GB811658A - A process for the production of granular salt mixtures containing perborates - Google Patents
A process for the production of granular salt mixtures containing perboratesInfo
- Publication number
- GB811658A GB811658A GB17728/56A GB1772856A GB811658A GB 811658 A GB811658 A GB 811658A GB 17728/56 A GB17728/56 A GB 17728/56A GB 1772856 A GB1772856 A GB 1772856A GB 811658 A GB811658 A GB 811658A
- Authority
- GB
- United Kingdom
- Prior art keywords
- perborate
- solution
- salt
- water
- crystallization
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000011833 salt mixture Substances 0.000 title abstract 3
- 239000000243 solution Substances 0.000 abstract 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 7
- 238000005507 spraying Methods 0.000 abstract 6
- 238000002425 crystallisation Methods 0.000 abstract 5
- 230000008025 crystallization Effects 0.000 abstract 5
- 239000002245 particle Substances 0.000 abstract 5
- 150000003839 salts Chemical class 0.000 abstract 5
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 abstract 4
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 abstract 4
- 239000008187 granular material Substances 0.000 abstract 4
- 239000011777 magnesium Substances 0.000 abstract 4
- 229910052749 magnesium Inorganic materials 0.000 abstract 4
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 abstract 4
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 abstract 2
- 229920000388 Polyphosphate Polymers 0.000 abstract 2
- 229910021538 borax Inorganic materials 0.000 abstract 2
- AUYOHNUMSAGWQZ-UHFFFAOYSA-L dihydroxy(oxo)tin Chemical compound O[Sn](O)=O AUYOHNUMSAGWQZ-UHFFFAOYSA-L 0.000 abstract 2
- GVALZJMUIHGIMD-UHFFFAOYSA-H magnesium phosphate Chemical compound [Mg+2].[Mg+2].[Mg+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O GVALZJMUIHGIMD-UHFFFAOYSA-H 0.000 abstract 2
- 239000004137 magnesium phosphate Substances 0.000 abstract 2
- 229960002261 magnesium phosphate Drugs 0.000 abstract 2
- 229910000157 magnesium phosphate Inorganic materials 0.000 abstract 2
- 235000010994 magnesium phosphates Nutrition 0.000 abstract 2
- 239000000203 mixture Substances 0.000 abstract 2
- 239000001205 polyphosphate Substances 0.000 abstract 2
- 229910000027 potassium carbonate Inorganic materials 0.000 abstract 2
- 229940093956 potassium carbonate Drugs 0.000 abstract 2
- 235000011181 potassium carbonates Nutrition 0.000 abstract 2
- 229920006395 saturated elastomer Polymers 0.000 abstract 2
- 239000000344 soap Substances 0.000 abstract 2
- 229910000029 sodium carbonate Inorganic materials 0.000 abstract 2
- 229940001593 sodium carbonate Drugs 0.000 abstract 2
- 235000017550 sodium carbonate Nutrition 0.000 abstract 2
- 239000004328 sodium tetraborate Substances 0.000 abstract 2
- 235000010339 sodium tetraborate Nutrition 0.000 abstract 2
- 229910021653 sulphate ion Inorganic materials 0.000 abstract 2
- 239000007864 aqueous solution Substances 0.000 abstract 1
- 239000010419 fine particle Substances 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
- 230000004048 modification Effects 0.000 abstract 1
- 238000012986 modification Methods 0.000 abstract 1
- 239000012266 salt solution Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3942—Inorganic per-compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D9/00—Crystallisation
- B01D9/0036—Crystallisation on to a bed of product crystals; Seeding
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D9/00—Crystallisation
- B01D9/0059—General arrangements of crystallisation plant, e.g. flow sheets
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2/00—Processes or devices for granulating materials, e.g. fertilisers in general; Rendering particulate materials free flowing in general, e.g. making them hydrophobic
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2/00—Processes or devices for granulating materials, e.g. fertilisers in general; Rendering particulate materials free flowing in general, e.g. making them hydrophobic
