GB872147A - Heat-hardenable compositions composed of polyvinyl chloride, epoxy resin and hardening agent - Google Patents
Heat-hardenable compositions composed of polyvinyl chloride, epoxy resin and hardening agentInfo
- Publication number
- GB872147A GB872147A GB6774/58A GB677458A GB872147A GB 872147 A GB872147 A GB 872147A GB 6774/58 A GB6774/58 A GB 6774/58A GB 677458 A GB677458 A GB 677458A GB 872147 A GB872147 A GB 872147A
- Authority
- GB
- United Kingdom
- Prior art keywords
- epoxy resin
- liquid
- mixture
- paste
- room temperature
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000203 mixture Substances 0.000 title abstract 13
- 239000003822 epoxy resin Substances 0.000 title abstract 5
- 229920000647 polyepoxide Polymers 0.000 title abstract 5
- 239000003795 chemical substances by application Substances 0.000 title 1
- 229920000915 polyvinyl chloride Polymers 0.000 title 1
- 239000004800 polyvinyl chloride Substances 0.000 title 1
- 239000007788 liquid Substances 0.000 abstract 6
- 229920001577 copolymer Polymers 0.000 abstract 5
- 150000008064 anhydrides Chemical class 0.000 abstract 4
- 239000004604 Blowing Agent Substances 0.000 abstract 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 abstract 3
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 abstract 2
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 abstract 2
- ZFIVKAOQEXOYFY-UHFFFAOYSA-N Diepoxybutane Chemical compound C1OC1C1OC1 ZFIVKAOQEXOYFY-UHFFFAOYSA-N 0.000 abstract 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 abstract 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 abstract 2
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 abstract 2
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 abstract 2
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 abstract 2
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 abstract 2
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical class C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 abstract 2
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 abstract 2
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 abstract 2
- -1 cresyl glycide Chemical compound 0.000 abstract 2
- 150000002148 esters Chemical class 0.000 abstract 2
- 150000002170 ethers Chemical class 0.000 abstract 2
- 238000000034 method Methods 0.000 abstract 2
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 abstract 2
- 229920001568 phenolic resin Polymers 0.000 abstract 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 abstract 2
- 239000004848 polyfunctional curative Substances 0.000 abstract 2
- 229920005989 resin Polymers 0.000 abstract 2
- 239000011347 resin Substances 0.000 abstract 2
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 abstract 2
- LGXVIGDEPROXKC-UHFFFAOYSA-N 1,1-dichloroethene Chemical class ClC(Cl)=C LGXVIGDEPROXKC-UHFFFAOYSA-N 0.000 abstract 1
- AHDSRXYHVZECER-UHFFFAOYSA-N 2,4,6-tris[(dimethylamino)methyl]phenol Chemical compound CN(C)CC1=CC(CN(C)C)=C(O)C(CN(C)C)=C1 AHDSRXYHVZECER-UHFFFAOYSA-N 0.000 abstract 1
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 abstract 1
- WVRNUXJQQFPNMN-VAWYXSNFSA-N 3-[(e)-dodec-1-enyl]oxolane-2,5-dione Chemical compound CCCCCCCCCC\C=C\C1CC(=O)OC1=O WVRNUXJQQFPNMN-VAWYXSNFSA-N 0.000 abstract 1
- 239000005995 Aluminium silicate Substances 0.000 abstract 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 abstract 1
- 229910000831 Steel Inorganic materials 0.000 abstract 1
- 239000000654 additive Substances 0.000 abstract 1
- 150000001298 alcohols Chemical class 0.000 abstract 1
- 235000012211 aluminium silicate Nutrition 0.000 abstract 1
- 238000007664 blowing Methods 0.000 abstract 1
- 150000001244 carboxylic acid anhydrides Chemical class 0.000 abstract 1
- 238000005266 casting Methods 0.000 abstract 1
