GB891848A - Process and composition for the printing and dyeing of textiles - Google Patents

Process and composition for the printing and dyeing of textiles

Info

Publication number
GB891848A
GB891848A GB4744/60A GB474460A GB891848A GB 891848 A GB891848 A GB 891848A GB 4744/60 A GB4744/60 A GB 4744/60A GB 474460 A GB474460 A GB 474460A GB 891848 A GB891848 A GB 891848A
Authority
GB
United Kingdom
Prior art keywords
vinyl
urea
methacrylamide
butadiene
styrene
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB4744/60A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bayer AG
Original Assignee
Bayer AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bayer AG filed Critical Bayer AG
Publication of GB891848A publication Critical patent/GB891848A/en
Expired legal-status Critical Current

Links

Classifications

    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Inks, Pencil-Leads, Or Crayons (AREA)
  • Coloring (AREA)

Abstract

A printing paste or dyeing liquor contains polymeric film former, titanium dioxide and a polymethylene urea of the general formula <FORM:0891848/IV (a)/1> wherein R and R1 stand for hydrogen or methylol or methylol ether groups and n and m are whole numbers, n+m being at least 4. The polymethylene ureas are obtained from urea and formaldehyde or mono- or dimethylol ureas by strongly acid condensation, preferably at pH values of 1 to 2. As film formers there are mentioned copolymerization products of, for example, acrylic acid esters, methacrylamide, styrene, vinyl chloride, vinylidene chloride, vinyl esters, butadiene and isoprene and also of methacrylamide-methylol methyl ether and butadiene, butyl acrylate, styrene and acrylonitrile. Other suitable film formers are polyethylene dispersions, polyurethanes, latices containing polyvinyl acetals, vinyl polymerizates having incorporated copolymerizates of vinyl oxethyl urea, 1,2-vinyl oxypropyl-2-imidazolidone and copolymerizates of vinyl compounds and glycidyl esters, acrylic acid and methacrylic acid. As cross-linking agents the compositions may contain latices with carboxylic groups, water soluble compounds of aldehydes with amines, aminotriazines or ureas, or reaction products of polymethylol ureas and hydroxyethylated polyfunctional alcohols. Printing pastes may also contain hydrophobing agents, plasticizers and thickeners, such as tragacanth, starch, cellulose ether, polyvinyl alcohol, polyacrylamide and the ammonium salt of polyacrylic acid. The pastes may be applied as emulsions. Carbon black and copper phthalocyanine are suitable as additional pigments. In examples, pastes are prepared of (1) titanium dioxide; a compound of the above formula in which R=H, R1=-CH2OH, n=8 to 12 and m is 1 to 2; glycol; an aqueous co-polymerization product of butadiene, butyl acrylate, styrene, acrylonitrile and methacrylamide; an aqueous solution of a trimethylol urea-hexanetriol-butane dihydroxyethyl-glycol polyether; aqueous methyl cellulose and ammonium chloride. After printing the paste is fixed at 100 DEG -150 DEG C.; (2) titanium dioxide and a polymethylene urea (I) where R and R1 = H, n=7 to 13 and m=0 to 1, ethylene glycol, a butadiene/acrylonitrile/styrene/methacrylamidemethylol methyl ether copolymer latex, a trimethylol urea-hexanetriol-butane-dihydroxyethyl glycol polyether modified by condensation with hexamethylol melamine and hexanetriol, methyl cellulose and aqueous ammonium chloride. Other ingredients specified are dyes and pigments; compounds of the general formula I where R is H, R1 is H or CH2OH, n is 8-12 or 12 to 20, and m is 1-2, 0-3; copolymerization products of as dichlorethene, butyl acrylate and methacrylamide or of butadiene, butyl acrylate, styrene, acrylonitrile and methacrylamide(30:30:30:6:2). Specifications 620,791, 669,739, 729,122, 769,255, 769,271, 774,101, 784,946, 804,738, 872,525 and 872,526 are referred to.ALSO:A printing paste or dyeing liquor contains a polymeric film former, titanium dioxide and a polymethylene