DE739417C - Laundry detergents containing powdered per-compounds - Google Patents
Laundry detergents containing powdered per-compoundsInfo
- Publication number
- DE739417C DE739417C DEH153150D DEH0153150D DE739417C DE 739417 C DE739417 C DE 739417C DE H153150 D DEH153150 D DE H153150D DE H0153150 D DEH0153150 D DE H0153150D DE 739417 C DE739417 C DE 739417C
- Authority
- DE
- Germany
- Prior art keywords
- compounds
- per
- atomized
- powdery
- hot
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000003599 detergent Substances 0.000 title claims description 25
- 150000001875 compounds Chemical class 0.000 claims description 12
- 239000007787 solid Substances 0.000 claims description 8
- 239000000243 solution Substances 0.000 claims description 8
- 238000000034 method Methods 0.000 claims description 7
- 239000000725 suspension Substances 0.000 claims description 6
- 239000004615 ingredient Substances 0.000 claims description 5
- 239000000470 constituent Substances 0.000 claims description 3
- 239000000155 melt Substances 0.000 claims description 3
- 239000000654 additive Substances 0.000 claims description 2
- 238000000889 atomisation Methods 0.000 description 9
- 239000002245 particle Substances 0.000 description 9
- 239000000843 powder Substances 0.000 description 9
- 239000000344 soap Substances 0.000 description 7
- 239000000126 substance Substances 0.000 description 7
- 239000007789 gas Substances 0.000 description 6
- 239000000203 mixture Substances 0.000 description 6
- 229960001922 sodium perborate Drugs 0.000 description 5
- YKLJGMBLPUQQOI-UHFFFAOYSA-M sodium;oxidooxy(oxo)borane Chemical compound [Na+].[O-]OB=O YKLJGMBLPUQQOI-UHFFFAOYSA-M 0.000 description 5
- 239000007788 liquid Substances 0.000 description 4
- 150000004665 fatty acids Chemical group 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- CDBYLPFSWZWCQE-UHFFFAOYSA-L sodium carbonate Substances [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 3
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- 150000001447 alkali salts Chemical class 0.000 description 2
- 239000007795 chemical reaction product Substances 0.000 description 2
- 239000012459 cleaning agent Substances 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- -1 metaborate Chemical compound 0.000 description 2
- 239000003595 mist Substances 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 2
- 235000019353 potassium silicate Nutrition 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- 240000007124 Brassica oleracea Species 0.000 description 1
- 235000003899 Brassica oleracea var acephala Nutrition 0.000 description 1
- 235000011301 Brassica oleracea var capitata Nutrition 0.000 description 1
- 235000001169 Brassica oleracea var oleracea Nutrition 0.000 description 1
- KXDHJXZQYSOELW-UHFFFAOYSA-N Carbamic acid Chemical class NC(O)=O KXDHJXZQYSOELW-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- KEAYESYHFKHZAL-UHFFFAOYSA-N Sodium Chemical compound [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 description 1
- 239000004115 Sodium Silicate Substances 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical class OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 1
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 1
- 235000011130 ammonium sulphate Nutrition 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000027455 binding Effects 0.000 description 1
- 238000009739 binding Methods 0.000 description 1
- 229910021538 borax Inorganic materials 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 239000000645 desinfectant Substances 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 235000011180 diphosphates Nutrition 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- 239000004088 foaming agent Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 159000000011 group IA salts Chemical class 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 125000005341 metaphosphate group Chemical group 0.000 description 1
- 125000002496 methyl group Chemical class [H]C([H])([H])* 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 125000004433 nitrogen atom Chemical group N* 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 125000005342 perphosphate group Chemical group 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 229910000027 potassium carbonate Inorganic materials 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000005204 segregation Methods 0.000 description 1
- 239000001632 sodium acetate Substances 0.000 description 1
