GB914879A - Insecticidal compositions - Google Patents

Insecticidal compositions

Info

Publication number
GB914879A
GB914879A GB28699/59A GB2869959A GB914879A GB 914879 A GB914879 A GB 914879A GB 28699/59 A GB28699/59 A GB 28699/59A GB 2869959 A GB2869959 A GB 2869959A GB 914879 A GB914879 A GB 914879A
Authority
GB
United Kingdom
Prior art keywords
resins
prepared
dimethyl
phosphorothioate
diethyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB28699/59A
Inventor
David Michael Langbridge
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Cooper Mcdougall and Robertson Ltd
Original Assignee
Cooper Mcdougall and Robertson Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to BE594266D priority Critical patent/BE594266A/xx
Priority to NL255024D priority patent/NL255024A/xx
Application filed by Cooper Mcdougall and Robertson Ltd filed Critical Cooper Mcdougall and Robertson Ltd
Priority to GB28699/59A priority patent/GB914879A/en
Priority to FR836068A priority patent/FR1274949A/en
Priority to ES0260515A priority patent/ES260515A1/en
Publication of GB914879A publication Critical patent/GB914879A/en
Expired legal-status Critical Current

Links

Classifications

    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/08Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing solids as carriers or diluents
    • A01N25/10Macromolecular compounds

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Agronomy & Crop Science (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

