GB900868A - Improvements in and relating to amylose sponges and gauze - Google Patents

Improvements in and relating to amylose sponges and gauze

Info

Publication number
GB900868A
GB900868A GB2757860A GB2757860A GB900868A GB 900868 A GB900868 A GB 900868A GB 2757860 A GB2757860 A GB 2757860A GB 2757860 A GB2757860 A GB 2757860A GB 900868 A GB900868 A GB 900868A
Authority
GB
United Kingdom
Prior art keywords
amylose
sponges
water
ammonium
dispersing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB2757860A
Inventor
Morton Wolf Rutenberg
Wadym Jarowenko
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ingredion Inc
Original Assignee
National Starch and Chemical Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to NL122390D priority Critical patent/NL122390C/xx
Priority to NL254963D priority patent/NL254963A/xx
Priority to US42520A priority patent/US3081181A/en
Application filed by National Starch and Chemical Corp filed Critical National Starch and Chemical Corp
Priority to GB2757860A priority patent/GB900868A/en
Publication of GB900868A publication Critical patent/GB900868A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/30Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof by mixing gases into liquid compositions or plastisols, e.g. frothing with air
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61FFILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
    • A61F13/00Bandages or dressings; Absorbent pads
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61FFILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
    • A61F13/00Bandages or dressings; Absorbent pads
    • A61F13/15Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
    • A61F13/20Tampons, e.g. catamenial tampons; Accessories therefor
    • A61F13/2082Apparatus or processes of manufacturing
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61LMETHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L15/00Chemical aspects of, or use of materials for, bandages, dressings or absorbent pads
    • A61L15/16Bandages, dressings or absorbent pads for physiological fluids such as urine or blood, e.g. sanitary towels, tampons
    • A61L15/22Bandages, dressings or absorbent pads for physiological fluids such as urine or blood, e.g. sanitary towels, tampons containing macromolecular materials
    • A61L15/28Polysaccharides or their derivatives
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61LMETHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L15/00Chemical aspects of, or use of materials for, bandages, dressings or absorbent pads
    • A61L15/16Bandages, dressings or absorbent pads for physiological fluids such as urine or blood, e.g. sanitary towels, tampons
    • A61L15/42Use of materials characterised by their function or physical properties
    • A61L15/64Use of materials characterised by their function or physical properties specially adapted to be resorbable inside the body
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08BPOLYSACCHARIDES; DERIVATIVES THEREOF
    • C08B30/00Preparation of starch, degraded or non-chemically modified starch, amylose, or amylopectin
    • C08B30/20Amylose or amylopectin
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L3/00Compositions of starch, amylose or amylopectin or of their derivatives or degradation products
    • C08L3/12Amylose; Amylopectin; Degradation products thereof
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F9/00Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2303/00Characterised by the use of starch, amylose or amylopectin or of their derivatives or degradation products
    • C08J2303/12Amylose; Amylopectin; Degradation products thereof

Landscapes

  • Health & Medical Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Materials Engineering (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Veterinary Medicine (AREA)
  • Medicinal Chemistry (AREA)
  • Public Health (AREA)
  • Epidemiology (AREA)
  • Hematology (AREA)
  • Biomedical Technology (AREA)
  • Heart & Thoracic Surgery (AREA)
  • Vascular Medicine (AREA)
  • Biochemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • General Chemical & Material Sciences (AREA)
  • Textile Engineering (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
  • Polysaccharides And Polysaccharide Derivatives (AREA)