- 235000017281 sodium acetate Nutrition 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 235000019795 sodium metasilicate Nutrition 0.000 description 1
- 239000001488 sodium phosphate Substances 0.000 description 1
- 229910000162 sodium phosphate Inorganic materials 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- 239000004328 sodium tetraborate Substances 0.000 description 1
- 235000010339 sodium tetraborate Nutrition 0.000 description 1
- 238000001694 spray drying Methods 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
- 210000003462 vein Anatomy 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D11/00—Special methods for preparing compositions containing mixtures of detergents
- C11D11/02—Preparation in the form of powder by spray drying
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/06—Powder; Flakes; Free-flowing mixtures; Sheets
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3902—Organic or inorganic per-compounds combined with specific additives
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3942—Inorganic per-compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D9/00—Compositions of detergents based essentially on soap
- C11D9/04—Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
- C11D9/42—Per-compounds
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S159/00—Concentrating evaporators
- Y10S159/14—Soap
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Inorganic Chemistry (AREA)
- Combustion & Propulsion (AREA)
- Detergent Compositions (AREA)
Description
Pulverförmige Perverbindungen enthaltende Waschmittel Perverbindungen enthaltende pule erförmige Waschmittel werden meistenteils durch mechanisches Vermischen der Einzelbestandteile, die verschiedene spezifische Gewichte aufweisen, erhalten. Auf Grund dieser Tatsache kann unter Umständen leicht eine Entmischung . der Einzelbestandteile eintreten, was insbesondere bei der Anwendung der Wasch- und Reinigungsmittel von Nachteil sein kann. Es "sind zwar Waschmittel bekannt, die aus verschiedenen Einzelbestand; teilen bestehen und dennoch ein einheitliches Produkt darstellen. Derartige einheitliche Stoffmischungen werden. beispielsweise durch Zerstäubung von Lösungen, Suspensionen oder Schmelzen der einzelnen Waschmittelbestandteile in Zerstäubungsvorrichtungen hergestellt. Hierbei. werden voluminöse Pulver erhalten., die staubfrei sind und eine gleichmäßige Korngröße und Struktur aufweisen. Es ist jedoch nicht möglich, nach Verfahren der vorgenannten Art Waschmittel in Pulverform herzustellen, die Perverbindungen enthalten, da, um ein trockenes Waschpulver zu erhalten, das Gut heiß zerstäubt werden muß. Bei einer Zerstäubung von heißen Lösungen, Suspensionen oder Schmelzen, die außer den übrigen Waschmittelbestandteilen auch bereits Perv erbindun.gen enthalten, werden aber infolge der bei dem Zerstäuhungsvorgang erforderlichen hohen Temperatur und durch die Anwesenheit von Wasser die Perverbindungen zersetzt, wobei ihr wirksamer Bestandteil, der aktive Sauerstoff, verlorengeht. Aus diesem Grunde -,var man auch bei der 'Verwendung von Zerstäubungsprodukten darauf angewiesen, diese nachträglich mit den Perverbindungen zu vermischen, wodurch wiederum ein Stoffgemisch mit verschiedenen spezifischen Gewichten und den damit verbundenen Nachteilen erhalten wurde. Es wurde nun. gefunden, daß .man Perverbindungen enthaltende Waschmittel in Forin 'eines einheitlichen Pulvers von gleichmäßiger Korngröße und Struktur auf dem Wege der Zerstäubungstrocknung in einem Arbeitsgang dadurch erhält, daß man heiße Lösungen, Suspensionen oder Schmelzen .der Waschmittelbestandteile in Abwesenheit der Perverbindungen in Zerstäubungsvorr ichtungen in einem Gasstrom in Form eines Hohlkegels zerstäubt und gleichzeitig in den oberen: inneren Teil des' von den zerstäubten Teilchen gebildeten Hohlkegels die jeweils zur Verwendung gelangenden. Perveibindungen in pulverförmigem Zustand hinein-sprüht. Beim. Eintritt der fein zerstäubten Lösung in -den Gasstrom wird der größte Teil des Wassers sofort verdampft. Die zerstäubten Teilchen treffen in noch halbfeuchtem Zustand mit den entgegengeblasenen festen Teilchen der Perverbindungen zusammen und umschließen diese wie eine Isölierschicht. Dadurch sind die einzelnen Teilchen der Perv erbindungen gegen die Einwirkung auch eines heißen, wasserdampfhaltigen Gasstromes und der damit verursachten Zersetzung weitgehend geschützt. Man erhält auf diese Weise ein einheitliches. Pulver, bei -dem die