02 1967-02-28 Thomson Houston Comp Francaise Grid electrode made of pyrolytic graphite
US3248592A (en) * 1963-09-10 1966-04-26 Varian Associates Anisotropic arc-spark emission electrodes
US4039145A (en) * 1974-09-06 1977-08-02 Air-Industrie Electrostatic powdering nozzle
GB2170489A (en) * 1984-12-21 1986-08-06 Leslie James Mayne An apparatus for crystallising carbon

Also Published As

Publication number Publication date
NL259428A (en)

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