GB905149A - Process for the manufacture of filamentary materials of regenerated cellulose by spinning viscose - Google Patents
Process for the manufacture of filamentary materials of regenerated cellulose by spinning viscoseInfo
- Publication number
- GB905149A GB905149A GB456561A GB456561A GB905149A GB 905149 A GB905149 A GB 905149A GB 456561 A GB456561 A GB 456561A GB 456561 A GB456561 A GB 456561A GB 905149 A GB905149 A GB 905149A
- Authority
- GB
- United Kingdom
- Prior art keywords
- ethylene oxide
- mols
- aliphatic
- carbon atoms
- viscose
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F2/00—Monocomponent artificial filaments or the like of cellulose or cellulose derivatives; Manufacture thereof
- D01F2/06—Monocomponent artificial filaments or the like of cellulose or cellulose derivatives; Manufacture thereof from viscose
- D01F2/08—Composition of the spinning solution or the bath
- D01F2/10—Addition to the spinning solution or spinning bath of substances which exert their effect equally well in either
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D1/00—Evaporating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D3/00—Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
- B01D3/007—Energy recuperation; Heat pumps
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D3/00—Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
- B01D3/08—Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping in rotating vessels; Atomisation on rotating discs
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02B—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO BUILDINGS, e.g. HOUSING, HOUSE APPLIANCES OR RELATED END-USER APPLICATIONS
- Y02B30/00—Energy efficient heating, ventilation or air conditioning [HVAC]
- Y02B30/52—Heat recovery pumps, i.e. heat pump based systems or units able to transfer the thermal energy from one area of the premises or part of the facilities to a different one, improving the overall efficiency
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Artificial Filaments (AREA)
Abstract
In viscose spinning, there is added to the viscose, and/or to the coagulating bath, an ethylene oxide addition product of a compound having at least 8 carbon atoms which contains an amide, sulphonamide or a primary or secondary amino group and in which the terminal hydroxyl group of the polyethylene oxide chain is substituted by an alkylamino residue having 2-3 carbon atoms. The compound may contain an aliphatic, aliphatic-cycloaliphatic, or aliphatic-aromatic hydrocarbon residue with 8-20 carbon atoms and a polyethylene oxide chain with 5-40 mols. ethylene oxide. Specified compounds are as follows:- <FORM:0905149/IV(a)/1> <FORM:0905149/IV(a)/2> <FORM:0905149/IV(a)/3> <FORM:0905149/IV(a)/4> <FORM:0905149/IV(a)/5> <FORM:0905149/IV(a)/6> These compounds are derived from high-molecular amines and acid amides which contain aliphatic, aliphatic-cycloaliphatic, or aliphatic-aromatic hydrocarbon residues, indicated by R, having 8-20 carbon atoms, and contain polyethylene oxide residues having 5-40 mols. ethylene oxide per molecule, the alkyl amino groups having 2-3 carbon atoms. Such compounds may be made by treating the ethylene oxide addition products with acrylonitrile followed by hydrogenation, or by treatment of the ethylene oxide addition products with ethylene imine, e.g. the hydrogenated reaction product of acrylonitrile with the addition product of 9 mols. ethylene oxide to 1 mol. dodecylamine, the hydrogenated reaction product of 1 or 2 mols. acrylonitrile with an alkylamine mixture having 8-18 carbon atoms made on the basis of coconut oil and reacted with 8 mols. ethylene oxide, the reaction product of ethylene imine with the addition product of 12 mols. ethylene oxide to 1 mol. oleic acid-N-methylamide, the mono-g -amino propyl ether of the addition product of 12 mols. ethylene oxide to either (a) 1 mol. fatty acid mono-ethanolamide (fatty acid residue C12-C18), or (b) 1 mol. of an alkylamine