GB898111A - Improvements in or relating to thermosettable polyester resin compositions and their curing - Google Patents
Improvements in or relating to thermosettable polyester resin compositions and their curingInfo
- Publication number
- GB898111A GB898111A GB3626860A GB3626860A GB898111A GB 898111 A GB898111 A GB 898111A GB 3626860 A GB3626860 A GB 3626860A GB 3626860 A GB3626860 A GB 3626860A GB 898111 A GB898111 A GB 898111A
- Authority
- GB
- United Kingdom
- Prior art keywords
- glycol
- hydroperoxide
- compositions
- methyl
- stabilizers
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000203 mixture Substances 0.000 title abstract 5
- 229920001225 polyester resin Polymers 0.000 title 1
- 239000004645 polyester resin Substances 0.000 title 1
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 abstract 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 abstract 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 abstract 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 abstract 3
- -1 lithium halides Chemical class 0.000 abstract 3
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 abstract 2
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 abstract 2
- HGINCPLSRVDWNT-UHFFFAOYSA-N Acrolein Chemical compound C=CC=O HGINCPLSRVDWNT-UHFFFAOYSA-N 0.000 abstract 2
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 abstract 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 abstract 2
- 239000002253 acid Substances 0.000 abstract 2
- KWGKDLIKAYFUFQ-UHFFFAOYSA-M lithium chloride Chemical group [Li+].[Cl-] KWGKDLIKAYFUFQ-UHFFFAOYSA-M 0.000 abstract 2
- YPFDHNVEDLHUCE-UHFFFAOYSA-N propane-1,3-diol Chemical compound OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 abstract 2
- 239000003381 stabilizer Substances 0.000 abstract 2
- BJELTSYBAHKXRW-UHFFFAOYSA-N 2,4,6-triallyloxy-1,3,5-triazine Chemical compound C=CCOC1=NC(OCC=C)=NC(OCC=C)=N1 BJELTSYBAHKXRW-UHFFFAOYSA-N 0.000 abstract 1
- FRIBMENBGGCKPD-UHFFFAOYSA-N 3-(2,3-dimethoxyphenyl)prop-2-enal Chemical compound COC1=CC=CC(C=CC=O)=C1OC FRIBMENBGGCKPD-UHFFFAOYSA-N 0.000 abstract 1
- JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical compound CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 abstract 1
- KNDQHSIWLOJIGP-UHFFFAOYSA-N 826-62-0 Chemical compound C1C2C3C(=O)OC(=O)C3C1C=C2 KNDQHSIWLOJIGP-UHFFFAOYSA-N 0.000 abstract 1
- MGYMHQJELJYRQS-UHFFFAOYSA-N Ascaridole Chemical compound C1CC2(C)OOC1(C(C)C)C=C2 MGYMHQJELJYRQS-UHFFFAOYSA-N 0.000 abstract 1
- 239000004342 Benzoyl peroxide Substances 0.000 abstract 1
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 abstract 1
- FBPFZTCFMRRESA-KVTDHHQDSA-N D-Mannitol Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-KVTDHHQDSA-N 0.000 abstract 1
- 239000004641 Diallyl-phthalate Substances 0.000 abstract 1
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 abstract 1
- 229930195725 Mannitol Natural products 0.000 abstract 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 abstract 1
- 150000007513 acids Chemical class 0.000 abstract 1
- 150000001279 adipic acids Chemical class 0.000 abstract 1
- 150000001298 alcohols Chemical class 0.000 abstract 1
- 239000010425 asbestos Substances 0.000 abstract 1
- MGYMHQJELJYRQS-ZJUUUORDSA-N ascaridole Natural products C1C[C@]2(C)OO[C@@]1(C(C)C)C=C2 MGYMHQJELJYRQS-ZJUUUORDSA-N 0.000 abstract 1
- 235000019400 benzoyl peroxide Nutrition 0.000 abstract 1
- QUDWYFHPNIMBFC-UHFFFAOYSA-N bis(prop-2-enyl) benzene-1,2-dicarboxylate Chemical compound C=CCOC(=O)C1=CC=CC=C1C(=O)OCC=C QUDWYFHPNIMBFC-UHFFFAOYSA-N 0.000 abstract 1
- MHWARLQBKUPZMN-UHFFFAOYSA-N butylbenzene;hydrogen peroxide Chemical compound OO.CCCCC1=CC=CC=C1 MHWARLQBKUPZMN-UHFFFAOYSA-N 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 229940120693 copper naphthenate Drugs 0.000 abstract 1
- SEVNKWFHTNVOLD-UHFFFAOYSA-L copper;3-(4-ethylcyclohexyl)propanoate;3-(3-ethylcyclopentyl)propanoate Chemical compound [Cu+2].CCC1CCC(CCC([O-])=O)C1.CCC1CCC(CCC([O-])=O)CC1 SEVNKWFHTNVOLD-UHFFFAOYSA-L 0.000 abstract 1
- 229930007927 cymene Natural products 0.000 abstract 1
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 abstract 1
- 239000000945 filler Substances 0.000 abstract 1
- 239000011521 glass Substances 0.000 abstract 1
- 150000004820 halides Chemical class 0.000 abstract 1
- RKDCQJSOERZJQM-UHFFFAOYSA-N hydrogen peroxide 1-methyl-1,2,3,4-tetrahydronaphthalene Chemical compound OO.C1=CC=C2C(C)CCCC2=C1 RKDCQJSOERZJQM-UHFFFAOYSA-N 0.000 abstract 1
- 238000010030 laminating Methods 0.000 abstract 1
- 229910052744 lithium Inorganic materials 0.000 abstract 1
- 239000000594 mannitol Substances 0.000 abstract 1
- 235000010355 mannitol Nutrition 0.000 abstract 1