- B01J2/14—Processes or devices for granulating materials, e.g. fertilisers in general; Rendering particulate materials free flowing in general, e.g. making them hydrophobic in rotating dishes or pans
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B15/00—Peroxides; Peroxyhydrates; Peroxyacids or salts thereof; Superoxides; Ozonides
- C01B15/055—Peroxyhydrates; Peroxyacids or salts thereof
- C01B15/12—Peroxyhydrates; Peroxyacids or salts thereof containing boron
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B15/00—Peroxides; Peroxyhydrates; Peroxyacids or salts thereof; Superoxides; Ozonides
- C01B15/055—Peroxyhydrates; Peroxyacids or salts thereof
- C01B15/12—Peroxyhydrates; Peroxyacids or salts thereof containing boron
- C01B15/123—Stabilisation of the solid compounds, subsequent to the preparation or to the crystallisation, by additives or by coating
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D11/00—Special methods for preparing compositions containing mixtures of detergents
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Glanulating (AREA)
- Detergent Compositions (AREA)
- Paper (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
Abstract
A composition containing a perborate is obtained by spraying a solution containing a salt which crystallizes with binding water of crystallization upon a moving layer of perborate particles not dispersed in air, the quantity and concentration of the sprayed-on solution being such that the water is completely bound as water of crystallization in the salt mixture. The spraying solution, which may be saturated, may comprise borax, sodium- or potassium-carbonate, -sulphate, -ortho, -pyro or -polyphosphates and may also contain dispersed magnesium or other insoluble silicate, magnesium phosphate, magnesium soaps or metastannic acid. The perborate may be wholly or partially dehydrated. The perborate particles may be at room temperature and the spraying solution may be at 15 DEG to 95 DEG C. As shown in Fig. 1, perborate particles are supplied from a vessel 1 via a metering device 2 and funnel 3 on to an inclined rotating plate 4, the inclination of which is adjustable. A calcined salt <PICT:0811658/III/1> <PICT:0811658/III/2> may be supplied from a vessel 5. The aqueous solution of the salt which crystallizes with binding water of crystallization (which may be the same salt as is contained in the vessel 5) is contained in a vessel 7 maintained under pressure by means of gas supplied from a conduit 8 and is sprayed upon the perborate from a nozzle 12, the conduit 10 to which may be heated by an element 11. The granulated material runs over the rim of the plate 4 into a funnel 13 and thence by a tube 14 into a vessel 15 to which air is supplied under pressure, thus impeding the fall of the granules and aiding delivery of the granules via pipes 19 and 20 to a separator 21 which is exhausted by a fan 27. From the separator 21, fine particles are withdrawn into a cyclone 23 and are returned to the funnel 3, and the separated granules are delivered to a shaker screen 28 and are removed through a tube 29. The coarse-grained material is broken up by a mill 30 and returned to the separator 21. In a modification, the rotating inclined plate 4 may be replaced by a rotating inclined cylinder 62, Fig. 3a, to which the perborate is delivered by a funnel 61 and the salt solution by nozzles 57.ALSO:A composition containing a perborate is obtained by spraying a solution containing a salt which crystallizes with binding water of crystallization upon a moving layer of perborate particles not dispersed in air, the quantity and concentration of the sprayed-on solution being such that the water is completely bound as water of crystallization in the salt mixture. The spraying solution, which may be saturated, may comprise borax, sodium- or potassiumcarbonate, -sulphate, -ortho-, -pyro-, or -polyphosphates and may also contain dispersed magnesium or other water-insoluble silicate, magnesium phosphate, magnesium soaps or metastannic acid. The perborate may be wholly or partially dehydrated. The perborate particles may be at room temperature and the spraying solution may be at 15 DEG to 95 DEG C.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEH0024133 | 1955-06-11 | ||