einzelnen Teilchen der Perverbindüngen nicht mehr neben .den übrigen -Waschmittelbestandteilen liegen, sondern in diese eingelagert bzw. mit diesen verkittet sind. Die neuen. Wasch- und Reinigungsmittel sind' daher Produkte mit einheitlichem -spezifischem Gewicht, die sich nicht entmischen können.Detergents containing powdered per-compounds per-compounds containing coil-shaped detergents are mostly produced by mechanical mixing of the individual components that have different specific weights. Due to this fact, a segregation can easily occur under certain circumstances. of the individual components occur, which is especially true when using detergents and cleaning agents from Can be disadvantage. There are "detergents known that consist of different individual items; parts exist and still represent a uniform product. Such uniform Mixtures of substances are. for example by atomizing solutions, suspensions or melting the individual detergent constituents in atomizing devices manufactured. Here. voluminous powders are obtained, which are dust-free and have a uniform grain size and structure. However, it is not possible using the method of the aforementioned type to produce detergents in powder form, the In order to obtain a dry washing powder, per compounds contain the good must be atomized hot. When atomizing hot solutions, suspensions or melts which, in addition to the other detergent ingredients, are also already perv erbindun.gen included, but are required as a result of the atomization process high temperature and the presence of water decomposes the per compounds, its active ingredient, active oxygen, is lost. For this Basically, one should also rely on the use of atomization products, to mix these with the per compounds afterwards, which in turn creates a mixture of substances obtained with different specific weights and the disadvantages associated therewith became. It was now. found that .man containing per compounds Laundry detergent in forin 'of a uniform powder of uniform grain size and Structure is obtained by means of spray drying in one operation, that hot solutions, suspensions or melts .the detergent components in the absence of the per compounds in atomizing devices in a gas stream atomized in the form of a hollow cone and at the same time in the upper: inner part of the hollow cone formed by the atomized particles, the respective for use arriving. Perveibindings in a powdery state sprayed in. At the. entry The finely atomized solution in the gas stream gets most of the water instantly evaporates. The atomized particles hit the while still semi-moist counter-blown solid particles of the per compounds together and enclose this like an insulating layer. As a result, the individual particles are the perversions against the action of a hot gas stream containing water vapor and the resulting caused decomposition largely protected. In this way you get a uniform. Powder, in which the individual particles of the Perverbindüngen are no longer next to The rest of the detergent components are stored in them or with them these are cemented. The new. Detergents and cleaning agents are therefore products with a uniform -specific weight that cannot separate.
Es. ist zwar bereits bekannt, daß man zum ununterbrochenen schnellen Trocknen oder Eindampfen auch heißer, fein zerstäubter Flüssigkeiten, die einzutrocknende Flüssigkeit im oberen Teil eines Turmes fein verteilt und in den so gebildeten Flüssigkeitsnebel fein verteilte feste Stoffe mittels Säug- oder Preßluft oder mittels mechanischer Mittel einführt. Dieses Verfahren ist jedoch im vorliegenden Falle für das Einsprühen von festen Perv erbindungen in Pulverform ungeeignet, da durch das unmittelbare Einsprühen der festen, z. B. Perboratteilchen in den heißen Flüssigkeitsnebel der Waschmittelhestandteile eine Zersetzung des Perborats stattfindet.It. it is already known that one can go for uninterrupted speed Drying or evaporation of hot, finely atomized liquids that are to be dried Liquid finely distributed in the upper part of a tower and into the liquid mist formed in this way finely divided solid substances by means of suction or compressed air or by means of mechanical Introduces means. However, this method is for spraying in the present case of solid perv compounds in powder form unsuitable because of the immediate Spraying the solid, z. B. Perborate particles in the hot liquid mist of the Detergent ingredients a decomposition of the perborate takes place.
