GB879950A - Polyether-polyacid products and method therefor - Google Patents

Polyether-polyacid products and method therefor

Info

Publication number
GB879950A
GB879950A GB1018358A GB1018358A GB879950A GB 879950 A GB879950 A GB 879950A GB 1018358 A GB1018358 A GB 1018358A GB 1018358 A GB1018358 A GB 1018358A GB 879950 A GB879950 A GB 879950A
Authority
GB
United Kingdom
Prior art keywords
products
oxides
average
polyether
polyacid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB1018358A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Union Carbide Corp
Original Assignee
Union Carbide Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Union Carbide Corp filed Critical Union Carbide Corp
Publication of GB879950A publication Critical patent/GB879950A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/02—Homopolymers or copolymers of acids; Metal or ammonium salts thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/66—Polyesters containing oxygen in the form of ether groups
    • C08G63/668—Polyesters containing oxygen in the form of ether groups derived from polycarboxylic acids and polyhydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G81/00—Macromolecular compounds obtained by interreacting polymers in the absence of monomers, e.g. block polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G81/00—Macromolecular compounds obtained by interreacting polymers in the absence of monomers, e.g. block polymers
    • C08G81/02—Macromolecular compounds obtained by interreacting polymers in the absence of monomers, e.g. block polymers at least one of the polymers being obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • C08G81/024—Block or graft polymers containing sequences of polymers of C08C or C08F and of polymers of C08G
    • C08G81/025—Block or graft polymers containing sequences of polymers of C08C or C08F and of polymers of C08G containing polyether sequences
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L35/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical, and containing at least one other carboxyl radical in the molecule, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L71/00—Compositions of polyethers obtained by reactions forming an ether link in the main chain; Compositions of derivatives of such polymers
    • C08L71/02—Polyalkylene oxides

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polyethers (AREA)
  • Phenolic Resins Or Amino Resins (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

Water-insoluble polyether-polyacid products which contain no neutralized carboxylic acid groups are made by mixing from 7%-97% by weight of an organic acid polymer containing an average of at least 10 carboxylic acid groups, and no neutralized groups, in the polymer molecule and having an average of at least 1 carboxyl group for each 6 carbon atoms of the polymer excluding the carboxyl carbon atom, and from 93%-3% by weight of a polyether containing an average of at least 7 non-cyclic aliphatic ether linkages in the molecule and having, on the average, a ratio of etheric oxygen atoms to carbon atoms of at least 1-6, and if necessary baking the product so obtained at a temperature in the range of 150 DEG -225 DEG C. to render it water-insoluble. Polymeric acids specified are homopolymers of acrylic and methacrylic acids and copolymers of such acids with maleic acid, styrene, vinyl toluene, isobutylene, vinyl chloride and vinyl benzoate. Polyethers specified are polyethylene and polypropylene oxides and ethers thereof with alcohols, glycols, glycerol, sorbitol and phenols, copolymers of ethylene and propylene oxides with each other and with other olefine oxides such as epoxybutanes, isobutylene oxide and styrene oxide, polytrimethylene and polytetramethylene oxides, polyethers made by reacting olefine oxides with Novolaks, polyvinyl alcohol, starch, sucrose and methyl glucoside, polyethylene glycol chloride, polyethylene triol and polyvinyl methyl ether. The products may be made by direct mixing of the polyether and polyacid, but the mixing is preferably carried out in aqueous solution from which precipitation of the product may be inhibited by the addition of ammonia, amino compounds, e.g. N, N, N1, N1-tetrakis (2-hydroxypropyl) ethylene diamine, alkalies, hydrazine or solvents such as acetone, a mono-lower alkyl ether of an alkylene glycol, dioxane, diacetone alcohol, ethanol, dimethyl sulphoxide, acetic acid and acrylic acid. The precipitation of the products from such solutions may be effected by appropriate treatment, e.g. heating, acidification or, in the case of solutions containing acetone, treatment with ferric chloride. The products are used in the production of films and coating which possess resistance to solvents and water.
GB1018358A 1957-04-02 1958-03-31 Polyether-polyacid products and method therefor Expired GB879950A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US65009257A 1957-04-02 1957-04-02

Publications (1)

Publication Number Publication Date
GB879950A true GB879950A (en) 1961-10-11

Family

ID=24607423

Family Applications (1)