A grindable solid resinous composition comprises an insecticide in a thermoset resin. The composition is prepared by p mixing the insecticide with the precursor of the thermosetting resin and then setting or curing the mixture by a catalyst, leaving for a period of time, heating or by exposure to ultra-violet irradiation. Specified thermosetting resins are (a) unsaturated alkyd resins prepared by condensing one or more unsaturated dibasic organic acids, e.g. maleic or phthalic acids or their anhydrides with one or more saturated or unsaturated glycols, e.g. propylene glycol, followed by blending with a monomeric unsaturated organic compound, e.g. styrene, a -methylstyrene, vinyl toluene, diallyl phthalate or methylmethacrylate, using as catalyst an organic peroxide such as benzoyl peroxide, ethyl methyl ketone peroxide, cyclohexanone peroxide or cumene hydroperoxide with or without an accelerator, e.g. cobalt or manganese napthenate; (b) the di-isocyanate-modified unsaturated alkydresins prepared as in (a) but using an organic di-isocyanate as blending agent; (c) epoxy resins prepared from a precursor which is a reaction product of a polyhydric alcohol or phenol with a halohydrin, e.g. epichlorohydrin or a diepoxy compound, e.g. butadiene dioxide using as catalyst a polyfunctional amine or amide, e.g. diethylenetriamine or diethylamino propylamine or one or more polybasic acids; (d) amino resins, e.g. "Cellobond" (Registered Trade Mark) prepared from precursors which are reaction products of formaldehyde with urea or melamine or both, the precursors of ethers of amino resins being prepared by a similar reaction employing an aliphatic monohydric alcohol of more than three carbon atoms, e.g. butanol. The precursor is cured by an acid catalyst; (e) phenolic resins, e.g. resoles and the ethers thereof prepared as in (d) using phenol, cresol, xyleneol or mixtures thereof instead of urea or melamine; and (f) the product obtained by curing the liquid polymer of an alkenyl phenol, e.g. obtained from cashew nut shell, with formaldehyde, formalin, hexamine or paraformaldehyde. The composition may also contain a filler, e.g. diatomaceous earth and may be formulated with a surface active agent. Specified insecticides are o,o-dimethyl-s-(1,2-dicarbethoxyethyl)-phosphorodithioate; o,o-diethyl-o-(2-isopropyl-4-methylpyrinidyl-6)-phosphorothioate; 2,3-p-dioxanedithiol-s,s-bis-(o,o-diethyl phosphorodithioate); o,o,o,o-tetraethyl-s,s-methylene-bis-(phosphorodithioate); o,o-diethyl-o-(2,4-dichlorophenyl)-phosphorothioate; o,o-diethyl-o-p-nitrophenylphosphorothioate; o,o-dimethyl-1,2-dibromo-2,2-dichloroethyl phosphate; o,o-dimethyl-2,2-dichlorovinyl phosphate; o,o-dimethyl-o-(3-chloro-4-nitrophenyl)-phosphorothioate; pyrethrins with or without a synergist, e.g. piperonylbutoxide; D.D.T; dieldrin and benzene hexachloride. The composition may contain other pesticides, e.g. miticides, acaricides, bactericides or nematocides providing they do not inhibit the setting of the resin.ALSO:A grindable solid resinous composition comprises an insecticide in a thermoset resin. The composition is prepared by mixing the insecticide with the precursor of the thermosetting resin and then setting or curing the mixture by a catylyst, leaving for a period of time, heating or by exposure to ultra-violet irradiation. Specified thermosetting resins are (a) unsaturated alkyd resins prepared by condensing one or more unsaturated dibasic organic acids e.g. maleic or phthalic acids or their anhydrides with one of more saturated or unsaturated glycols e.g. propylene glycol, followed by blending with a monomeric unsaturated organic compound e.g. styrene, a -methylstyrene, vinyl toluene, diallyl phthalate or methyl methacrylate, using as catalyst an organic peroxide such as benzoyl peroxide, ethyl methyl ketone peroxide, cyclohexanone peroxide or cumene hydroperoxide with or without an accelerator, e.g. cobalt or manganese naphthenate; (b) the di-isocyanate-modified unsaturated alkyd resins prepared as in (a) but using an organic di-isocyanate as blending agent; (c) epoxy resins prepared from a precursor which is a reaction product of a polyhydric alcohol or phenol with a halohydrin e.g. epichlorohydrin or a diepoxy compound e.g. butadiene dioxide using as catalyst a polyfunctional amine or amide e.g. diethylene triamine or diethylamino propylamine or one or more polybasic acids; (d) amino resins e.g. "Cello-bond" (Registered Trade Mark) prepared from precursors which are reaction products of formaldehyde with urea or malmine or both, the precursors of ethers of amino resins being prepared by a similar reaction employing an aliphatic monohydric alcohol of more than three carbon atoms e.g. butanol. The precursor is cured by an acid catalyst; (e) phenolic resins e.g. resoles and the ethers thereof prepared as in (d) using phenol, cresol, xyleneol or mixtures thereof instead of urea or melamine; and (f) the product obtained by curing the liquid polymer of an alkenyl phenol e.g. obtained from cashew nut shell, with formaldehyde, formalin, hexamine or paraformaldehyde. The composition may also contain a filler e.g. diatomaceus earth and may be formulated with a surface active agent. Specified insecticides are o, o-dimethyl-s-(1, 2-dicarbethoxyethyl)-phos-phorodithioate; o, o-diethyl-o-(2-isopropyl-4-methyl-pyrmidyl-6)-phosphorothioate; 2, 3-p-dioxanedithiol-s, s-bis-(o, o-diethylphosphorodithioate); o, o, o, o-tetraethyl-s, s-methylene-bis-(phosphoro-dithioate); o, o-diethyl-o-(2, 4-dichlorophenyl)-phosphorothioate; o,o-diethyl-o-p-nitrophenyl phosphorothioate; o, o-dimethyl-1, 2-dibromo-2, 2-dichloroethyl phosphate; o, o-dimethyl-2, 2-dichlorovinyl phosphate; o, o-dimethyl-o-(3-chloro-4-nitrophenyl)-phosphorothioate; pyrethrins with or without a synergist e.g. piperonyl butoxide; D.D.T.; dieldrin and benzene hexachloride. The composition may contain other pesticides e.g. miticides, acarcides, bactericicles or nematocides providing they do not inhibit the setting of the resin.ALSO:A grindable solid insecticidal composition comprises an insecticide in a thermoset resin. Specified insecticides are o,o-dimethyl-s-(1,2-dicarbethoxyethyl) - phosphorodithioate; o,o-diethyl - o - (2 - isopropyl - 4 - methyl - pyrimidyl - 6) - phosphorothioate; 2,3 - p - dioxanedithiol - s,s - bis - (o,o - diethylphosphorodithioate); o,o,o,o - tetraethyl - s,s - methylene-bis - (phosphorodithioate); o,o - diethyl - o - (2,4-dichlorophenyl) - phosphorothioate; o,o-diethyl-o - p - nitrophenylphosphorothioate; o,o - dimethyl - 1,2 - dibromo - 2,2 - dichloroethyl phosphate; o,o - dimethyl - 2,2 - dichlorovinyl phosphate; o,o - dimethyl - o - (3 - chloro - 4 - nitrophenyl) - phosphorothioate; pyrethrins with or without a synergist such as piperonyl butoxide; D.D.T.; Dieldrin and benzene hexachloride. Specified resins (see Group IV (a)) are unsaturated polyester resins, diisocyanate-modified polyether resins, epoxy resins, amino-aldehyde resins, phenolic resins, e.g. resoles and the ethers thereof and the resins obtained by curing the liquid polymer of an alkenyl phenol with formaldehyde or a source of formaldehyde. The compositions may be powdered and preferably mixed with a particulate filler, e.g. diatomaceous earth, or may be in the form of a wettable powder containing a surface-active agent or a deflocculating agent, e.g. sodium salt of di-isobutylnaphthalene sulphonic acid "Orotan" (Registered Trade Mark). The compositions may contain other pesticides, e.g. miticides, acaricides, bactericides or nematocides providing they do not inhibit the setting of the resin. The solid compositions are prepared by mixing the insecticide with the precursor of the thermosetting resin and setting the mixture.
GB28699/59A 1959-08-21 1959-08-21 Insecticidal compositions Expired GB914879A (en)