urea of the general formula <FORM:0891848/IV (c)/1> wherein R and R1 stand for hydrogen or methylol or methylol ether groups and n and m are whole numbers, n+m being at least 4. The polymethylene ureas are obtained from urea and formaldehyde or mono- or dimethylol ureas by strongly acid condensation, preferably at pH values of 1 to 2. As film formers there are mentioned copolymerisation products of, for example, acrylic acid esters, methacrylamide, styrene, vinyl chloride, vinylidene chloride, vinyl esters, butadiene and isoprene and also of methacrylamide-methylol methyl ether and butadiene, butyl acrylate, styrene and acrylonitrile. Other suitable film formers are polyethylene dispersions, polyurethanes, latices containing polyvinyl acetals, vinyl polymerizates having incorporated copolymerizates of vinyl oxethyl urea, 1,2-vinyl oxypropyl-2-imidazolidone and copolymerizates of vinyl compounds and glycidyl esters, acrylic acid and methacrylic acid. As cross-linking agents the compositions may contain latices with carboxylic groups, water soluble compounds of aldehydes with amines, aminotriazines or ureas, or reaction products of polymethylol ureas and hydroxyethylated polyfunctional alcohols. Printing pastes may also contain hydrophobing agents, plasticizers and thickeners, such as tragacanth, starch, cellulose ether, polyvinyl alcohol, polyacrylamide and the ammonium salt of polyacrylic acid. The pastes may be applied as emulsions. Carbon black and copper phthalocyanine are suitable as additional pigments. In examples, pastes are prepared of (1) titanium dioxide; a compound of the above formula in which R=H, R1= -CH2OH, n=8 to 12 and m is 1 to 2; glycol; an aqueous co-polymerization product of butadiene, butyl acrylate, styrene, acrylonitrile and methacrylamide; an aqueous solution of a trimethylol urea-hexanetriol-butane dihydroxyethylglycol polyether; aqueous methyl cellulose and ammonium chloride. After printing the paste is fixed at 100 DEG C.-150 DEG C.; (2) titanium dioxide and a polymethylene urea (I) where R and R1=H, n=7 to 13 and m=0-1, ethylene glycol, a butadiene / acrylonitrile / styrene / methacryl - amide-methylol methyl ether copolymer latex, a trimethylol urea-hexanetriol-butane-dihydroxyethyl glycol polyether modified by condensation with hexamethylol melamine and hexanetriol, methyl cellulose and aqueous ammonium chloride. Other ingredients specified are dyes and pigments; compounds of the general formula I where R is H, R1 is H or CH2OH, n is 8-12 or 12 to 20, and m is 1-2, 0-3; copolymerization products of as dichlorethene, butyl acrylate and methacrylamide or of butadiene, butyl acrylate, styrene, acrylonitrile and methacrylamide (30 : 30 : 30 : 6 : 2). Specifications 620,791, 669, 739, 729,122, 769,255, 769,271, 774,101, 784,946, 804,738, 872,525 and 872,526 are referred to.
GB4744/60A 1959-02-24 1960-02-10 Process and composition for the printing and dyeing of textiles Expired GB891848A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE891848X 1959-02-24

Publications (1)

Publication Number Publication Date
GB891848A true GB891848A (en) 1962-03-21

Family

ID=6846052

Family Applications (1)

Application Number Title Priority Date Filing Date
GB4744/60A Expired GB891848A (en) 1959-02-24 1960-02-10 Process and composition for the printing and dyeing of textiles

Country Status (1)

Country Link
GB (1) GB891848A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110904701A (en) * 2019-12-17 2020-03-24 辽宁恒星精细化工有限公司 Printing paste for polyvinyl chloride material handicraft leaves and preparation method thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110904701A (en) * 2019-12-17 2020-03-24 辽宁恒星精细化工有限公司 Printing paste for polyvinyl chloride material handicraft leaves and preparation method thereof
CN110904701B (en) * 2019-12-17 2022-02-01 辽宁恒星精细化工有限公司 Printing paste for polyvinyl chloride material handicraft leaves and preparation method thereof

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