Application Number Title Priority Date Filing Date
GB1018358A Expired GB879950A (en) 1957-04-02 1958-03-31 Polyether-polyacid products and method therefor

Country Status (6)

Country Link
BE (1) BE571756A (en)
CH (1) CH392068A (en)
DE (1) DE1100950B (en)
FR (1) FR1204449A (en)
GB (1) GB879950A (en)
NL (2) NL111374C (en)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0187391A2 (en) * 1985-01-04 1986-07-16 Ernst Prof. Dr. Bayer Graft polymers from cross-linked polymers and polyoxyethylene, their preparation and use
US5278303A (en) * 1992-06-12 1994-01-11 University Of Toronto Innovations Foundation Polymer-supported solution synthesis of oligosaccharides
WO1995009821A2 (en) * 1993-09-29 1995-04-13 W.R. Grace & Co.-Conn. Improved cement admixture product having improved rheological properties and process of forming same
US5616698A (en) * 1994-01-10 1997-04-01 University Of Toronto Innovations Foundation Polymer-supported solution synthesis of oligosaccharides
WO1999047468A1 (en) * 1998-03-19 1999-09-23 Lafarge S.A. Water soluble or water dispersible dispersing agent for cement compositions and mineral particle aqueous suspension, and additives containing such dispersing agent
WO2000035961A1 (en) * 1998-12-14 2000-06-22 Rhodia Inc. Polymers which exhibit thermothickening properties and process making same

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1149895B (en) * 1961-04-10 1963-06-06 Engis Equipment Company Polymeric ether as a carrier for gemstone particles in grinding pastes
CH1424174A4 (en) * 1974-10-24 1975-11-28
US4788122A (en) * 1985-03-14 1988-11-29 Kao Corporation Production of polyester and elecrophotographic toner containing the same
DE3522078A1 (en) * 1985-06-20 1987-01-02 Fraunhofer Ges Forschung GEL WITH TEMPERATURE-DEPENDENT LIGHT TRANSMISSION, METHOD FOR THE PRODUCTION THEREOF AND ITS USE
US4743244A (en) * 1985-06-28 1988-05-10 Arco Chemical Company Water absorbing polymer compositions and articles prepared therefrom
IT1270705B (en) * 1994-11-17 1997-05-07 3V Sigma Spa THICKENING COMPOSITIONS.

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1144274A (en) * 1955-02-17 1957-10-11 Us Rubber Co Synthetic resin enhancements

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0187391A2 (en) * 1985-01-04 1986-07-16 Ernst Prof. Dr. Bayer Graft polymers from cross-linked polymers and polyoxyethylene, their preparation and use
EP0187391A3 (en) * 1985-01-04 1989-01-04 Ernst Prof. Dr. Bayer Graft polymers from cross-linked polymers and polyoxyethylene, their preparation and use
US5278303A (en) * 1992-06-12 1994-01-11 University Of Toronto Innovations Foundation Polymer-supported solution synthesis of oligosaccharides
WO1995009821A2 (en) * 1993-09-29 1995-04-13 W.R. Grace & Co.-Conn. Improved cement admixture product having improved rheological properties and process of forming same
WO1995009821A3 (en) * 1993-09-29 1995-05-04 Grace W R & Co Improved cement admixture product having improved rheological properties and process of forming same
US5728207A (en) * 1993-09-29 1998-03-17 W.R. Grace & Co.-Conn. Cement admixture product having improved rheological properties and process of forming same
US5616698A (en) * 1994-01-10 1997-04-01 University Of Toronto Innovations Foundation Polymer-supported solution synthesis of oligosaccharides
WO1999047468A1 (en) * 1998-03-19 1999-09-23 Lafarge S.A. Water soluble or water dispersible dispersing agent for cement compositions and mineral particle aqueous suspension, and additives containing such dispersing agent
FR2776285A1 (en) * 1998-03-19 1999-09-24 Chryso A water soluble or water dispersible dispersing agent
WO2000035961A1 (en) * 1998-12-14 2000-06-22 Rhodia Inc. Polymers which exhibit thermothickening properties and process making same

Also Published As

Publication number Publication date
CH392068A (en) 1965-05-15
BE571756A (en)
NL226509A (en)
DE1100950B (en) 1961-03-02
FR1204449A (en) 1960-01-26
NL111374C (en)

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