Die neuen Waschmittel entsprechen in ihrer Zusammensetzung bekannten Waschmittelkompositionen, die beispielsweise Seife, Seifenersatzstoffe, Schaummittel, Perverbin-. dungen und andere Stoffe enthalten. Als Perverbindungen können Perborate, wie Natriumperborat, -Percarbonate, Perphosphate, Perpyrophosphate, Anlagerungsv erbindungen von Wasserstoffsuperoxyd an- feste Substanzen, z. B. Natrium- oder Kaliumcarbonat, Natrium-. oder Ammoniumsulfat, Metaborat, Natriumphosphat oder -acetat, verwendet werden.. Auch können Stabilisatoren in Verbindung mit den Perverbindungen zur Verbendung gelangen.The composition of the new detergents corresponds to familiar ones Detergent compositions containing, for example, soap, soap substitutes, foaming agents, Perverbin-. contain chemicals and other substances. Perborates, such as sodium perborate, percarbonates, perphosphates, perpyrophosphates, Anlagungsv bindings of hydrogen peroxide solid substances, z. B. sodium or potassium carbonate, Sodium-. or ammonium sulfate, metaborate, sodium phosphate or acetate is used .. Stabilizers can also be used in connection with the Perverbindungen reach.
Unter den Stoffen mit ausgesprochener Wasch- und Reinigungswirkung können außer Seife auch Gemische der Natriumsalze der Schwefelsäureester höherer Fettalkohole, Salze von durch höhere Fettsäurereste acylierten Methyltaurinen und andere Seifenersatzstoffe zur Verwendung gelangen.Among the fabrics with pronounced washing and cleaning properties In addition to soap, mixtures of the sodium salts of the higher sulfuric acid esters can also be used Fatty alcohols, salts of methyl taurines acylated by higher fatty acid residues and other soap substitutes are used.
Die Waschmittel der vorliegenden Erfindung können weiterhin auch alkalische Salze, wie Wasserglas; Natriummetasilicat, Borax, Soda, Phosphate, beispielsweise Alkaliorthophosphate, -metaphosphate und -pyrophosphate, und ferner Alkalisalze solcher organischer Aminocarbonsäuren, die für jedes basische Stickstoffatom mehr als eine Carboxyl-.gruppe besitzen, enthalten.The detergents of the present invention can furthermore also be alkaline Salts such as water glass; Sodium metasilicate, borax, soda, phosphates, for example Alkali orthophosphates, metaphosphates and pyrophosphates, and also alkali salts such organic aminocarboxylic acids, which are more for each basic nitrogen atom as a carboxyl group.
Die einzelnen Arbeitsbedingungen des Verfahrens, wie .die Temperatur des Gasstromes, die Behandlungsdauer, der Luftumlauf und der Druck, mit dem die zu zerstäubende heiße Lösung, Schmelze oder Suspension sowie die pulverförmigen Perverbindüngen zerstäubt werden, können je nach der gewünschten Beschaffenheit des Waschmittels ausgewählt werden. Je nach der gewünschten Beschaffenheit des Endproduktes kann man den Gasstrom, in welchem .die Zerstäubung vorgenommen wird, im Gleichstrom oder im Gegenstrom zu den zerstäubten Teilchen. führen; auch kann man mit einem heißen oder kalten Gasstrom arbeiten. Mit den Perverbindungen können in trockener Form -auch gleichzeitig andere Stoffe in festem Zustand mit den übrigen Waschmittelbestandteilen vermischt werden; beispielsweise Stabilisierungsmittel, Desinfektionsmittel, Fällmittel ü. dgl.The individual working conditions of the process, such as the temperature of the gas flow, the duration of the treatment, the air circulation and the pressure with which the Hot solution, melt or suspension to be atomized, as well as the powdery Perverbindüngen can be atomized, depending on the desired texture of the detergent can be selected. Depending on the desired properties of the end product the gas flow in which the atomization is carried out can be used in cocurrent or in countercurrent to the atomized particles. to lead; also you can with one hot or cold gas flow. With the per connections can be in drier Form - also other substances in solid state at the same time with the other detergent ingredients be mixed; for example stabilizers, disinfectants, precipitants ü. like
