GB825680A - Graft polymers and method of making the same - Google Patents

Graft polymers and method of making the same

Info

Publication number
GB825680A
GB825680A GB1598957A GB1598957A GB825680A GB 825680 A GB825680 A GB 825680A GB 1598957 A GB1598957 A GB 1598957A GB 1598957 A GB1598957 A GB 1598957A GB 825680 A GB825680 A GB 825680A
Authority
GB
United Kingdom
Prior art keywords
vinyl
polyvinyl
styrene
polymer
unsaturated
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB1598957A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dow Chemical Co
Original Assignee
Dow Chemical Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to US61577056A priority Critical
Application filed by Dow Chemical Co filed Critical Dow Chemical Co
Publication of GB825680A publication Critical patent/GB825680A/en
Application status is Expired legal-status Critical

Links

Abstract

Graft polymers are made by contacting a polymer containing at least one unsaturated double bond between adjacent carbon atoms, and in dry, solid particulate form, with ozone and then contacting the ozonized polymer with a grafting ethylenically unsaturated monomer capable of being polymerized by free radicals. Suitable base polymers are polyethylene, polypropylene, polybutadiene, polyisoprene, butadiene-styrene copolymers, polystyrene polyhalostyrenes, polyvinyltoluene, polyvinyl naphthalene, polyvinyl cyclohexane, divinyl benzene, polyvinyl indene, polyacrylates, polymethacrylates, polyacrylonitrile, polyvinyl chloride, vinyl and allyl siloxanes, polyamides, unsaturated polyesters and unsaturated fatty acid modified glycerol-phthalic acid polyesters. Grafting monomers specified are styrene, vinyl toluene, vinyl xylene, divinyl benzene, alphamethyl styrene, chlorostyrene, dichlorostyrene, tert.-butyl styrene, ethylene, butadiene, isoprene, vinyl halides, ethers, esters, ketones and amides, vinylidene chloride, vinyl pyrrolidone, ethyl and butyl acrylates, methyl methacrylate, acrylonitrile and methacrylonitrile. Prior to ozonization the unsaturation of the base polymer may be increased by milling or by exposure to ionizing radiations such as X-rays, gamma rays, neutrons or accelerated electrons. In preferred processes the base polymer is in the form of a film or fibre.
GB1598957A 1956-10-15 1957-05-20 Graft polymers and method of making the same Expired GB825680A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
US61577056A true 1956-10-15 1956-10-15

Publications (1)

Publication Number Publication Date
GB825680A true GB825680A (en) 1959-12-16

Family

ID=35385405

Family Applications (1)

Application Number Title Priority Date Filing Date
GB1598957A Expired GB825680A (en) 1956-10-15 1957-05-20 Graft polymers and method of making the same

Country Status (4)

Country Link
DE (1) DE1250635B (en)
FR (1) FR1177898A (en)
GB (1) GB825680A (en)
NL (1) NL96690C (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3242231A (en) * 1961-10-11 1966-03-22 Du Pont Process for making graft polymers with polysulfone grafts
EP0874009A1 (en) * 1996-01-10 1998-10-28 Kaneka Corporation Modified polypropylene resin, foam made from the resin and processes for the production of both

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1411704A (en) * 1964-04-29 1965-09-24 Pneumatiques, Caoutchouc Manufacture Et Plastiques Kleber Colombes cell polyolefin
FR2517682B1 (en) * 1981-12-03 1985-05-03 Centre Nat Rech Scient
FR2597489B1 (en) * 1986-04-22 1988-07-01 Charbonnages Ste Chimique Polyethylene-based resins, their process for the preparation and their use as binders in coatings.
US4978481A (en) * 1989-01-13 1990-12-18 Ciba-Geigy Corporation Process for the encapsulation of preformed substrates by graft copolymerization
US4968532A (en) * 1989-01-13 1990-11-06 Ciba-Geigy Corporation Process for graft copolymerization on surfaces of preformed substrates to modify surface properties
US4965026A (en) * 1989-01-13 1990-10-23 Ciba-Geigy Corporation Process for hydroxylating hydrophobic polymer surfaces
EA001545B1 (en) * 1999-12-07 2001-04-23 Зао "Карат 3" Process for modifying the surfaces of rubber crumbs

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3242231A (en) * 1961-10-11 1966-03-22 Du Pont Process for making graft polymers with polysulfone grafts
EP0874009A1 (en) * 1996-01-10 1998-10-28 Kaneka Corporation Modified polypropylene resin, foam made from the resin and processes for the production of both
EP0874009A4 (en) * 1996-01-10 1999-03-03 Kaneka Corp Modified polypropylene resin, foam made from the resin and processes for the production of both

Also Published As

Publication number Publication date
FR1177898A (en) 1959-04-30
DE1250635B (en) 1967-09-21
NL96690C (en) 1961-01-16

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