GB907664A - Lubricant material - Google Patents

Lubricant material

Info

Publication number
GB907664A
GB907664A GB40499/58A GB4049958A GB907664A GB 907664 A GB907664 A GB 907664A GB 40499/58 A GB40499/58 A GB 40499/58A GB 4049958 A GB4049958 A GB 4049958A GB 907664 A GB907664 A GB 907664A
Authority
GB
United Kingdom
Prior art keywords
lubricant
esters
added
tin sulphide
oils
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB40499/58A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ethyl Corp
Original Assignee
Ethyl Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ethyl Corp filed Critical Ethyl Corp
Publication of GB907664A publication Critical patent/GB907664A/en
Expired legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M1/00—Liquid compositions essentially based on mineral lubricating oils or fatty oils; Their use as lubricants
    • C10M1/08—Liquid compositions essentially based on mineral lubricating oils or fatty oils; Their use as lubricants with additives
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/22—Tin compounds
    • C07F7/226—Compounds with one or more Sn-S linkages
    • C—CHEMISTRY; METALLURGY
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    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/02—Water
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    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/06—Metal compounds
    • C10M2201/062—Oxides; Hydroxides; Carbonates or bicarbonates
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    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/06—Metal compounds
    • C10M2201/063—Peroxides
    • C—CHEMISTRY; METALLURGY
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    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/087—Boron oxides, acids or salts
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    • C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
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    • C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
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    • C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C10M2203/102—Aliphatic fractions
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    • C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C10M2203/104—Aromatic fractions
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    • C10M2203/106—Naphthenic fractions
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    • C10M2203/108—Residual fractions, e.g. bright stocks
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    • C10M2205/02—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
    • C10M2205/026—Butene
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    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/18—Natural waxes, e.g. ceresin, ozocerite, bees wax, carnauba; Degras
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    • C10M2207/021—Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms
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    • C10M2207/021—Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/022—Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms containing at least two hydroxy groups
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    • C10M2207/026—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings with tertiary alkyl groups
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    • C10M2207/125—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
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    • C10M2207/129—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of thirty or more carbon atoms
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    • C10M2207/16—Naphthenic acids
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    • C10M2207/282—Esters of (cyclo)aliphatic oolycarboxylic acids
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    • C10M2207/283—Esters of polyhydroxy compounds
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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2050/00—Form in which the lubricant is applied to the material being lubricated
    • C10N2050/10—Semi-solids; greasy
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2060/00—Chemical after-treatment of the constituents of the lubricating composition
    • C10N2060/04—Oxidation, e.g. ozonisation

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Lubricants (AREA)

Abstract

A lubricant material contains an oleoginous lubricant base together with (a) a dialkyl tin sulphide compound of formula <FORM:0907664/III/1> wherein R1 and R2 are the same or different alkyl groups containing 3-6 carbon atoms or (b) a trimeric tin sulphide compound of formula <FORM:0907664/III/2> wherein the R1s are methyl or ethyl groups or hydrogen. The lubricant base may be chosen from hydrocarbon oils (e.g. petroleum or polyolefin oils), organosilicon compounds (e.g. polysiloxanes, halogen-substituted polysiloxanes or silicate esters), polyesters (e.g. dialkyl esters of dicarboxylic acids, complex esters, esters formed between polycarboxylic acids and mono- or poly-hydric alcohols, or esters formed between monocarboxylic acids and polyhydric alcohols), fluorocarbon or chlorofluorocarbon oils, aromatic ether oils (which may be halogen-substituted), phosphate esters, tetrahydrofuran/alkene oxide copolymers, polyalkylene glycols or their esters or ethers, polyglycidyl ethers and polythioglycols. The lubricant material may contain additional ingredients such as soaps (e.g. lead oleate, aluminium tristearate, lithium naphthenate or barium oleate), antioxidants or other thickeners, and may be used as a lubricant in electric equipment or as a cutting oil. Where the lubricant material is a grease, it may contain unreacted fat, fatty acids and alkali; unsaponifiable matter including glycerol and fatty alcohols; rosin or wool grease; water; and modifiers or peptizers. In use, the lubricant material may be placed between the rubbing surfaces, the surfaces allowed to rub together at a low initial load while in contact with the lubricant material, and the load gradually increased up to the operating load. In this way, an anti-wear film is believed to be formed on the rubbing surfaces. Alternatively, a break-in lubricant (comprising an organometallic compound of a Group IIIa or IVa metal and a mineral oil) may first be placed between the rubbing surfaces, the surfaces allowed to rub together lightly while in contact with the break-in lubricant, and the break-in lubricant then removed and replaced by the lubricant containing the tin sulphide compound. In the examples, (1) diisopropyl tin sulphide is added to a grease prepared from mineral oil, 12-hydroxy stearic acid, boric acid and quicklime, (2) di-n-butyl tin sulphide is added to a grease prepared from mineral oil, blown asphalt, hydrogenated fish oil fatty acids and litharge, (3)2,2,4,4,6,6-hexamethyl-1,3,5,2,4,6-trithiatristanninane is added to mineral white oil and (4) 2,4,6-triethyl- 2,4,6-trimethyl-1,3,5,2,4,6,-trithiatristanninane is added to a mixture of the o-, m- and p-isomers of bis-(methylphenoxy) benzene.
GB40499/58A 1957-12-17 1958-12-16 Lubricant material Expired GB907664A (en)

