GB859492A - Preparation of perchloryl fluoride - Google Patents

Preparation of perchloryl fluoride

Info

Publication number
GB859492A
GB859492A GB35698/58A GB3569858A GB859492A GB 859492 A GB859492 A GB 859492A GB 35698/58 A GB35698/58 A GB 35698/58A GB 3569858 A GB3569858 A GB 3569858A GB 859492 A GB859492 A GB 859492A
Authority
GB
United Kingdom
Prior art keywords
perchlorate
fluorinating agent
mixture
reaction temperature
reaction time
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB35698/58A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Pennwalt Corp
Original Assignee
Pennsalt Chemical Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Pennsalt Chemical Corp filed Critical Pennsalt Chemical Corp
Publication of GB859492A publication Critical patent/GB859492A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B7/00—Halogens; Halogen acids
    • C01B7/24—Inter-halogen compounds
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B11/00—Oxides or oxyacids of halogens; Salts thereof
    • C01B11/24—Oxygen compounds of fluorine

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)

Abstract

<PICT:0859492/III/1> perchloryl fluoride gas is produced by interaction of an inorganic perchlorate and a fluorinating agent consisting of a mixture of fluosulphonic acid and antimony pentafluoride. The influence on the yield of increasing the proportion of antimony pentafluoride is shown by the Figure. The perchlorate may be added to the mixture or to either of the constituents before mixing. Ammonium, lithium, sodium, potassium, silver, magnesium, calcium, barium, and nitrosyl perchlorate are specified. Sufficient fluorinating agent to dissolve the perchlorate completely is preferably employed, i.e. not less than about 5 parts of fluorinating agent per part of perchlorate. The reaction temperature may be 70-130 DEG C. and the reaction time 2-24 hours. In continuous operation the reaction temperature is preferably 100-135 DEG C. and the reaction time 1-10 minutes. Examples are given.
GB35698/58A 1957-11-07 1958-11-06 Preparation of perchloryl fluoride Expired GB859492A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US859492XA 1957-11-07 1957-11-07

Publications (1)

Publication Number Publication Date
GB859492A true GB859492A (en) 1961-01-25

Family

ID=22195035

Family Applications (1)

Application Number Title Priority Date Filing Date
GB35698/58A Expired GB859492A (en) 1957-11-07 1958-11-06 Preparation of perchloryl fluoride

Country Status (1)

Country Link
GB (1) GB859492A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2253588A1 (en) * 2008-03-10 2010-11-24 Central Glass Company, Limited Method for producing oxygen-containing halogenated fluoride

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2253588A1 (en) * 2008-03-10 2010-11-24 Central Glass Company, Limited Method for producing oxygen-containing halogenated fluoride
EP2253588A4 (en) * 2008-03-10 2012-08-01 Central Glass Co Ltd Method for producing oxygen-containing halogenated fluoride

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