GB900463A - Improvements in the refining of industrial hydrocarbon mixtures - Google Patents

Improvements in the refining of industrial hydrocarbon mixtures

Info

Publication number
GB900463A
GB900463A GB22170/59A GB2217059A GB900463A GB 900463 A GB900463 A GB 900463A GB 22170/59 A GB22170/59 A GB 22170/59A GB 2217059 A GB2217059 A GB 2217059A GB 900463 A GB900463 A GB 900463A
Authority
GB
United Kingdom
Prior art keywords
compounds
oxygen
cyclopentadienyl
chromium
mono
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB22170/59A
Inventor
Guenther Nottes
Hans Cordes
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Badische Anilin and Sodafabrik AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE, Badische Anilin and Sodafabrik AG filed Critical BASF SE
Publication of GB900463A publication Critical patent/GB900463A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G27/00—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation
    • C10G27/04—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation with oxygen or compounds generating oxygen
    • C10G27/10—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation with oxygen or compounds generating oxygen in the presence of metal-containing organic complexes, e.g. chelates, or cationic ion-exchange resins
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02B—INTERNAL-COMBUSTION PISTON ENGINES; COMBUSTION ENGINES IN GENERAL
    • F02B3/00—Engines characterised by air compression and subsequent fuel addition
    • F02B3/06—Engines characterised by air compression and subsequent fuel addition with compression ignition
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02B—INTERNAL-COMBUSTION PISTON ENGINES; COMBUSTION ENGINES IN GENERAL
    • F02B47/00—Methods of operating engines involving adding non-fuel substances or anti-knock agents to combustion air, fuel, or fuel-air mixtures of engines

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)

Abstract

Aromatic p -compounds of the formula Mea(R)x(CO)y, where Me is a group VIA, VIIA or VIII metal, a is from 1 to 4, R is a five or six membered aromatic p -system, x is from 1 to 5 and y is from 0 to 9, are used as catalysts in the refining of hydrocarbon mixtures with an oxygen-containing gas or oxygen-liberating compound which is soluble in hydrocarbons. Hydrocarbon mixtures specified are gasolines, Diesel oils, fuel oils and lubricating oils. The oxy-compound treatment may be used to effect oxidation of sulphur compounds or polymerization, condensation or resinification of nitrogen compounds, e.g. pyrrole, oxygen compounds, e.g. coumarone or indene, olefines and diolefines. The oxygen-containing gas or compound may be air or benzoyl, diacetyl, dilauroyl, dibenzoyl, di-p-toluoyl or di-t-butyl peroxide. Gasolines containing peroxides such as thermal reformates or cracking products which have stood in the air can also be used to provide the oxygen. In the catalyst Me may be manganese, nickel, iron, cobalt, molybdenum or chromium and R may be benzene, toluene, xylene, mesitylene, hexamethylbenzene, mono- or di-ethyl benzene, propylbenzene, diphenyl, polyphenyl methane or ethane, tetrahydrobenzene, anthracene, phenanthrene, pyrene, benzpyrene, coronene, cyclopentadienyl, phenyl- or mono- or di-methyl or ethyl-cyclopentadienyl or fluorene. The catalyst may be subsequently decomposed by heating or irradiation with light, e.g. from mercury vapour lamps. The refined product may be after-treated with active carbon or bleaching earths and filtration or distillation. In examples the catalysts used are dimesitylene chromium, dicyclopentadienyl nickel and cyclopentadienyl manganese tricarbonyl.ALSO:Aromatic p -compounds, MaRx(CO)y where M is a Group VIa, VIIa or VIII metal, a is 1 to 4, R is a five or six membered aromatic p system, x is 1 to 5 and y is 0 to 9 are used as catalysts in refining hydrocarbons (see Group III). M may be magnesia, nickel, iron, cobalt, molybdenum or chromium and R may be benzene; toluene; xylene; mesitylene; hexamethyl-, mono- or diethyl- or propyl-benzene; diphenyl; polyphenyl methane or ethane; tetrahydrobenzene; anthracene; phenanthrene; pyrene; benzpyrene; coronene; cyclopentadienyl; phenyl- or mono- or dimethyl- or ethylcyclopentadienyl; or fluorene. Specific compounds used in examples are dimesitylene chromium, dicylopentadienyl nickel and cyclopentadienyl manganese tricarbonyl of formulae: <FORM:0900463/IV (b)/1> <FORM:0900463/IV (b)/2> <FORM:0900463/IV (b)/3>
GB22170/59A 1958-07-03 1959-06-29 Improvements in the refining of industrial hydrocarbon mixtures Expired GB900463A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DEB49478A DE1105087B (en) 1958-07-03 1958-07-03 Process for refining technical hydrocarbon mixtures

