GB878363A - Improvements relating to non-actinic preparations for the human skin - Google Patents
Improvements relating to non-actinic preparations for the human skinInfo
- Publication number
- GB878363A GB878363A GB41863/59A GB4186359A GB878363A GB 878363 A GB878363 A GB 878363A GB 41863/59 A GB41863/59 A GB 41863/59A GB 4186359 A GB4186359 A GB 4186359A GB 878363 A GB878363 A GB 878363A
- Authority
- GB
- United Kingdom
- Prior art keywords
- benztriazole
- methylphenyl
- groups
- acetoxy
- methoxy
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000002360 preparation method Methods 0.000 title abstract 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 abstract 6
- 230000008878 coupling Effects 0.000 abstract 5
- 238000010168 coupling process Methods 0.000 abstract 5
- 238000005859 coupling reaction Methods 0.000 abstract 5
- 125000003118 aryl group Chemical group 0.000 abstract 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 3
- 229910052736 halogen Inorganic materials 0.000 abstract 3
- 238000000034 method Methods 0.000 abstract 3
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 abstract 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical group [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract 2
- -1 aryl diazonium compounds Chemical class 0.000 abstract 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 2
- 229910052799 carbon Inorganic materials 0.000 abstract 2
- 125000004432 carbon atom Chemical group C* 0.000 abstract 2
- 150000001875 compounds Chemical class 0.000 abstract 2
- 239000002537 cosmetic Substances 0.000 abstract 2
- 238000004043 dyeing Methods 0.000 abstract 2
- 125000005843 halogen group Chemical group 0.000 abstract 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 abstract 2
- 239000000203 mixture Substances 0.000 abstract 2
- 125000004433 nitrogen atom Chemical group N* 0.000 abstract 2
- 239000001301 oxygen Substances 0.000 abstract 2
- 229910052760 oxygen Inorganic materials 0.000 abstract 2
- 229920006395 saturated elastomer Polymers 0.000 abstract 2
- ALSTYHKOOCGGFT-KTKRTIGZSA-N (9Z)-octadecen-1-ol Chemical compound CCCCCCCC\C=C/CCCCCCCCO ALSTYHKOOCGGFT-KTKRTIGZSA-N 0.000 abstract 1
- 239000004166 Lanolin Substances 0.000 abstract 1
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical class C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 abstract 1
- 239000004264 Petrolatum Substances 0.000 abstract 1
- XKGDWZQXVZSXAO-ADYSOMBNSA-N Ricinoleic Acid methyl ester Chemical compound CCCCCC[C@@H](O)C\C=C/CCCCCCCC(=O)OC XKGDWZQXVZSXAO-ADYSOMBNSA-N 0.000 abstract 1
- 239000004480 active ingredient Substances 0.000 abstract 1
- 150000001412 amines Chemical class 0.000 abstract 1
- 239000012185 ceresin wax Substances 0.000 abstract 1
- 125000004093 cyano group Chemical group *C#N 0.000 abstract 1
- 150000002367 halogens Chemical class 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 abstract 1
- 229940039717 lanolin Drugs 0.000 abstract 1
- 235000019388 lanolin Nutrition 0.000 abstract 1
- 239000002480 mineral oil Substances 0.000 abstract 1
- 235000010446 mineral oil Nutrition 0.000 abstract 1
- 150000002790 naphthalenes Chemical class 0.000 abstract 1
- 150000004780 naphthols Chemical class 0.000 abstract 1
- 229940055577 oleyl alcohol Drugs 0.000 abstract 1
- XMLQWXUVTXCDDL-UHFFFAOYSA-N oleyl alcohol Natural products CCCCCCC=CCCCCCCCCCCO XMLQWXUVTXCDDL-UHFFFAOYSA-N 0.000 abstract 1
- 239000002304 perfume Substances 0.000 abstract 1
- 235000019271 petrolatum Nutrition 0.000 abstract 1
- 229940066842 petrolatum Drugs 0.000 abstract 1
- 150000002989 phenols Chemical class 0.000 abstract 1
- XKGDWZQXVZSXAO-UHFFFAOYSA-N ricinoleic acid methyl ester Natural products CCCCCCC(O)CC=CCCCCCCCC(=O)OC XKGDWZQXVZSXAO-UHFFFAOYSA-N 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/02—Preparations containing skin colorants, e.g. pigments
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/42—Amides
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Dermatology (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Cosmetics (AREA)
Abstract
