GB877923A - Improved elastomer adhesives and method for the employment thereof - Google Patents

Improved elastomer adhesives and method for the employment thereof

Info

Publication number
GB877923A
GB877923A GB32649/58A GB3264958A GB877923A GB 877923 A GB877923 A GB 877923A GB 32649/58 A GB32649/58 A GB 32649/58A GB 3264958 A GB3264958 A GB 3264958A GB 877923 A GB877923 A GB 877923A
Authority
GB
United Kingdom
Prior art keywords
dioxime
dinitroso
aromatic compound
bonding agent
parts
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB32649/58A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Borg Warner Corp
Original Assignee
Borg Warner Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Borg Warner Corp filed Critical Borg Warner Corp
Publication of GB877923A publication Critical patent/GB877923A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J115/00—Adhesives based on rubber derivatives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/32—Compounds containing nitrogen bound to oxygen
    • C08K5/33—Oximes
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J115/00—Adhesives based on rubber derivatives
    • C09J115/02—Rubber derivatives containing halogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
    • C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials
    • C08L2666/04—Macromolecular compounds according to groups C08L7/00 - C08L49/00, or C08L55/00 - C08L57/00; Derivatives thereof
    • C08L2666/08—Homopolymers or copolymers according to C08L7/00 - C08L21/00; Derivatives thereof

Abstract

In the bonding agent for elastomers of Specification 877,035 comprising a solution of chlorinated rubber, halogenated polychlorobutadiene and a dinitroso-aromatic compound, the dinitroso-aromatic compound is replaced by a quinone dioxime and a mild oxidizing agent; under the conditions of cure these react to form the dinitroso-aromatic compound. Quinone dioximes specified are p-benzoquinone dioxime, 2, 5-dichloro p-benzoquinone dioxime, toluquinone dioxime, p-xyloquinone dioxime, thymoquinone dioxime, 1, 2-naphthoquinone dioxime, and 1, 4-naphthoquinone dioxime. Oxidizing agents preferred are 2, 21-dithiobis benzothiazole and tetramethyl thiuram disulphide. One typical agent comprises a solution in 20 parts of xylene of 3,5 parts chlorinated rubber of 125 cps. viscosity (determined in 20% w/w toluene solution at 25 DEG C.), 1,5 parts brominated Neoprene, 0,25 part dibasic lead phosphite, 0,4 part p-benzoquinone dioxime, 0,7 part 2, 21-dithiobis-benzothiazole, and 0,8 part carbon black. In an example, this bonding agent was applied by brushing to the surface of clean, dry steel strip, the resulting film was allowed to dry in air for twenty minutes following which a layer of freshly sheeted, uncured natural or QR-S rubber stock was pressed into intimate contact with the partially dried film of the bonding agent on the metal surface; the resulting assembly was then cured at 307 DEG F. for 20 minutes.
GB32649/58A 1957-10-29 1958-10-13 Improved elastomer adhesives and method for the employment thereof Expired GB877923A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US877923XA 1957-10-29 1957-10-29

Publications (1)

Publication Number Publication Date
GB877923A true GB877923A (en) 1961-09-20

Family

ID=22207294

Family Applications (1)

Application Number Title Priority Date Filing Date
GB32649/58A Expired GB877923A (en) 1957-10-29 1958-10-13 Improved elastomer adhesives and method for the employment thereof

Country Status (1)

Country Link
GB (1) GB877923A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0278375A1 (en) * 1987-02-11 1988-08-17 Henkel Kommanditgesellschaft auf Aktien Thermostable rubber/metal bonding agents
EP0330089A2 (en) * 1988-02-22 1989-08-30 Ashland Oil, Inc. Splice adhesive for EPDM roofing
EP1923443A1 (en) * 2006-11-15 2008-05-21 Rohm and Haas Chemicals LLC Adhesive for elastomers

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0278375A1 (en) * 1987-02-11 1988-08-17 Henkel Kommanditgesellschaft auf Aktien Thermostable rubber/metal bonding agents
US4994519A (en) * 1987-02-11 1991-02-19 Henkel Kommanditgesellschaft Auf Aktien Rubber-to-metal binders from chlorinated rubber and brominated polydichlorobutadiene
EP0330089A2 (en) * 1988-02-22 1989-08-30 Ashland Oil, Inc. Splice adhesive for EPDM roofing
EP0330089A3 (en) * 1988-02-22 1991-10-23 Ashland Oil, Inc. Splice adhesive for epdm roofing
EP1923443A1 (en) * 2006-11-15 2008-05-21 Rohm and Haas Chemicals LLC Adhesive for elastomers
US8466226B2 (en) 2006-11-15 2013-06-18 Rohm And Haas Company Adhesives for elastomers

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