GB878163A - Improvements in or relating to the manufacture of polyoxymethylenes - Google Patents
Improvements in or relating to the manufacture of polyoxymethylenesInfo
- Publication number
- GB878163A GB878163A GB2302059A GB2302059A GB878163A GB 878163 A GB878163 A GB 878163A GB 2302059 A GB2302059 A GB 2302059A GB 2302059 A GB2302059 A GB 2302059A GB 878163 A GB878163 A GB 878163A
- Authority
- GB
- United Kingdom
- Prior art keywords
- catalysts
- boron trifluoride
- complexes
- water
- acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2/00—Addition polymers of aldehydes or cyclic oligomers thereof or of ketones; Addition copolymers thereof with less than 50 molar percent of other substances
- C08G2/06—Catalysts
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2/00—Addition polymers of aldehydes or cyclic oligomers thereof or of ketones; Addition copolymers thereof with less than 50 molar percent of other substances
- C08G2/10—Polymerisation of cyclic oligomers of formaldehyde
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2/00—Addition polymers of aldehydes or cyclic oligomers thereof or of ketones; Addition copolymers thereof with less than 50 molar percent of other substances
- C08G2/28—Post-polymerisation treatments
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)
Abstract
Trioxane is polymerized in the presence of an electrophilic catalyst, the water content of the reaction mixture being less than 0,1%. Specified catalysts are Friedel-Crafts catalysts particularly boron trifluoride, stannic chloride and ferric chloride complexes of these catalysts with water and organic compounds containing an oxygen, nitrogen (when weakly basic) or p sulphur donor atom, non-oxidizing inorganic acids and their boron trifluoride complexes, e.g. dihydroxyfluoroboric acid and polyphosphoric acid, halogens and interhalogen compounds, and oxonium salts. The polymerization may take place in the presence or absence of an inert liquid medium, e.g. hydrocarbons, nitro-hydro carbons and carboxylic esters. Metallic ions are removed from the product by extracting with an organic solvent or a solution of a sequestering agent. Specifications 557,873 and 748,836 are referred to.
Priority Applications (8)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
BE592599D BE592599A (en) | 1959-07-03 | ||
NL127433D NL127433C (en) | 1959-07-03 | ||
NL253350D NL253350A (en) | 1959-07-03 | ||
GB2302059A GB878163A (en) | 1959-07-03 | 1959-07-03 | Improvements in or relating to the manufacture of polyoxymethylenes |
DE19601495124 DE1495124A1 (en) | 1959-06-02 | 1960-07-02 | Process for the preparation of polyoxymethylenes |
DE19601445220 DE1445220A1 (en) | 1959-07-03 | 1960-07-02 | Process for the preparation of polyoxymethylenes |
FR832003A FR1264730A (en) | 1959-07-03 | 1960-07-02 | Process for the polymerization of trioxane and products thus obtained |
CH760060A CH390546A (en) | 1959-07-03 | 1960-07-04 | Trioxane polymerization process |
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB2302059A GB878163A (en) | 1959-07-03 | 1959-07-03 | Improvements in or relating to the manufacture of polyoxymethylenes |
GB1961560 | 1960-05-23 | ||
GB1817560 | 1960-05-23 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB878163A true GB878163A (en) | 1961-09-27 |
Family
ID=27257592
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB2302059A Expired GB878163A (en) | 1959-06-02 | 1959-07-03 | Improvements in or relating to the manufacture of polyoxymethylenes |
Country Status (5)
Country | Link |
---|---|
BE (1) | BE592599A (en) |
CH (1) | CH390546A (en) |
DE (1) | DE1445220A1 (en) |
GB (1) | GB878163A (en) |
NL (2) | NL253350A (en) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3197438A (en) * | 1961-01-16 | 1965-07-27 | Grace W R & Co | Polymerization and co-polymerization of trioxane in inert solvents |
US3207726A (en) * | 1960-06-16 | 1965-09-21 | Jaffe Fred | Preparing trioxane epoxide copolymers with trialkyloxonium catalysts |
US3219631A (en) * | 1960-11-15 | 1965-11-23 | Hoechst Ag | Copolymers of cyclic acetals with oxacyclopropane or oxacyclobutane or the derivatives thereof and process for preparing said copolymers |
US3256246A (en) * | 1961-10-27 | 1966-06-14 | Hoechst Ag | Copolymerization of trioxane with preformed linear polymers |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1040171A (en) * | 1962-03-19 | 1966-08-24 | British Industrial Plastics | Manufacture of polyoxymethylenes |
DE1204823B (en) * | 1963-04-30 | 1965-11-11 | Hoechst Ag | Process for polymerizing cyclic acetals individually or in admixture |
NL125851C (en) * | 1963-09-28 |
-
0
- BE BE592599D patent/BE592599A/xx unknown
- NL NL127433D patent/NL127433C/xx active
- NL NL253350D patent/NL253350A/xx unknown
-
1959
- 1959-07-03 GB GB2302059A patent/GB878163A/en not_active Expired
-
1960
- 1960-07-02 DE DE19601445220 patent/DE1445220A1/en active Pending
- 1960-07-04 CH CH760060A patent/CH390546A/en unknown
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3207726A (en) * | 1960-06-16 | 1965-09-21 | Jaffe Fred | Preparing trioxane epoxide copolymers with trialkyloxonium catalysts |
US3219631A (en) * | 1960-11-15 | 1965-11-23 | Hoechst Ag | Copolymers of cyclic acetals with oxacyclopropane or oxacyclobutane or the derivatives thereof and process for preparing said copolymers |
US3197438A (en) * | 1961-01-16 | 1965-07-27 | Grace W R & Co | Polymerization and co-polymerization of trioxane in inert solvents |
US3256246A (en) * | 1961-10-27 | 1966-06-14 | Hoechst Ag | Copolymerization of trioxane with preformed linear polymers |
Also Published As
Publication number | Publication date |
---|---|
NL127433C (en) | |
CH390546A (en) | 1965-04-15 |
BE592599A (en) | |
DE1445220A1 (en) | 1968-11-07 |
NL253350A (en) |
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