GB852729A - Improvements in the treatment of cellulose triacetate fibres - Google Patents

Improvements in the treatment of cellulose triacetate fibres

Info

Publication number
GB852729A
GB852729A GB9904/56A GB990456A GB852729A GB 852729 A GB852729 A GB 852729A GB 9904/56 A GB9904/56 A GB 9904/56A GB 990456 A GB990456 A GB 990456A GB 852729 A GB852729 A GB 852729A
Authority
GB
United Kingdom
Prior art keywords
fibres
esters
water
ethers
polyhydric alcohol
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB9904/56A
Inventor
George Frederick Bull
Ralph James Mann
Maitland Walton Alford
Boleslaw Krzesinski
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Acordis UK Ltd
Original Assignee
British Celanese Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by British Celanese Ltd filed Critical British Celanese Ltd
Priority to GB9904/56A priority Critical patent/GB852729A/en
Priority to GB9844/57A priority patent/GB852730A/en
Priority to US644442A priority patent/US3132919A/en
Priority to DEB43839A priority patent/DE1045966B/en
Priority to FR1173094D priority patent/FR1173094A/en
Publication of GB852729A publication Critical patent/GB852729A/en
Expired legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/144—Alcohols; Metal alcoholates
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/165—Ethers
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
    • D06M13/188—Monocarboxylic acids; Anhydrides, halides or salts thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
    • D06M13/207—Substituted carboxylic acids, e.g. by hydroxy or keto groups; Anhydrides, halides or salts thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
    • D06M13/228—Cyclic esters, e.g. lactones
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S8/00—Bleaching and dyeing; fluid treatment and chemical modification of textiles and fibers
    • Y10S8/92—Synthetic fiber dyeing
    • Y10S8/921—Cellulose ester or ether

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)
  • Treatment Of Fiber Materials (AREA)
  • Coloring (AREA)
  • Chemical And Physical Treatments For Wood And The Like (AREA)

Abstract

The sticking temperature and safe ironing temperature of cellulose triacetate fibres are raised by subjecting the fibres to the action of carboxylic esters, ethers or ether-carboxylic esters of polyhydric alcohols. The esters, ethers or ether-esters are preferably those of polyhydric alcohols containing up to 4 carbon atoms, e.g. glycol, propylene glycol, diethylene glycol and glycerol. Carboxylic esters are preferably lower fatty acid (C1-C4) esters, and ethers are preferably C1-C4 alkyl ethers. The esters, ethers or ether-esters, which may contain at the most one free hydroxyl group, are preferably miscible with water to the extent of at least 5 parts to 95 parts of water by weight and may have boiling points of at least 190 DEG C. The fibres may be impregnated with the polyhydric alcohol derivative by padding either directly or in an aqueous liquid. If the polyhydric alcohol derivative is not miscible with water in the proportion employed a water-miscible liquid, e.g. methyl, ethyl, n-propyl or isopropyl alcohol, glycol, glycerol or diethylene glycol, may be added in order to render the aqueous liquid homogeneous, and in order that the liquid may remain uniformly disposed on the padded fibres during subsequent manipulation a small proportion of a thickener, e.g. 1-3% of water-soluble methyl cellulose, may be added, The impregnated fibres may subsequently be subjected to a heat treatment such as steaming or immersion in a hot inert liquid, e.g. hot mercury or a low melting alloy such as Wood's metal. The fibres may also be treated with the polyhydric alcohol derivatives by passage through the treatment liquids or passing the treatment liquids through the fibres. The treatment facilitates the subsequent dyeing of the fibres, e.g. with disperse dyes, provided that the material carries the polyhydric alcohol derivative or has not been dried after washing with water until free of the polyhydric alcohol derivative when it enters the dye bath. Specifications 748,442 and 845,752 are referred to The first Provisional Specification also refers to Specifications 448,816, 448,817 448,917, 687,414, 719,853, 721,674, 726,900, 731,930 and 748,772. The second Provisional Specification refers to Specification 776,346.ALSO:The dyeing of cellulose triacetate fibres, e.g. with disperse dyes, is facilitated by subjecting them to the action of carboxylic esters, ethers or ether-carboxylic esters of polyhydric alcohols. The esters, ethers or ether-esters are preferably those of polyhydric alcohols containing up to 4 carbon atoms, e.g. glycol, propylene glycol, diethylene glycol and glycerol. Carboxylic esters are preferably lower fatty acid (C1-C4) esters, and ethers are preferably C1-C4 alkyl ethers. The esters, ethers or ether-esters, which may contain at the most one free hydroxyl group, are preferably miscible with water to the extent of at least 5 parts to 95 parts of water by weight and may have boiling points of at least 190 DEG C. The fibres may be impregnated with the polyhydric alcohol derivative by padding either directly or in an aqueous liquid. If the polyhydric alcohol derivative is not miscible with water in the proportion employed a watermiscible liquid, e.g. methyl, ethyl, n-propyl or isopropyl alcohol, glycol, glycerol or diethylene glycol, may be added in order to render the aqueous liquid homogeneous, and in order that the liquid may remain uniformly disposed on the padded fibres during subsequent manipulation a small proportion of a thickener, e.g. 1-3% of water-soluble methyl cellulose, may be added. The impregnated fibres may subsequently be subjected to a heat treatment such as steaming or immersion in a hot inert liquid, e.g. hot mercury or a low melting alloy such as Wood's metal. The fibres may also be treated with the polyhydric alcohol derivatives by passage through the treatment liquids or passing the treatment liquids through the fibres. The treatment facilitates the subsequent dyeing of the fibres provided that the material carries the polyhydric alcohol derivative or has not been dried after washing with water until free of the polyhydric alcohol derivative when it enters the dye bath. Specifications 758,442 and 845,752 are referred to. The first Provisional Specification refers also to Specifications 448,816, 448,817, 448,917, 687,414, 719,853, 721,674, 726,900, 731,930 and 748,772. The second Provisional Specification refers to Specification 776,346.
GB9904/56A 1956-03-29 1956-03-29 Improvements in the treatment of cellulose triacetate fibres Expired GB852729A (en)