- 239000000178 monomer Substances 0.000 abstract 1
- 238000000465 moulding Methods 0.000 abstract 1
- HFPZCAJZSCWRBC-UHFFFAOYSA-N p-cymene Chemical compound CC(C)C1=CC=C(C)C=C1 HFPZCAJZSCWRBC-UHFFFAOYSA-N 0.000 abstract 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 abstract 1
- 239000000049 pigment Substances 0.000 abstract 1
- 229920000728 polyester Polymers 0.000 abstract 1
- HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 abstract 1
- 229910052895 riebeckite Inorganic materials 0.000 abstract 1
- 150000003330 sebacic acids Chemical class 0.000 abstract 1
- CIHOLLKRGTVIJN-UHFFFAOYSA-N tert‐butyl hydroperoxide Chemical compound CC(C)(C)OO CIHOLLKRGTVIJN-UHFFFAOYSA-N 0.000 abstract 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 abstract 1
- 229920006337 unsaturated polyester resin Polymers 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/16—Halogen-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
- C08F283/01—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to unsaturated polyesters
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Macromonomer-Based Addition Polymer (AREA)
Abstract
Polymerizable compositions comprise unsaturated polyester resins having acid numbers not greater than 100 and lithium halides as stabilizers or promoters. The compositions may also comprise copolymerizable monomers, e.g. styrene, p-methyl styrene, vinyl toluene, divinyl benzene, methyl acrylate, methyl methacrylate, acrolein, diallyl phthalate, triallyl cyanurate and the diallyl ester of endomethylene tetrahydrophthalic anhydride; catalysts, e.g. benzoyl peroxide, tertiary butylhydroperoxide, cyclohexanol peroxide, ascaridol, cumene hydroperoxide, cymene hydroperoxide, sec. butyl benzene hydroperoxide and 1-methyl tetralin hydroperoxide; and copper naphthenate. The preferred halide is lithium chloride. The polyester may be derived from maleic, fumaric, glutaconic, itaconic, mesaconic, citraconic, allyl malonic, allyl succinic and xeronic acids, optionally together with phthalic, isophthalic, tetrachlorophthalic, hexachloroendomethylene tetrahydrophthalic, adipic and sebacic acids; and from ethylene glycol, diethylene glycol, triethylene glycol, trimethylene glycol, propylene glycol, dipropylene glycol and small amounts of higher polyhydric p alcohols such as glycerol, pentaerythritol and mannitol. Glass and asbestos fibres and conventional fillers, stabilizers and pigments may also be added and the compositions used for moulding, laminating and extruding. Products such as button blanks and corrugated panels may be cut or stamped from the semi-cured compositions and postcured at elevated temperatures.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US84789459A | 1959-10-22 | 1959-10-22 | |
| US847906A US3061580A (en) | 1959-10-22 | 1959-10-22 | Unsaturated polyester resins containing a lithium halide as stabilizer and method ofmaking |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB898111A true GB898111A (en) | 1962-06-06 |
Family
ID=27126736
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB3626860A Expired GB898111A (en) | 1959-10-22 | 1960-10-21 | Improvements in or relating to thermosettable polyester resin compositions and their curing |
Country Status (2)
| Country | Link |
|---|---|
| DE (1) | DE1174978B (en) |
| GB (1) | GB898111A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1705215A1 (en) * | 2005-03-23 | 2006-09-27 | DSM IP Assets B.V. | Gel time drift-free resin compositions |
| EP3208316A1 (en) * | 2016-02-22 | 2017-08-23 | Immo de Moor N.V. | Vehicle body filler comprising an unsaturated polyester resin |
| CN118562065A (en) * | 2024-07-31 | 2024-08-30 | 浙江伟星实业发展股份有限公司 | Low-VOC and low-MEK polyester resin button and manufacturing process thereof |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL98509C (en) * | 1956-05-07 |
-
1960
- 1960-10-21 GB GB3626860A patent/GB898111A/en not_active Expired
- 1960-10-22 DE DE1960A0035866 patent/DE1174978B/en active Pending
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1705215A1 (en) * | 2005-03-23 | 2006-09-27 | DSM IP Assets B.V. | Gel time drift-free resin compositions |
| WO2006100122A1 (en) * | 2005-03-23 | 2006-09-28 | Dsm Ip Assets B.V. | Gel time drift-free resin compositions |
| EP3208316A1 (en) * | 2016-02-22 | 2017-08-23 | Immo de Moor N.V. | Vehicle body filler comprising an unsaturated polyester resin |
| CN118562065A (en) * | 2024-07-31 | 2024-08-30 | 浙江伟星实业发展股份有限公司 | Low-VOC and low-MEK polyester resin button and manufacturing process thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| DE1174978B (en) | 1964-07-30 |
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