| DEH0024909 | 1955-09-08 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB811658A true GB811658A (en) | 1959-04-08 |
Family
ID=25979395
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB17728/56A Expired GB811658A (en) | 1955-06-11 | 1956-06-08 | A process for the production of granular salt mixtures containing perborates |
Country Status (7)
| Country | Link |
|---|---|
| US (2) | US2972584A (en) |
| BE (1) | BE548170A (en) |
| CH (1) | CH350274A (en) |
| DE (2) | DE1417131A1 (en) |
| FR (1) | FR1153767A (en) |
| GB (1) | GB811658A (en) |
| NL (2) | NL207905A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2700797A1 (en) * | 1977-01-11 | 1978-07-20 | Peroxid Chemie Gmbh | PROCESS FOR IMPROVING THE STORAGE LIFE OF OXYGEN-RELEASING COMPOUNDS |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL269436A (en) * | 1960-09-23 | |||
| NL297419A (en) * | 1962-09-04 | |||
| US3289312A (en) * | 1964-03-17 | 1966-12-06 | Fmc Corp | Drying of chlorinated isocyanurates and salts thereof |
| GB1585476A (en) * | 1976-11-01 | 1981-03-04 | Unilever Ltd | Slowdissolving perborate |
| FR2423536A1 (en) * | 1978-04-17 | 1979-11-16 | Interox | COMPOSITIONS AND METHOD FOR WASHING AND BLEACHING |
| GB8713756D0 (en) * | 1987-06-12 | 1987-07-15 | Procter & Gamble | Liquid detergent |
| EP0296813A1 (en) * | 1987-06-24 | 1988-12-28 | Imperial Chemical Industries Plc | Powder compositions and detergent compositions |
| IL115003A (en) | 1995-08-21 | 1999-12-22 | Green Top Wood Recycling Ltd | Agglomerate and a method for its manufacture |
| DE19635405A1 (en) * | 1996-08-31 | 1998-03-05 | Henkel Kgaa | Process for the production of granular detergent ingredients |
| DE102010013095A1 (en) * | 2010-03-29 | 2011-09-29 | Haver Engineering Gmbh | pelletizer |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2767146A (en) * | 1956-10-16 | Method of making cleaning | ||
| US1989759A (en) * | 1931-06-22 | 1935-02-05 | Swann Res Inc | Chlorinated alkaline silicate |
| DE739417C (en) * | 1937-10-03 | 1943-09-25 | Henkel & Cie Gmbh | Laundry detergents containing powdered per-compounds |
| US2524394A (en) * | 1946-12-23 | 1950-10-03 | Samuel L Madorsky | Method of manufacturing stable alkali hypochlorite compositions |
| US2706178A (en) * | 1951-02-10 | 1955-04-12 | Du Pont | Preparation of hydrated perborate products |
| US2765239A (en) * | 1952-05-21 | 1956-10-02 | Ciba Ltd | Process for the improvement of organic material |
| US2763618A (en) * | 1955-09-07 | 1956-09-18 | Pro Nyl Chemicals Inc | Whitening and brightening wash and rinse powder composition |
-
0
- NL NL110775D patent/NL110775C/xx active
- BE BE548170D patent/BE548170A/xx unknown
- NL NL207905D patent/NL207905A/xx unknown
-
1955
- 1955-06-11 DE DE19551417131 patent/DE1417131A1/en active Pending
- 1955-09-08 DE DE19551417132 patent/DE1417132A1/en active Pending
-
1956
- 1956-05-04 US US582886A patent/US2972584A/en not_active Expired - Lifetime
- 1956-05-04 US US582885A patent/US2975142A/en not_active Expired - Lifetime
- 1956-06-08 CH CH350274D patent/CH350274A/en unknown
- 1956-06-08 GB GB17728/56A patent/GB811658A/en not_active Expired
- 1956-06-08 FR FR1153767D patent/FR1153767A/en not_active Expired
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2700797A1 (en) * | 1977-01-11 | 1978-07-20 | Peroxid Chemie Gmbh | PROCESS FOR IMPROVING THE STORAGE LIFE OF OXYGEN-RELEASING COMPOUNDS |
Also Published As
| Publication number | Publication date |
|---|---|
| NL207905A (en) | |
| DE1417132A1 (en) | 1968-10-03 |
| DE1417131A1 (en) | 1968-10-03 |
| FR1153767A (en) | 1958-03-21 |
| NL110775C (en) | |
| US2972584A (en) | 1961-02-21 |
| CH350274A (en) | 1960-11-30 |
| US2975142A (en) | 1961-03-14 |
| BE548170A (en) |
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