Priority Applications (5)

Application Number Priority Date Filing Date Title
GB9904/56A GB852729A (en) 1956-03-29 1956-03-29 Improvements in the treatment of cellulose triacetate fibres
GB9844/57A GB852730A (en) 1956-03-29 1956-03-29 Improvements in the treatment of cellulose triacetate fibres
US644442A US3132919A (en) 1956-03-29 1957-03-07 Increasing safe ironing temperatures of cellulsoe triacetate fibers with swelling agents boiling above 190deg. c.
DEB43839A DE1045966B (en) 1956-03-29 1957-03-11 Process for increasing the permissible ironing temperature of products made from fibers or threads of cellulose triacetate, especially fabrics
FR1173094D FR1173094A (en) 1956-03-29 1957-03-20 Textile processing

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB9904/56A GB852729A (en) 1956-03-29 1956-03-29 Improvements in the treatment of cellulose triacetate fibres

Publications (1)

Publication Number Publication Date
GB852729A true GB852729A (en) 1960-11-02

Family

ID=9880950

Family Applications (2)

Application Number Title Priority Date Filing Date
GB9844/57A Expired GB852730A (en) 1956-03-29 1956-03-29 Improvements in the treatment of cellulose triacetate fibres
GB9904/56A Expired GB852729A (en) 1956-03-29 1956-03-29 Improvements in the treatment of cellulose triacetate fibres

Family Applications Before (1)

Application Number Title Priority Date Filing Date
GB9844/57A Expired GB852730A (en) 1956-03-29 1956-03-29 Improvements in the treatment of cellulose triacetate fibres

Country Status (4)

Country Link
US (1) US3132919A (en)
DE (1) DE1045966B (en)
FR (1) FR1173094A (en)
GB (2) GB852730A (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE635262A (en) * 1959-07-23
US3477806A (en) * 1965-10-15 1969-11-11 Celanese Corp Treatment of cellulose triacetate with selected compounds to introduce stretch properties

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1826608A (en) * 1925-10-29 1931-10-06 Celanese Corp Treatment of cellulose acetate or products made therewith
BE359123A (en) * 1928-06-06
GB380504A (en) * 1931-06-18 1932-09-19 British Celanese Improvements in textiles containing cellulose derivatives
US2073629A (en) * 1932-10-19 1937-03-16 Celanese Corp Treatment of textile materials
GB450936A (en) * 1935-01-23 1936-07-23 Henry Dreyfus Improvements relating to the manufacture or treatment of artificial filaments, threads, films and like materials
US2202804A (en) * 1937-08-14 1940-05-28 Commercial Solvents Corp Cellulose acetate composition
NL51049C (en) * 1938-05-28
US2328682A (en) * 1938-05-28 1943-09-07 Schnegg Robert Dyeing cellulose esters
US2514410A (en) * 1945-05-08 1950-07-11 Celanese Corp Printing of cellulose acetate using methyl cellulose as a thickener for strongly alcoholic dye solutions
GB758442A (en) * 1953-01-01 1956-10-03 British Celanese Improvements in cellulose acetate textile materials

Also Published As

Publication number Publication date
FR1173094A (en) 1959-02-19
GB852730A (en) 1960-11-02
US3132919A (en) 1964-05-12
DE1045966B (en) 1958-12-11

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