mixture (C6-C18 alkyl residues), or the bis-g -amino-propyl ether of the addition product of 12 mols. ethylene oxide to 1 mol. of an alkylamine mixture (C8-C18 alkyl residues). In the examples these compounds are added to the viscose before ripening. From 0,01-0,5% by weight of the compound calculated on the viscose, or on the coagulating bath, as appropriate, may be added, and the viscose may be spun into an acid coagulating bath which contains at least 35 g/l. ZnSO4, preferably 35-105 g/l. ZnSO4, and 60-100 g/l. H2SO4. Desirably, the bath contains 95 g/l. ZnSO4 and 75 g/l. H2SO4. The filaments may be stretched in a second, weak acid bath. Filaments so made have a round or bean-shaped structure with a full or thick shell, and a smooth periphery, and show higher strengths and lower swelling values compared with conventional filaments. The filaments are suitable for use in tyre cord.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DEG29042A DE1163489B (en) | 1960-02-17 | 1960-02-17 | Process for the production of threads, fibers or films from regenerated cellulose by spinning viscose |
DEG32494A DE1257354B (en) | 1960-02-17 | 1961-06-14 | Process for the production of threads, fibers or films from regenerated cellulose by the viscose process |
Publications (1)
Publication Number | Publication Date |
---|---|
GB905149A true GB905149A (en) | 1962-09-05 |
Family
ID=25978243
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB456561A Expired GB905149A (en) | 1960-02-17 | 1961-02-07 | Process for the manufacture of filamentary materials of regenerated cellulose by spinning viscose |
GB2210562A Expired GB947020A (en) | 1960-02-17 | 1962-06-07 | Process for the manufacture of threads, filaments and films of regenerated cellulose by spinning viscose |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB2210562A Expired GB947020A (en) | 1960-02-17 | 1962-06-07 | Process for the manufacture of threads, filaments and films of regenerated cellulose by spinning viscose |
Country Status (6)
Country | Link |
---|---|
BE (1) | BE597656A (en) |
CH (1) | CH250654A (en) |
DE (1) | DE1257354B (en) |
FR (1) | FR924496A (en) |
GB (2) | GB905149A (en) |
NL (4) | NL259963A (en) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2313955A1 (en) * | 1975-06-13 | 1977-01-07 | Mac Cord James | Vapour generating and recovering appts. - with a variable refrigeration system including an automatic evaporating by-pass arrangement |
EP0006612B1 (en) * | 1978-06-28 | 1984-01-18 | McCord, James W. | Vapor generating and recovering apparatus |
DE3015525C2 (en) * | 1980-04-23 | 1982-07-01 | Langbein-Pfanhauser Werke Ag, 4040 Neuss | Plant for distilling liquids with a heat pump |
DE4125216A1 (en) * | 1991-07-30 | 1993-02-04 | Linde Ag | DEVICE FOR PURIFYING OR PREPARING GASES |
DE19754314A1 (en) * | 1997-12-08 | 1999-06-10 | Henkel Kgaa | Aid for the production of cellulose fibers |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
AT197529B (en) * | 1956-07-24 | 1958-05-10 | Glanzstoff Ag | Process for increasing the stretchability of freshly spun viscose threads |
-
0
- NL NL124391D patent/NL124391C/xx active
- BE BE597656D patent/BE597656A/xx unknown
- NL NL124546D patent/NL124546C/xx active
- NL NL278295D patent/NL278295A/xx unknown
- NL NL259963D patent/NL259963A/xx unknown
-
1945
- 1945-03-31 CH CH250654D patent/CH250654A/en unknown
-
1946
- 1946-03-27 FR FR924496D patent/FR924496A/en not_active Expired
-
1961
- 1961-02-07 GB GB456561A patent/GB905149A/en not_active Expired
- 1961-06-14 DE DEG32494A patent/DE1257354B/en active Pending
-
1962
- 1962-06-07 GB GB2210562A patent/GB947020A/en not_active Expired
Also Published As
Publication number | Publication date |
---|---|
FR924496A (en) | 1947-08-06 |
NL278295A (en) | |
NL259963A (en) | |
GB947020A (en) | 1964-01-22 |
BE597656A (en) | |
CH250654A (en) | 1947-09-15 |
NL124391C (en) | |
NL124546C (en) | |
DE1257354B (en) | 1967-12-28 |
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