Abstract

An amylose sponge is obtained by foaming and gelling a dispersion of amylose. The term amylose includes a whole starch which is composed of at least 50% amylose or mixtures of whole starch with at least 50% of amylose. The sponges may be obtained by:- (1) Dispersing amylose in water containing 15 to 50% of an alkali such as an alkali metal hydroxide or a quaternary ammonium base, stabilizing with the addition of any alkali-resistant non-ionic, anionic or cationic surfactant such as "Pluronic" (Registered Trade Mark) F68, Tetronic 908, Igepal CO-880, sodium dodecyl benzene sulphonate and soap and then inflating by adding ammonium oxalate, ammonium gluconate, dibasic ammonium citrate, ammonium chloride, or dibasic ammonium phosphate, or by blowing in an inert gas such as nitrogen, or by the action of acetic acid or citric acid on a carbonate or bicarbonate. The sponges may be washed with distilled water and then with acetone, isopropanol, ethanol, or methanol and finally dried. The product can absorb 10 to 25 times its own weight of water. A plasticizer such as glycerol or diethylene or triethylene glycol may be applied in the form of a solution in ethanol or propanol by spraying into the dried gauze. (2) Dispersing the amylose in water in an autoclave or jet cooker at a temperature above 160 DEG C. and then stabilizing by adding formaldehyde and sodium carbonate solution optionally in the presence of a sodium phosphate buffer. The aerated, stabilized dispersion is cast to the desired shape and gelled by exposure to ammonia, sulphur dioxide or gaseous aliphatic amines. (3) Dispersing the amylose in water at a temperature above 160 DEG C., cooling to 95 DEG C., adding a foam stabilizer and then aerating by beating for 3-7 minutes. After casting into the desired size and shape the sponges are gelled by being allowed to cool for 2-3 hours at room temperature, or by being placed in a refrigerator for 30 minutes.
GB2757860A 1960-07-13 1960-08-09 Improvements in and relating to amylose sponges and gauze Expired GB900868A (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
NL122390D NL122390C (en) 1960-08-09
NL254963D NL254963A (en) 1960-08-09
US42520A US3081181A (en) 1960-07-13 1960-07-13 Amylose sponges and gauze
GB2757860A GB900868A (en) 1960-08-09 1960-08-09 Improvements in and relating to amylose sponges and gauze

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB2757860A GB900868A (en) 1960-08-09 1960-08-09 Improvements in and relating to amylose sponges and gauze

Publications (1)

Publication Number Publication Date
GB900868A true GB900868A (en) 1962-07-11

Family

ID=10261919

Family Applications (1)

Application Number Title Priority Date Filing Date
GB2757860A Expired GB900868A (en) 1960-07-13 1960-08-09 Improvements in and relating to amylose sponges and gauze

Country Status (2)

Country Link
GB (1) GB900868A (en)
NL (2) NL122390C (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3765419A (en) * 1971-05-14 1973-10-16 Int Paper Co Amylose acetate
US3799166A (en) * 1972-05-22 1974-03-26 A Marsan Starch type gel seals for ostomy patients
US4292972A (en) 1980-07-09 1981-10-06 E. R. Squibb & Sons, Inc. Lyophilized hydrocolloio foam
US5853050A (en) * 1997-05-07 1998-12-29 Rusmar Incorporated Composition and method for generating a foam barrier and methods of use thereof
US6261679B1 (en) 1998-05-22 2001-07-17 Kimberly-Clark Worldwide, Inc. Fibrous absorbent material and methods of making the same

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3765419A (en) * 1971-05-14 1973-10-16 Int Paper Co Amylose acetate
US3799166A (en) * 1972-05-22 1974-03-26 A Marsan Starch type gel seals for ostomy patients
US4292972A (en) 1980-07-09 1981-10-06 E. R. Squibb & Sons, Inc. Lyophilized hydrocolloio foam
US5853050A (en) * 1997-05-07 1998-12-29 Rusmar Incorporated Composition and method for generating a foam barrier and methods of use thereof
US6261679B1 (en) 1998-05-22 2001-07-17 Kimberly-Clark Worldwide, Inc. Fibrous absorbent material and methods of making the same
US6603054B2 (en) 1998-05-22 2003-08-05 Kimberly-Clark Worldwide, Inc. Fibrous absorbent material and methods of making the same

Also Published As

Publication number Publication date
NL254963A (en)
NL122390C (en)

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