GB835749A - Improvements in or relating to preparations for protection against light, especiallysunlight - Google Patents
Improvements in or relating to preparations for protection against light, especiallysunlightInfo
- Publication number
- GB835749A GB835749A GB20727/56A GB2072756A GB835749A GB 835749 A GB835749 A GB 835749A GB 20727/56 A GB20727/56 A GB 20727/56A GB 2072756 A GB2072756 A GB 2072756A GB 835749 A GB835749 A GB 835749A
- Authority
- GB
- United Kingdom
- Prior art keywords
- group
- groups
- formula
- alkyl
- aralkyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
- A61Q17/04—Topical preparations for affording protection against sunlight or other radiation; Topical sun tanning preparations
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/41—Amines
- A61K8/416—Quaternary ammonium compounds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/49—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/49—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
- A61K8/4906—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with one nitrogen as the only hetero atom
- A61K8/4926—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with one nitrogen as the only hetero atom having six membered rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/06—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom containing only hydrogen and carbon atoms in addition to the ring nitrogen atom
- C07D213/16—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom containing only hydrogen and carbon atoms in addition to the ring nitrogen atom containing only one pyridine ring
- C07D213/20—Quaternary compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D213/78—Carbon atoms having three bonds to hetero atoms, with at the most one bond to halogen, e.g. ester or nitrile radicals
- C07D213/79—Acids; Esters
- C07D213/80—Acids; Esters in position 3
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D215/00—Heterocyclic compounds containing quinoline or hydrogenated quinoline ring systems
- C07D215/02—Heterocyclic compounds containing quinoline or hydrogenated quinoline ring systems having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen atoms or carbon atoms directly attached to the ring nitrogen atom
- C07D215/04—Heterocyclic compounds containing quinoline or hydrogenated quinoline ring systems having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen atoms or carbon atoms directly attached to the ring nitrogen atom with only hydrogen atoms or radicals containing only hydrogen and carbon atoms, directly attached to the ring carbon atoms
- C07D215/10—Quaternary compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D295/00—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms
- C07D295/04—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms
- C07D295/10—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms substituted by doubly bound oxygen or sulphur atoms
- C07D295/104—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms substituted by doubly bound oxygen or sulphur atoms with the ring nitrogen atoms and the doubly bound oxygen or sulfur atoms attached to the same carbon chain, which is not interrupted by carbocyclic rings
- C07D295/108—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms substituted by doubly bound oxygen or sulphur atoms with the ring nitrogen atoms and the doubly bound oxygen or sulfur atoms attached to the same carbon chain, which is not interrupted by carbocyclic rings to an acyclic saturated chain
Landscapes
- Organic Chemistry (AREA)
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Veterinary Medicine (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Epidemiology (AREA)
- Birds (AREA)
- Dermatology (AREA)
- Cosmetics (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
Abstract
The invention comprises compounds of the formula <FORM:0835749/IV (b)/1> or tautomeric forms thereof, in which R is an acyl group (e.g. acetyl), X is a halogen anion, and "Am" represents a 1-quinolyl- or (except where X is bromine) a 1-pyridyl group (which groups may be unsubstituted or substituted by one or more hydroxy, alkoxy or carbalkoxy groups) or indicates the group <FORM:0835749/IV (b)/2> where R1, R2 and R3, which may be the same or different, are aralkyl groups or C1-12 alkyl groups, or where any two of the substituents R1, R2 and R3 together with the nitrogen atom forms a saturated heterocyclic ring (e.g. piperidino or morpholino) and the remaining substituent is an aralkyl or C1-12 alkyl group. The compounds are prepared by reacting bases of the formula: H-Am with appropriate halogen acetophenones bearing a group R-NH- in para position to the keto group, and which may be prepared either by direct halogenation of the corresponding acetophenones or by a Friedel-Crafts condensation between a halogenacetic acid halide and a compound of the formula <FORM:0835749/IV (b)/3>ALSO:Compositions affording protection against sunlight and also functioning as skin disinfectants comprise one or more compounds of the formula <FORM:0835749/VI/1> or tautomeric forms thereof, in which R is an acyl group (e.g. acetyl), X is a halogen anion, and "Am" represents a 1-pyridyl- or a 1-quinolyl group (which groups may be unsubstituted or substituted by one or more C1-3 alkyl, hydroxy, alkoxy or carbalkoxy groups) or indicates the group <FORM:0835749/VI/2> where R1, R2 and R3, which may be the same or different, are hydrogen, C1-12 alkyl groups or aralkyl groups, or where any two of the substituents R1, R2 and R3 together with the nitrogen atom forms a saturated heterocyclic ring (which may also contain further hetero atoms) and the remaining substituent is a hydrogen atom or an aralkyl or C1-12 alkyl group, in combination with a base or carrier adapted for application to the skin, the active substance forming not more than 5% by weight of the preparation. Carriers or diluents include water, alcohol, cetyl-alcohol, beeswax, propylene glycol, sorbitol, paraffin oil, white petroleum jelly, woolfat, titanium dioxide, zinc oxide and/or talcum.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DET12299A DE1015986B (en) | 1955-07-04 | 1955-07-04 | Light and sun protection products |
DE348240X | 1955-07-04 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB835749A true GB835749A (en) | 1960-05-25 |
Family
ID=25828287
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB20727/56A Expired GB835749A (en) | 1955-07-04 | 1956-07-04 | Improvements in or relating to preparations for protection against light, especiallysunlight |
Country Status (4)
Country | Link |
---|---|
CH (1) | CH348240A (en) |
DE (1) | DE1015986B (en) |
FR (1) | FR1186159A (en) |
GB (1) | GB835749A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4234732A (en) * | 1974-05-02 | 1980-11-18 | General Electric Company | Photoinitiators |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2569193B2 (en) * | 1984-08-20 | 1987-01-16 | Lafon Labor | 1- (ACETYLAMINOPHENYL) -2-AMINO-PROPANONE DERIVATIVES, THEIR USE IN THERAPEUTICS AND THEIR PREPARATION PROCESS |
MA20246A1 (en) * | 1983-10-14 | 1985-07-01 | Lafon Labor | Process for the preparation of new derivatives of 1- (acetylaminophenyl) -2 aminopropanone. |
FR2553407B1 (en) * | 1983-10-14 | 1986-01-03 | Lafon Labor | N- (4-ACETYLAMINOPHENACYL) -AMINE DERIVATIVES, THEIR USE IN THERAPEUTICS AND THEIR PREPARATION METHOD |
FR2569186B1 (en) * | 1984-08-20 | 1986-09-05 | Lafon Labor | 1- (N- (A-AMINO-A-METHYLACETYL) -AMINOPHENYL) -2-AMINO-PROPANONE DERIVATIVES, PREPARATION METHOD AND THERAPEUTIC USE |
-
1955
- 1955-07-04 DE DET12299A patent/DE1015986B/en active Pending
-
1956
- 1956-06-27 CH CH348240D patent/CH348240A/en unknown
- 1956-07-04 FR FR1186159D patent/FR1186159A/en not_active Expired
- 1956-07-04 GB GB20727/56A patent/GB835749A/en not_active Expired
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4234732A (en) * | 1974-05-02 | 1980-11-18 | General Electric Company | Photoinitiators |
Also Published As
Publication number | Publication date |
---|---|
DE1015986B (en) | 1957-09-19 |
FR1186159A (en) | 1959-08-17 |
CH348240A (en) | 1960-08-15 |
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