In der Abb. h ist eine Vorrichtung zur Herstellung der neuen Perverbindungen enthaltenden Waschmittel. schematisch im Schnitt wiedergegeben- In dieser Zeichnung bedeutet g einen Zerstäubungsturm, .der an seinem unteren Teil kegelförmig.gestal.tet ist und am untersten Ende eine Vorrichtung f zum Austragen'.des fertigen Pulvers besitzt; d ist eine Vorrichtung für die Zufuhr heißer Ader kalter Glase, beispielsweise Luft, Stickstoff oder Kohlensäure, die durch e bzw. durch die ringförmig angeordneten Luftschlitze h entweichen können. In dem oberen Teil des Zerstäubtingsturmes ist eine Zerstäuberdüse a angebracht, durch die eine Lösung, Schmelze oder Suspension der Waschmittelbestandtei.le in Form eines Hohlkegels c in den Zerstäubungstuim eingeblasen werden kann; b ist eine Zerstäuburigsdüse zum Zerstäuben der pulverförmigen Perverbindungen oder Mischungen derselben mit anderen pulverförmigen Zusatzstoffen. Es- äst wesentlich, daß der Abstand der Düsen a und b so gewählt wird, daB die pulverförmigen Pervexbindungen stets in den oberen inneren Teil des Hohlkegels c gelangen. Dabei ist es nicht erforderlich, daß die Düsen a und b in der beschriebenen Anordnung unbedingt im oberen Teil des Zarsfäubungstumes angebracht sind. Sie können sich auch in der Mitte oder am unteren Ende des Zerstäubungsturmes befinden, je nachdem, ob man die Zerstäubung innerhalb des Turmes von oben nach unten oder von-unten nach oben vornimmt-. Die Zerstäubungsdüsen d und b sind in den Abb. II und III nochmals besonders wiedergegeben. Die Zerstäubungsdüse a (vgl. Abb. II), durch welche. das zerstäubte Gut in Hohlkegelform -gebracht wird, besteht im wesentlichen aus einem metallischen Hohlkegel k,- in: dessen Spitze sich die Düsenöffnung n befindet. Vor der- Spitze n. befindet sich eine Einsatz o mit Spiralen nt. Wenn ilas zu zerstäubende Gut, das durch L' eingeführt wird, durch diese Düse hindurchgedrückt wird, wird es durch den Spiralengang fz in drehende Bewegung versetzt und verläßt den Aufsatz k in Hohlkegelform.In Fig. H is a device for the preparation of the new detergent containing per compounds. shown schematically in section - In this drawing, g denotes an atomization tower, which is conical-shaped at its lower part and has a device f for discharging the finished powder at the lower end; d is a device for the supply of hot veins of cold glass, for example air, nitrogen or carbonic acid, which can escape through e or through the annularly arranged air slots h. In the upper part of the atomizing tower is an atomizing nozzle a through which a solution, melt or suspension of the detergent constituents can be blown into the atomizing tube in the form of a hollow cone c; b is an atomizing nozzle for atomizing the powdery per compounds or mixtures thereof with other powdery additives. It is essential that the distance between the nozzles a and b is chosen so that the powdery pervex bonds always reach the upper inner part of the hollow cone c. It is not necessary that the nozzles a and b in the described arrangement are necessarily attached in the upper part of the Zarsfäubungstumes. They can also be located in the middle or at the lower end of the atomization tower, depending on whether the atomization inside the tower is from top to bottom or from bottom to top. The atomizing nozzles d and b are shown again in Figs. II and III. The atomizing nozzle a (see Fig. II) through which. the atomized material is brought into a hollow cone shape, consists essentially of a metallic hollow cone k, - in: the tip of which is the nozzle opening n . In front of the tip n. There is an insert o with spirals nt. When the material to be atomized, which is introduced through L ', is pressed through this nozzle, it is set in rotating motion by the spiral path fz and leaves the attachment k in the form of a hollow cone.
