GB874355A - New azo dyestuffs of the phthalocyanine series - Google Patents
New azo dyestuffs of the phthalocyanine seriesInfo
- Publication number
- GB874355A GB874355A GB25743/59A GB2574359A GB874355A GB 874355 A GB874355 A GB 874355A GB 25743/59 A GB25743/59 A GB 25743/59A GB 2574359 A GB2574359 A GB 2574359A GB 874355 A GB874355 A GB 874355A
- Authority
- GB
- United Kingdom
- Prior art keywords
- phthalocyanine
- compound
- coupling
- residue
- dyestuff
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B62/00—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves
- C09B62/002—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves with the linkage of the reactive group being alternatively specified
- C09B62/006—Azodyes
- C09B62/0068—Azodyes dyes containing in the molecule at least one azo group and at least one other chromophore group
Abstract
The invention comprises azo dyestuff of the phthalocyanine series of formula:- <FORM:0874355/IV(c)/1> wherein Phth is a phthalocyanine residue which may contain metal, X is hydrogen or an alkyl, aralkyl, cycloalkyl or aryl radical, R1 is the radical of an oxo-, hydroxy- or aminocompound capable of coupling, R2 is an arylene residue, Y the residue of a saturated or unsaturated halofatty acid or of a mono- or di-halotriazine compound, Z is a carboxy and/or sulphonic acid group, m is an integer of at least 2 and n is an integer from 1-4. The dyestuffs are prepared by (a) reacting a phthalocyanine sulphonyl halide with an amino-compound (X-HN-R1-H) capable of coupling which contains an oxo-, hydroxy- or further amino group and coupling the condensation product with a diazo compound from an arylamine (H2N-R2-N(X)-Y), or (b) reacting a phthalocyanine sulphonyl halide with an aminoazo compound (X-NH-R1 -N=N-R2-NX-Y), or (c) treating a phthalocyanine-azo dye of the formula above but where Y is hydrogen with a saturated or unsaturated halo-fatty acid halide or anhydride or a di- or tri-halotriazine, the components being so selected that the final dyestuff contains at least one reactive halogen atom and at least two carboxylic and/or sulphonic acid groups. The dyestuffs may be used to dye animal and synthetic polyamide fibres, but preferably are used to dye cellulose materials in the presence of acidbinding agents, in green, brown, blue, grey and black shades. Many examples and intermediate compounds are specified. The aminoazo dyestuff 1-amino- 3-acetylaminobenzene- 6-sulphonic acid --> 1-(31-aminophenyl)-5-pyrazolone-3-carboxylic acid is prepared intermediately.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE874355X | 1958-08-07 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB874355A true GB874355A (en) | 1961-08-02 |
Family
ID=6816852
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB25743/59A Expired GB874355A (en) | 1958-08-07 | 1959-07-27 | New azo dyestuffs of the phthalocyanine series |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB874355A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2617062A1 (en) * | 1976-04-17 | 1977-10-20 | Cassella Farbwerke Mainkur Ag | NEW WATER-SOLUBLE HYDRAZONE OF THE PHTHALOCYANIN SERIES, THEIR PRODUCTION AND USE |
DE2617126A1 (en) * | 1976-04-17 | 1977-10-20 | Cassella Farbwerke Mainkur Ag | PROCESS FOR THE PRODUCTION OF FIBER REACTIVE PHTHALOCYANINE-AZO DYES |
-
1959
- 1959-07-27 GB GB25743/59A patent/GB874355A/en not_active Expired
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2617062A1 (en) * | 1976-04-17 | 1977-10-20 | Cassella Farbwerke Mainkur Ag | NEW WATER-SOLUBLE HYDRAZONE OF THE PHTHALOCYANIN SERIES, THEIR PRODUCTION AND USE |
DE2617126A1 (en) * | 1976-04-17 | 1977-10-20 | Cassella Farbwerke Mainkur Ag | PROCESS FOR THE PRODUCTION OF FIBER REACTIVE PHTHALOCYANINE-AZO DYES |
DE2617126C2 (en) * | 1976-04-17 | 1982-05-27 | Cassella Ag, 6000 Frankfurt | Process for the preparation of fiber-reactive phthalocyanine azo dyes |
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