- 239000001913 cellulose Substances 0.000 abstract 1
- 229920002678 cellulose Polymers 0.000 abstract 1
- 235000010980 cellulose Nutrition 0.000 abstract 1
- 239000011248 coating agent Substances 0.000 abstract 1
- 238000000576 coating method Methods 0.000 abstract 1
- 239000000470 constituent Substances 0.000 abstract 1
- 238000001816 cooling Methods 0.000 abstract 1
- 239000003085 diluting agent Substances 0.000 abstract 1
- 239000000945 filler Substances 0.000 abstract 1
- 239000011888 foil Substances 0.000 abstract 1
- 239000011521 glass Substances 0.000 abstract 1
- 239000003365 glass fiber Substances 0.000 abstract 1
- 235000011187 glycerol Nutrition 0.000 abstract 1
- MUTGBJKUEZFXGO-UHFFFAOYSA-N hexahydrophthalic anhydride Chemical class C1CCCC2C(=O)OC(=O)C21 MUTGBJKUEZFXGO-UHFFFAOYSA-N 0.000 abstract 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 abstract 1
- 239000004850 liquid epoxy resins (LERs) Substances 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
- 235000012054 meals Nutrition 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 abstract 1
- 239000010445 mica Substances 0.000 abstract 1
- 229910052618 mica group Inorganic materials 0.000 abstract 1
- 150000002989 phenols Chemical class 0.000 abstract 1
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 abstract 1
- LGRFSURHDFAFJT-UHFFFAOYSA-N phthalic anhydride Chemical class C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 abstract 1
- 239000004014 plasticizer Substances 0.000 abstract 1
- 239000000843 powder Substances 0.000 abstract 1
- 239000010453 quartz Substances 0.000 abstract 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 1
- 239000003381 stabilizer Substances 0.000 abstract 1
- 239000010959 steel Substances 0.000 abstract 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 abstract 1
- 229920002554 vinyl polymer Polymers 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/0061—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof characterized by the use of several polymeric components
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
- C08G59/42—Polycarboxylic acids; Anhydrides, halides or low molecular weight esters thereof
- C08G59/4215—Polycarboxylic acids; Anhydrides, halides or low molecular weight esters thereof cycloaliphatic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D127/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
- C09D127/02—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
- C09D127/04—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C09D127/06—Homopolymers or copolymers of vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
- C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
- C08J2327/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08J2327/06—Homopolymers or copolymers of vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2463/00—Characterised by the use of epoxy resins; Derivatives of epoxy resins
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Materials Engineering (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Epoxy Resins (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
Abstract
Heat-hardenable compositions, which are paste-like to liquid at room temperature, comprise (i) powdered P.V.C. or paste-forming co-polymers thereof (ii) an epoxy resin, and (iii) a hardener for (ii) which is a polycarboxylic anhydride and is capable of forming with the epoxy resin, at least upon being so heated with the resin as to avoid gelatinization, and being subsequently cooled, a mixture that is a pourable liquid at room temperature. Components specified are: (i) P.V.C., and co-polymers of vinyl chloride with vinylidene chloride, vinyl ethers, or vinyl acetate, and in Examples (7) and (8) a mixture of P.V.C. with a copolymer of vinyl and vinylidene chlorides; (ii), which are preferably liquid, polyglycidyl