GB915420A - Improvements in and relating to the fixation of pigments and the simultaneous application of antistatic coatings to fibrous materials and foils - Google Patents

Improvements in and relating to the fixation of pigments and the simultaneous application of antistatic coatings to fibrous materials and foils

Info

Publication number
GB915420A
GB915420A GB2925959A GB2925959A GB915420A GB 915420 A GB915420 A GB 915420A GB 2925959 A GB2925959 A GB 2925959A GB 2925959 A GB2925959 A GB 2925959A GB 915420 A GB915420 A GB 915420A
Authority
GB
United Kingdom
Prior art keywords
condensation product
chloride
formaldehyde
polyethylene glycol
foils
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB2925959A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hoechst AG
Original Assignee
Hoechst AG
Farbwerke Hoechst AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hoechst AG, Farbwerke Hoechst AG filed Critical Hoechst AG
Publication of GB915420A publication Critical patent/GB915420A/en
Expired legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/39—Aldehyde resins; Ketone resins; Polyacetals
    • D06M15/423—Amino-aldehyde resins
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/325—Amines
    • D06M13/332—Di- or polyamines
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/402—Amides imides, sulfamic acids
    • D06M13/432—Urea, thiourea or derivatives thereof, e.g. biurets; Urea-inclusion compounds; Dicyanamides; Carbodiimides; Guanidines, e.g. dicyandiamides
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders

Abstract

A method of fixing an inorganic or organic colouring or matting pigment on fibrous materials or foils and for imparting an p antistatic finish thereto comprises treating the material with a padding liquor or printing paste containing the pigment and a water-soluble condensation product of formaldehyde, ethylene oxide or a compound containing polyethylene glycol radicals and melamine or an aliphatic bis-urea of the general formula <FORM:0915420/IV(a)/1> in which n is zero or an integer from 1 to 3, R represents a lower alkylene radical and R1 represents a hydrogen atom or a lower alkyl radical, which condensation product contains from 50 to about 97% by weight of polyethylene glycol radicals, and heating the materials thus treated to harden the condensation product. To the paste or liquor there may be added one or more of: a dispersion of an artificial resin, a plasticizer, a hardening catalyst, a wetting agent, a dispersing agent or a thickening agent. The artificial resin may be a homo- or copolymer based on one or more of the monomers: a vinyl ester, an acrylic ester, vinyl chloride, vinylidene chloride, styrene, butyladiene, acrylonitrile, and isobutylene, or may be a polyvinyl acetal derived from a polyvinyl alcohol and an aldehyde in the presence of an acid condensation catalyst and, if desired, a dispersing agent, the acetalation and dispersion being carried out in a single operation (as in Specification 895,428). Specified additives include reaction products of ethylene oxide with fatty acids, fatty alcohols, fatty acid amides or alkylnaphthols; alginates; mucilages; locust bean flour; dextrine; cellulose ether carboxylic acid; white spirit emulsions; and, as catalysts, ammonium nitrate or chloride. In examples the condensates are obtained by reacting (1) polyethylene glycol dibenzene sulphonyl ester with bis-(ureido-propyl)-methylamine and condensing the quaternary product with formaldehyde; (2) hydroxyethylated triethanolamine, formaldehyde, melamine and sulphuric acid, followed by methylation with methyl sulphate; (6) melamine and the reaction product of formaldehyde with hydroxyethylated triethanolamine which has been methylated with dimethyl sulphate. Artificial resins mentioned, in addition to those of Specification 895,428, are copolymers of (5) butadiene and acrylonitrile, (7) ethyl acrylate, vinyl isobutyl ether, styrene and acrylic acid, and also polyvinyl acetal. Specification 818,844 also is referred to.ALSO:A method of fixing an inorganic or organic colouring or matting pigment on fibrous materials or foils and for imparting an antistatic finish thereto comprises treating the material with a padding liquor or printing paste containing the pigment and a watersoluble condensation product of formaldehyde, ethylene oxide or a compound containing polyethylene glycol radicals and melamine or an aliphatic bis-urea of the general formula <FORM:0915420/IV (b)/1> in which n is zero or an integer from 1 to 3, R represents a lower alkylene radical and R1 represents a hydrogen atom or a lower alkyl radical, which condensation product contains from 50 to 97% by weight of polyethylene glycol radicals, and heating the material thus treated to harden the condensation product. To the paste or liquor there may be added one or more of: a dispersion of an artificial resin, a plasticizer, a hardening catalyst, a wetting agent, a dispersing agent or a thickening agent. The artificial resin may be a homoor copolymer based on one or more of the monomers: a vinyl ester, an acrylic ester, vinyl chloride, vinylidene chloride, styrene, butadiene, acrylonitrile and isobutylene or may be a polyvinyl acetal prepared as described in Specification 895,428. Specified additives include reaction products of ethylene oxide with fatty acids, fatty alcohols, fatty acid amides or alkyl-naphthols; alginates; mucilages; locust bean flour; dextrine; cellulose ether carboxylic acid; white spirit emulsions; and, as catalysts, ammonium nitrate or chloride. The materials to be treated may be foils, fibres or textile materials made therefrom, such as natural or regenerated cellulose, polyacrylonitrile, polyvinyl chloride, superpolyamides, polyolefins, polyesters, glass or asbestos fibres, shaped structures of acetyl cellulose or artificial leather. Artificial resins mentioned, in addition to those of Specification 895,428, are copolymers of (5) butadiene and acrylonitrile, (7) ethyl acrylate, vinyl isobutyl ether, styrene and acrylic acid; and also polyvinyl acetal. Specification 818,844 also is referred to.
GB2925959A 1958-08-26 1959-08-26 Improvements in and relating to the fixation of pigments and the simultaneous application of antistatic coatings to fibrous materials and foils Expired GB915420A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DEF0026486 1958-08-26

Publications (1)

Publication Number Publication Date
GB915420A true GB915420A (en) 1963-01-09

Family

ID=7092046

Family Applications (1)

Application Number Title Priority Date Filing Date
GB2925959A Expired GB915420A (en) 1958-08-26 1959-08-26 Improvements in and relating to the fixation of pigments and the simultaneous application of antistatic coatings to fibrous materials and foils

Country Status (4)

Country Link
BE (1) BE582030A (en)
CH (1) CH366025A (en)
FR (1) FR1233931A (en)
GB (1) GB915420A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2133025A (en) * 1982-12-31 1984-07-18 Nippon Paint Co Ltd Polymers and pigment-in-polymer dispersions
CN103726369A (en) * 2013-11-08 2014-04-16 绍兴鼎翔纺织品贸易有限公司 Cationic fixing agent emulsion and preparation method thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2133025A (en) * 1982-12-31 1984-07-18 Nippon Paint Co Ltd Polymers and pigment-in-polymer dispersions
CN103726369A (en) * 2013-11-08 2014-04-16 绍兴鼎翔纺织品贸易有限公司 Cationic fixing agent emulsion and preparation method thereof

Also Published As

Publication number Publication date
CH7698159A4 (en) 1962-08-15
BE582030A (en)
FR1233931A (en) 1960-10-13
CH366025A (en) 1963-01-31

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