GB865342A - Process for the production of boron hydride hydrocarbon compounds - Google Patents
Process for the production of boron hydride hydrocarbon compoundsInfo
- Publication number
- GB865342A GB865342A GB25214/59A GB2521459A GB865342A GB 865342 A GB865342 A GB 865342A GB 25214/59 A GB25214/59 A GB 25214/59A GB 2521459 A GB2521459 A GB 2521459A GB 865342 A GB865342 A GB 865342A
- Authority
- GB
- United Kingdom
- Prior art keywords
- boron
- dimethyl ether
- ether
- reaction
- tetrahydrofuran
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- -1 boron hydride hydrocarbon compounds Chemical class 0.000 title abstract 7
- 229910010277 boron hydride Inorganic materials 0.000 title abstract 2
- 229910052796 boron Inorganic materials 0.000 abstract 8
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 abstract 5
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 abstract 4
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 abstract 4
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 abstract 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 abstract 2
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 abstract 2
- 125000001931 aliphatic group Chemical group 0.000 abstract 2
- SBZXBUIDTXKZTM-UHFFFAOYSA-N diglyme Chemical compound COCCOCCOC SBZXBUIDTXKZTM-UHFFFAOYSA-N 0.000 abstract 2
- 229930195733 hydrocarbon Natural products 0.000 abstract 2
- 239000002904 solvent Substances 0.000 abstract 2
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 abstract 2
- YJTKZCDBKVTVBY-UHFFFAOYSA-N 1,3-Diphenylbenzene Chemical group C1=CC=CC=C1C1=CC=CC(C=2C=CC=CC=2)=C1 YJTKZCDBKVTVBY-UHFFFAOYSA-N 0.000 abstract 1
- 229910052783 alkali metal Inorganic materials 0.000 abstract 1
- 150000001340 alkali metals Chemical class 0.000 abstract 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 abstract 1
- 150000001342 alkaline earth metals Chemical class 0.000 abstract 1
- 229910052786 argon Inorganic materials 0.000 abstract 1
- 238000009835 boiling Methods 0.000 abstract 1
- 150000002170 ethers Chemical class 0.000 abstract 1
- 229910052757 nitrogen Inorganic materials 0.000 abstract 1
- 238000010992 reflux Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
- C07F5/02—Boron compounds
- C07F5/027—Organoboranes and organoborohydrides
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
Abstract
Boron hydride hydrocarbons of the formula (Rn BH3-n)m wherein R stands for an aliphatic, cycloaliphatic or aromatic hydrocarbon radical, n is 1 or 2 and m is 1 or 2, are produced by reacting a boron trialkyl, boron tricycloalkyl or a boron triaryl with at least one borohydride of an alkali metal or alkaline earth metal and with at least one boron halide or addition product of a boron halide with an aliphatic or cycloaliphatic ether, in an inert atmosphere, for example nitrogen or argon. Solvents such as tetrahydrofuran and diethylene glycol dimethyl ether may be used or the reaction may be accomplished in the absence of solvents. It is preferred to use reaction temperatures of 30-60 DEG C. but the reaction may be completed by boiling under reflux. Suitable boron hydrocarbons are boron trimethyl, triethyl, tripropyl, tricyclohexyl, triphenyl, tritolyl and tri (ethylphenyl). Instead of the free boron halides, the addition products with ethers such as dimethyl ether, diethyl ether, tetrahydrofuran or diethylene-glycol-dimethyl ether, may be used.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE865342X | 1958-07-24 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB865342A true GB865342A (en) | 1961-04-12 |
Family
ID=6801824
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB25214/59A Expired GB865342A (en) | 1958-07-24 | 1959-07-22 | Process for the production of boron hydride hydrocarbon compounds |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB865342A (en) |
-
1959
- 1959-07-22 GB GB25214/59A patent/GB865342A/en not_active Expired
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