ethers of resorcinol, hydroquinone, bisphenol A, phenol-formaldehyde resins, ethylene glycol or glycerine, polyglycidyl esters of phthalic or terephthalic acid, and butadiene dioxide; (iii) methyl-endomethylene tetrahydrophthalic, dodecenyl-succinic, or hexahydrophthalic anhydrides, or mixtures of anhydrides, the mixtures being liquid at room temperature after their components have been melted together and cooled, e.g. a mixture of hexahydrophthalic with tetrahydrophthalic and/or phthalic, and a mixture of hexachloroendomethylene tetrahydrophthalic with hexahydrophthalic or with methyl endomethylene tetrahydrophthalic with or without endomethylene tetrahydrophthalic. Other additives specified are: accelerators (2,4,6-tris-(dimethylaminomethyl)-phenol and BF3), diluents (cresyl glycide), stabilizers (Pb stearate, carbonate or phosphite), dioctyl phthalate, fillers, e.g. glass fibres, mica, quartz meal, cellulose, kaolin and metal powder, and blowing agents (see Group V). All the various components may be mixed in various orders. Uses: Coating (steel or glass), laminates, printing pastes, casting, impregnating, embedding, foils, and foamed articles. Specification 872,148 is referred to.ALSO:Foamed materials may be produced by incorporating a blowing agent in a heat-hardenable composition which is paste-like to liquid at room temperature and which comprises (i) a powdered P.V.C. or a paste-forming co-polymer thereof, (ii) an epoxy resin, and (iii) a hardener for (ii) which is a polycarboxylic anhydride and is capable of forming in the epoxy resin, at least upon being so heated with the resin as to avoid gelatiniation, and being subsequently cooled, a mixture that is a pourable liquid at room temperature. Especially suitable is a 2-stage blowing method in which in the first stage a homogeneous paste is gelatinized in a closed mould at about 150 degree under pressure, the moulded article is removed from the mould after cooling, whereupon an initial expansion takes place, and then in the same stage the final expansion and hardening are brought about at 100 DEG C. without a mould. In Examples (9), (10) and (11) this process is carried out using compositions comprising : pulverulent P.V.C., a liquid epoxy resin, cresylglycide, Pb stearate, ether hexalhydrophthalic anhydride or a mixture of hexahydro-, tetrahydro- and phthalic anhydrides, and, as blowing agent, either azodiisobutyronitrile or azo-hexahydrobenzonitrile. The quantities of the various components are varied to give products of different densities and all sizes; the cells are apparently closed. The dimensional stability of the products may be increased by adding a plasticizer such as dioctyl phthalate. Constituents listed include: (i) co-polymers of vinyl chloride with vinylidene chloride, vinyl ethers or vinyl acetate; (ii) polyglycidyl ethers of phenols, phenol-formaldehyde resins, or alcohols, polyglycidyl esters, and butadiene dioxide; and (iii) dodecenyl succinic anhydride and various carboxylic anhydrides including a chlorinated one, which may be used alone or in mixtures (see Group IV(a)). Specifications 872,148 is referred to.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH872147X | 1957-03-01 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB872147A true GB872147A (en) | 1961-07-05 |
Family
ID=4544114
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB6774/58A Expired GB872147A (en) | 1957-03-01 | 1958-03-03 | Heat-hardenable compositions composed of polyvinyl chloride, epoxy resin and hardening agent |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US2965586A (en) |
| BE (1) | BE565319A (en) |
| CH (1) | CH352139A (en) |
| DE (1) | DE1074261B (en) |
| FR (1) | FR1199495A (en) |
| GB (1) | GB872147A (en) |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE608993A (en) * | 1960-10-11 | 1900-01-01 | ||