Publications (1)

Publication Number Publication Date
GB900463A true GB900463A (en) 1962-07-04

Family

ID=6968889

Family Applications (1)

Application Number Title Priority Date Filing Date
GB22170/59A Expired GB900463A (en) 1958-07-03 1959-06-29 Improvements in the refining of industrial hydrocarbon mixtures

Country Status (4)

Country Link
US (1) US3053756A (en)
DE (1) DE1105087B (en)
FR (1) FR1229204A (en)
GB (1) GB900463A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20100173815A1 (en) * 2007-02-01 2010-07-08 Eiji Nagatomi Organic molybdenum compounds and lubricating compositions which contain said compounds

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3173860A (en) * 1961-12-20 1965-03-16 Universal Oil Prod Co Hydrorefining of crude oil and catalyst therefor
US3180822A (en) * 1961-12-20 1965-04-27 Universal Oil Prod Co Hydrorefining of crude oil and catalyst therefor
US3196104A (en) * 1962-07-02 1965-07-20 Universal Oil Prod Co Hydrorefining of crude oils
US3161584A (en) * 1962-07-02 1964-12-15 Universal Oil Prod Co Hydrorefining with decomposed organo-metallic catalyst
US3165463A (en) * 1962-07-02 1965-01-12 Universal Oil Prod Co Hydrorefining of crude oil and catalyst therefor
US3161585A (en) * 1962-07-02 1964-12-15 Universal Oil Prod Co Hydrorefining crude oils with colloidally dispersed catalyst
US3231488A (en) * 1963-10-28 1966-01-25 Universal Oil Prod Co Process for hydrorefining heavy hydrocarbon charge stocks and catalyst therefor
US3996130A (en) * 1974-01-03 1976-12-07 Nikolai Sergeevich Nametkin Method of purifying crude petroleum and primary refining products
DE2549690A1 (en) * 1975-11-05 1977-05-12 Nynaes Petroleum Ab Products from petroleum distillates and extracts - by air blowing followed by fractionation
FR2437243A1 (en) * 1978-09-29 1980-04-25 Inst Neftechimicheskogo Sintez Catalysts for purifying liq. and gas mixts. contg. mercaptan(s) - e.g. for treating petrochemical streams, convert mercaptan(s) into di:sulphide cpds.
US4507185A (en) * 1983-10-25 1985-03-26 University Of Georgia Research Foundation, Inc. Photogeneration of active formate decomposition catalysts from transition metal complexes containing manganese and the production of hydrogen
RU2163979C1 (en) * 1999-08-05 2001-03-10 Мишин Александр Иванович Method of complex treatment of diesel fuel and swirling apparatus used at treatment
US20020148754A1 (en) * 2001-02-08 2002-10-17 Gong William H. Integrated preparation of blending components for refinery transportation fuels
FR2877951B1 (en) 2004-11-17 2006-12-22 Inst Francais Du Petrole PROCESS FOR THE PROCESSING OF SATURATED SOFT COMPOUNDS OF A HYDROCARBON CUT CONTAINING LITTLE OR NO OLEFINS

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB449783A (en) * 1934-07-14 1936-07-03 Bataafsche Petroleum A process for refining light hydrocarbons containing mercaptans
US2659691A (en) * 1949-08-26 1953-11-17 Raffinage Cie Francaise Process for refining petroleum products
US2615831A (en) * 1949-12-08 1952-10-28 Socony Vacuum Oil Co Inc Desulfurization of hydrocarbon mixtures with nickel carbonyl
US2818416A (en) * 1952-12-10 1957-12-31 Ethyl Corp Cyclomatic compounds
US2756182A (en) * 1955-01-12 1956-07-24 Exxon Research Engineering Co Desulfurization of hydrocarbons with an iron group carbonyl impregnated on an adsorbent

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20100173815A1 (en) * 2007-02-01 2010-07-08 Eiji Nagatomi Organic molybdenum compounds and lubricating compositions which contain said compounds

Also Published As

Publication number Publication date
FR1229204A (en) 1960-09-05
DE1105087B (en) 1961-04-20
US3053756A (en) 1962-09-11

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