Compounds of the general formula <FORM:0878363/IV (b)/1> in which A and B represent aromatic radicals consisting of at most 2 fused rings which can further be substituted by halogens and by groups not having dyeing characteristics such groups being bound to the aromatic rings by means of a carbon, oxygen or sulphur atom and any further aromatic radicals being linked direct or by means of saturated bridging members to A and B, and in which A is bound to the nitrogen atoms at adjacent carbon atoms, are prepared by methods known per se, for example, by coupling aryl diazonium compounds with azo compounds of the benzene and napthalene series coupling in the o-position to a primary amino group, and oxidising the o-amino-azo dyestuffs thus formed to the corresponding 1.2.3-triazole compound. Alternatively they may be produced by coupling o-nitro aryl diazonium compounds with phenols or naphthols coupling in the o-or p-position or with amines of the benzene or naphthalene series coupling in the p-position to a primary amine group and then reducing the o-nitro-azo dyestuffs by usual methods. The aromatic rings can be further substituted as defined and in the product free hydroxyl groups may also be alkylated or acylated. Primary amino groups must be removed by diazotising and replacing by the usual methods with, for example, hydrogen, halogen or cyano or hydroxyl groups. Products referred to include 2-(21-acetoxy-51-methylphenyl) - 5 - methylbenztriazole, 2 - (21-acetoxy-51-methylphenyl)-benztriazole, 2 - (21-stearoyloxy-51-methylphenyl) - benztriazole, 2-(21-benzoyloxy-51-methylphenyl) - benztriazole, 2-(21-p-tosyloxy-51-methylphenyl) - benztriazole, 2-(21-methyl-41-hydroxyphenyl)-benztriazole, 2-(21-methoxy-51-methylphenyl)-benztriazole and 2-(21-methoxy - 51 - chlorophenyl) - benztriazole. Th products may be incorporated in nonactinic preparations for the human skin (see Group VI).ALSO:Non-actinic preparations for the human skin comprise a cosmetic base and a minor proportion of a compound of the general formula <FORM:0878363/VI/1> in which A and B represent aromatic radicals consisting of at most 2 fused rings which can be further substituted by halogen and by groups not having dyeing characteristics such groups being bound to the aromatic rings by means of a carbon, oxygen or sulphur atom and when aromatic being linked direct or by saturated bridging members to A and B, and in which A is bound to the nitrogen atoms at two adjacent carbon atoms. Examples are given of preparations containing as cosmetic bases (a) a mixture of ceresin wax, petrolatum, white mineral oil, lanolin, water and perfume; and (b) a mixture of ricinoleic acid methyl ester, oleyl alcohol and ethanol, with a minor proportion of one of the following active ingredients: (a) 2 - (21 - acetoxy - 51 - methylphenyl) - 5-methylbenztriazole; (b) 2 - (21 - acetoxy - 51-methyl phenyl) - benztriazole; (c) 2 - (21-stearoyloxy - 51 - methylphenyl) - benztriazole; (d) 2 - (21 - benzoyloxy - 51 - methyl phenyl)-benztriazole; (c) 2 - (21 - p - tosyloxy - 51-methylphenyl) - benztriazole; (f) 2 - (21 - methyl - 41 - hydroxyphenyl) - benztriazole; (g) 2 - (21 - methoxy - 51 - methyl phenyl) - benztriazole; and (h) 2 - (21 - methoxy - 51 - chlorphenyl)-benztriazole.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH878363X | 1956-12-14 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB878363A true GB878363A (en) | 1961-09-27 |
Family
ID=4544625
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB41863/59A Expired GB878363A (en) | 1956-12-14 | 1957-12-13 | Improvements relating to non-actinic preparations for the human skin |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB878363A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3197475A (en) * | 1962-03-12 | 1965-07-27 | Du Pont | Certain 2-(o-aminophenyl)-tetrahydrobenzotriazole compounds |
| US3213058A (en) * | 1960-12-19 | 1965-10-19 | American Cyanamid Co | Polymers reacted with benzotriazole uv absorbers |
| US4727158A (en) * | 1985-09-03 | 1988-02-23 | Ciba-Geigy Corporation | 5-Higher alkyl substituted-2H-benzotriazoles |
| US4760148A (en) * | 1985-09-03 | 1988-07-26 | Ciba-Geigy Corporation | 5-aralkyl substituted 2H-benzotriazoles and stabilized compositions |
-
1957
- 1957-12-13 GB GB41863/59A patent/GB878363A/en not_active Expired
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3213058A (en) * | 1960-12-19 | 1965-10-19 | American Cyanamid Co | Polymers reacted with benzotriazole uv absorbers |
| US3197475A (en) * | 1962-03-12 | 1965-07-27 | Du Pont | Certain 2-(o-aminophenyl)-tetrahydrobenzotriazole compounds |
| US4727158A (en) * | 1985-09-03 | 1988-02-23 | Ciba-Geigy Corporation | 5-Higher alkyl substituted-2H-benzotriazoles |
| US4760148A (en) * | 1985-09-03 | 1988-07-26 | Ciba-Geigy Corporation | 5-aralkyl substituted 2H-benzotriazoles and stabilized compositions |
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