GB897697A - Improvements in and relating to the production of copolymeric products - Google Patents

Improvements in and relating to the production of copolymeric products

Info

Publication number
GB897697A
GB897697A GB519358A GB519358A GB897697A GB 897697 A GB897697 A GB 897697A GB 519358 A GB519358 A GB 519358A GB 519358 A GB519358 A GB 519358A GB 897697 A GB897697 A GB 897697A
Authority
GB
United Kingdom
Prior art keywords
acrylonitrile
preferred
alcohol
mixture
volumes
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB519358A
Inventor
Albert Stanley Carpenter
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Akzo Nobel UK PLC
Original Assignee
Courtaulds PLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Courtaulds PLC filed Critical Courtaulds PLC
Priority to GB519358A priority Critical patent/GB897697A/en
Publication of GB897697A publication Critical patent/GB897697A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F214/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F214/02Monomers containing chlorine
    • C08F214/04Monomers containing two carbon atoms
    • C08F214/08Vinylidene chloride
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/42Nitriles
    • C08F220/44Acrylonitrile

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Artificial Filaments (AREA)
  • Polymerisation Methods In General (AREA)
  • Polymerization Catalysts (AREA)

Abstract

A mixture of acrylonitrile and vinylidene chloride are polymerized in the presence of a polymerization initiator and a mixture of water and an aliphatic alcohol containing not more than three carbon atoms, the amount of acrylonitrile being chosen so as to give a copolymer precipitate containing a major proportion of acrylonitrile. A redox initiator, e.g. ammonium sulphate plus potassium bisulphite is preferred, while ethanol is the preferred alcohol. Mixtures of 25 to 45 volumes water with 75 to 55 volumes alcohol are preferred. The copolymers are soluble in acetone to form solutions which may be wet or dry spun to form threads. Specifications 569,182 and 643,198 are referred to.
GB519358A 1958-02-18 1958-02-18 Improvements in and relating to the production of copolymeric products Expired GB897697A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB519358A GB897697A (en) 1958-02-18 1958-02-18 Improvements in and relating to the production of copolymeric products

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB519358A GB897697A (en) 1958-02-18 1958-02-18 Improvements in and relating to the production of copolymeric products

Publications (1)

Publication Number Publication Date
GB897697A true GB897697A (en) 1962-05-30

Family

ID=9791462

Family Applications (1)

Application Number Title Priority Date Filing Date
GB519358A Expired GB897697A (en) 1958-02-18 1958-02-18 Improvements in and relating to the production of copolymeric products

Country Status (1)

Country Link
GB (1) GB897697A (en)

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