| US3383337A (en) * | 1962-08-02 | 1968-05-14 | Firestone Tire & Rubber Co | Method of treating a plastisol composition containing an epoxy resin adhesive |
| US3354109A (en) * | 1963-11-19 | 1967-11-21 | Goodrich Co B F | Heat-fusible composition comprised of vinyl halide resin, epoxy resin and acid plasticizer |
| US3305514A (en) * | 1964-02-06 | 1967-02-21 | Standard Oil Co | Vinyl halide resin, epoxy or alkyd resin, monoalkenyl and polyalkenyl monomer reinforced thermoplastic composition |
| DE1544943A1 (en) * | 1964-02-12 | 1969-07-31 | Goodrich Co B F | Thermosetting vinyl plastisols |
| US3488314A (en) * | 1965-07-23 | 1970-01-06 | Paisley Products Inc | Polyvinyl chloride coating compositions containing phenol-formaldehyde and epoxy resins |
| US3486924A (en) * | 1966-02-14 | 1969-12-30 | Unitog Co | Plastic labels coated with cross-linked polyvinyl chloride-epoxide-anhydride mixture |
| US3819560A (en) * | 1972-01-06 | 1974-06-25 | Minnesota Mining & Mfg | Vinyl halide polymer/epoxide resin powder coating compositions |
| US3988493A (en) * | 1975-01-23 | 1976-10-26 | E. I. Du Pont De Nemours And Company | Polymer powder coating composition |
| US4250006A (en) * | 1979-03-19 | 1981-02-10 | American Can Company | Polymerizable coating composition containing polymerizable epoxide compound and vinyl chloride dispersion polymer and method of coating utilizing same and coated articles produced thereby |
| US4959399A (en) * | 1988-05-20 | 1990-09-25 | W. R. Grace & Co.-Conn. | Acidic adhesion promoters for PVC plastisols |
| DE19823491C2 (en) * | 1998-05-26 | 2001-06-07 | Boehme Chem Fab Kg | Process for the production of soft PVC foams and then obtainable soft PVC foams |
| JP4491236B2 (en) * | 2001-12-21 | 2010-06-30 | ヘンケル・テロソン・ゲゼルシャフト・ミット・ベシュレンクテル・ハフツング | Expandable epoxy resin system modified with thermoplastic polymer |
| BR102017016857B1 (en) * | 2016-08-08 | 2023-02-14 | Sika Technology Ag | FILLER COMPOSITION, FILLER AGENT, USE OF THE COMPOSITION, METHOD FOR FILLING AN CLOSED SPACE AND VEHICLE PART |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL171984B (en) * | 1951-08-24 | Sandoz Ag | PROCESS FOR OPTICAL BLEACHING OF NATURAL OR SYNTHETIC FIBERS OR FIBER FORMING POLYMERS, THE OPTICALLY BLEACHED NATURAL OR SYNTHETIC FIBERS OR FIBER FORMING POLYMERS AVAILABLE FOR THE PREPARED USE OF HEREVIJVENVIJLEN FOR THE PREPARATION OF WIJVERVIJLEN PREPARED FOR THE PREPARATION OF WIJVIJVIJEN | |
| GB783956A (en) * | 1953-01-13 | 1957-10-02 | Aero Res Ltd | Manufacture of epoxy resin products |
| GB745060A (en) * | 1953-02-18 | 1956-02-22 | Vinyl Products Ltd | Improvements in or relating to polyvinyl chloride compositions |
| BE533138A (en) * | 1953-11-09 | 1900-01-01 | ||
| GB777052A (en) * | 1953-12-22 | 1957-06-19 | Dunlop Rubber Co | Coating metal surfaces |
| US2717216A (en) * | 1954-07-01 | 1955-09-06 | Gen Electric | Flame-retardant insulated conductors, method of making same, and compositions used to prepare the same |
| NL104723C (en) * | 1954-08-25 | |||
| US2839495A (en) * | 1955-11-07 | 1958-06-17 | Shell Dev | Process for resinifying polyepoxides and resulting products |
-
0
- DE DENDAT1074261D patent/DE1074261B/de active Pending
- BE BE565319D patent/BE565319A/xx unknown
-
1957
- 1957-03-01 CH CH352139D patent/CH352139A/en unknown
-
1958
- 1958-02-25 US US717331A patent/US2965586A/en not_active Expired - Lifetime
- 1958-02-28 FR FR1199495D patent/FR1199495A/en not_active Expired
- 1958-03-03 GB GB6774/58A patent/GB872147A/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| BE565319A (en) | 1900-01-01 |
| US2965586A (en) | 1960-12-20 |
| CH352139A (en) | 1961-02-15 |
| DE1074261B (en) | 1960-01-28 |
| FR1199495A (en) | 1959-12-14 |
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