Priority Applications (5)

Application Number Priority Date Filing Date Title
BE594266D BE594266A (en) 1959-08-21
NL255024D NL255024A (en) 1959-08-21
GB28699/59A GB914879A (en) 1959-08-21 1959-08-21 Insecticidal compositions
FR836068A FR1274949A (en) 1959-08-21 1960-08-18 Insecticidal compositions
ES0260515A ES260515A1 (en) 1959-08-21 1960-08-20 Insecticidal compositions

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB28699/59A GB914879A (en) 1959-08-21 1959-08-21 Insecticidal compositions

Publications (1)

Publication Number Publication Date
GB914879A true GB914879A (en) 1963-01-09

Family

ID=10279689

Family Applications (1)

Application Number Title Priority Date Filing Date
GB28699/59A Expired GB914879A (en) 1959-08-21 1959-08-21 Insecticidal compositions

Country Status (5)

Country Link
BE (1) BE594266A (en)
ES (1) ES260515A1 (en)
FR (1) FR1274949A (en)
GB (1) GB914879A (en)
NL (1) NL255024A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2715595A1 (en) * 1977-04-07 1978-10-12 Bayer Ag Insecticidal coating mass for animal collars - contg. an insecticide in a cold-hardening two-component system pref. polyurethane

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2715595A1 (en) * 1977-04-07 1978-10-12 Bayer Ag Insecticidal coating mass for animal collars - contg. an insecticide in a cold-hardening two-component system pref. polyurethane

Also Published As

Publication number Publication date
FR1274949A (en) 1961-11-03
ES260515A1 (en) 1961-04-01
BE594266A (en)
NL255024A (en)

Similar Documents

Publication Publication Date Title
GB744388A (en) Improvements in and relating to chlorinated maleic adduct-ethoxyline resinous compositions
KR890010094A (en) Flexible Treated Epoxy Resin Composition
GB914879A (en) Insecticidal compositions
US3428601A (en) Method of converting an epoxy resin into the infusible state
GB999389A (en) Method for the production of permanent magnets
JPS5569616A (en) Epoxy resin composition for carbon fiber-reinforcement
GB1172916A (en) Amino Epoxy Phosphonates, Compositions containing them and process of preparation
JPS5765716A (en) Curing of thermosetting resin composition
EP0303164A3 (en) Curing agent compositions laminating varnishes containing same and laminates prepared therefrom
KR890003901A (en) Powder coating composition
JPS60202117A (en) Epoxy resin composition
JPS5659841A (en) Epoxy resin composition
JP5235254B2 (en) Latent curing accelerator, epoxy resin composition containing the same, and cured product thereof
GB809191A (en) Improvements in or relating to the manufacture of abrasive articles
GB1273780A (en) Process for hardening epoxy resins
DE1233606B (en) Process for the preparation of polymeric boron compounds
JPS57121028A (en) Epoxy resin composition
JPS5573725A (en) Epoxy resin composition for carbon fiber reinforced plastics
JPS5731966A (en) Production of epoxy resin powdered paint
GB1009198A (en) Sealing composition and lining material
JPH1192670A (en) Thermosetting resin composition
SU981327A1 (en) Polymeric molding composition
JPS5454199A (en) Epoxy resin composition
GB1031369A (en) New diels-alder derivatives of phosphorus-containing fulvene derivatives
US3544517A (en) Amino-ethylated novolaks as curing agents for epoxy resins