Applications Claiming Priority (7)

Application Number Priority Date Filing Date Title
US703286A US3058912A (en) 1957-12-17 1957-12-17 Lubricant compositions
US71900058A 1958-03-04 1958-03-04
US72364158A 1958-03-25 1958-03-25
US723640A US3036972A (en) 1957-12-17 1958-03-25 Lubricant composition
US73967958A 1958-06-04 1958-06-04
US752414A US3077451A (en) 1957-12-17 1958-08-01 Lubricant compositions
US759416A US3063943A (en) 1957-12-17 1958-09-08 Lubricant compositions

Publications (1)

Publication Number Publication Date
GB907664A true GB907664A (en) 1962-10-10

Family

ID=27569889

Family Applications (1)

Application Number Title Priority Date Filing Date
GB40499/58A Expired GB907664A (en) 1957-12-17 1958-12-16 Lubricant material

Country Status (3)

Country Link
US (4) US3058912A (en)
FR (1) FR1234139A (en)
GB (1) GB907664A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3489683A (en) * 1967-05-29 1970-01-13 Ethyl Corp Synergistic antioxidant compositions
US3511782A (en) * 1967-05-29 1970-05-12 Ethyl Corp Synthetic ester lubricants containing trihydrocarbyl tin sulfides and phenothiazines

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3251661A (en) * 1961-11-15 1966-05-17 Ethyl Corp Two-cycle internal combustion engine fuel
US3303132A (en) * 1964-03-19 1967-02-07 Mobil Oil Corp High temperature lubricating compositions
US3442806A (en) * 1966-12-22 1969-05-06 Ethyl Corp Stabilized organic material
US3530069A (en) * 1969-03-10 1970-09-22 Ethyl Corp Stabilized organic material
US4462935A (en) * 1982-07-12 1984-07-31 Gulf Research & Development Company Quaternary phosphonium thiostannates
JPS61266494A (en) * 1985-05-20 1986-11-26 Nippon Mining Co Ltd Lubricating oil used in flon atomosphere

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2187802A (en) * 1937-09-25 1940-01-23 Tide Water Associated Oil Comp Lubricating oil and lubrication therewith
US2288288A (en) * 1938-08-26 1942-06-30 Socony Vacuum Oil Co Inc Lubricating oil
US2257750A (en) * 1939-05-24 1941-10-07 Continental Oil Co Lubricating oil
US2334566A (en) * 1940-03-11 1943-11-16 Lubri Zol Dev Corp Lubricating oil
US2354218A (en) * 1940-06-03 1944-07-25 Indium Corp America Operation and lubrication of mechanical apparatus
US2417833A (en) * 1944-04-22 1947-03-25 Continental Oil Co Lubricant
US2511250A (en) * 1947-11-14 1950-06-13 Gulf Research Development Co Stabilized extreme pressure lubricants
US2499984A (en) * 1948-12-16 1950-03-07 Rohm & Haas Oily complex esters
US2891922A (en) * 1951-07-07 1959-06-23 Metal & Thermit Corp Organo tin compounds and compositions containing same
US2642395A (en) * 1952-02-08 1953-06-16 Dow Corning Siloxane boundary lubricants
US2789103A (en) * 1954-01-29 1957-04-16 Metal & Thermit Corp Rubber stabilized with hydrocarbon tin compounds

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3489683A (en) * 1967-05-29 1970-01-13 Ethyl Corp Synergistic antioxidant compositions
US3511782A (en) * 1967-05-29 1970-05-12 Ethyl Corp Synthetic ester lubricants containing trihydrocarbyl tin sulfides and phenothiazines

Also Published As

Publication number Publication date
FR1234139A (en) 1960-10-14
US3058912A (en) 1962-10-16
US3077451A (en) 1963-02-12
US3036972A (en) 1962-05-29
US3063943A (en) 1962-11-13

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