Die in Abb.III wiedergegebene Zerstäubungsdüse für die pulverförmigen Perverbindungen besteht aus einem konischen Zylinder r, in dem sich ein Kegel s befindet. Das zü zerstäubende Pulver tritt bei t in die Düsen ein und verläBt :die Düse durch den von .dem Kegel und dem konischen Zylinder gebildeten Kohlraum u..The atomizing nozzle shown in Fig. III for the powdery Per connections consists of a conical cylinder r, in which there is a cone s is located. The powder to be atomized enters the nozzles at t and leaves: the Nozzle through the cabbage space formed by the cone and the conical cylinder and
In Ausübung des neuen Verfahrens wird beispielsweise eine heiße, wässerige Lösung, die etwa ¢3 Gewichtsteile Seife, 17 Gewichtsteile Soda und 3 Gewichtsteile Wasserglas enthält, in der im vorstehenden beschriebenen Zerstäubungsvorrichtung durch die Düse a in Fbrm eines Hohlkegels in den Turm eingesprüht. Gleichzeitig wird festes, pulverförmiges Natriumperborat durch .die Düse b in den inneren Teil des Hohlkegels eingeblasen. Dabei wird die Zufuhrgeschwindigkeit des Natriumperborates derart bemessen, daB im Endprodukt ein Gehalt von etwa ioo% Natriumperborat vgrh:anden ist. Die aus der Düse b austretenden Perboratteilrchen gelangen in denjenigen Teil des Hohlkegels, in dem der Abstand der den Hohlkegel bildenden Teilchen noch sehr gering ist. Dadurch wird erreicht, daß die einzelnen Natriumperboratkörner von den: halbfeuchten, zerstäubten übrigen Waschmittelbestandteilen umschlossen werden. Auf diese Weise wird ein -einheitliches Pulver gewonnen, das im Gegenstrom zu dem aus d austretenden heißen Luftstrom durch den Turm herabrieselt und dabei vollkommen getrocknet wird. Die Zerstäubungstemperatur beträgt in der oberen Hälfte des Zerstäubungst.urmes etwa 14o0, in dem' unteren Teil des Zerstäubungsturmes nimmt die Temperatur beständig so ab, daß in dem untersten Ende des Turmes etwa eine Temperatur von 35°besteht. Gegebenenfalls kann auch noch Kaltluft zur weiteren Kühlung des zerstÄubten Materials an gesonderten Stellen zugeführt werden. Das fertige Waschmittel sammelt sich in dem unteren konischen Ende des Zerstäubungsturmes an und! wird durch die. Schleuse f aus dem Turm ausgetragen.In the practice of the new process, for example, a hot, watery Solution containing about ¢ 3 parts by weight of soap, 17 parts by weight of soda and 3 parts by weight Contains water glass in the atomizing device described above sprayed through the nozzle a in the shape of a hollow cone into the tower. Simultaneously solid, powdery sodium perborate is passed through nozzle b into the inner part blown into the hollow cone. The feed rate of the sodium perborate is thereby dimensioned in such a way that the end product has a content of about 100% sodium perborate is. The perborate particles emerging from nozzle b reach that part of the hollow cone, in which the distance between the particles forming the hollow cone is still very high is low. This ensures that the individual grains of sodium perborate from the: semi-moist, atomized remaining detergent ingredients are enclosed. on in this way a uniform powder is obtained, which flows in countercurrent to that from d emerging hot air stream trickles down through the tower and is completely is dried. The atomization temperature is in the upper half of the atomization tower about 14o0, in the lower part of the atomizing tower the temperature increases steadily so that there is a temperature of about 35 ° in the lowest end of the tower. If necessary, cold air can also be used for further cooling of the atomized material are fed in at separate locations. The finished detergent collects in the lower conical end of the atomization tower and! is through the. lock f discharged from the tower.
Im Rahmen des vorstehenden Verfahrens kann man an Stelle von Seife auch Fettalkoholsulfonate, Alkalisalze von durchi Oxydaxion von Paraffinen erhaltenen Fettsäuren, von durch höhere Fettsäurereste acylierten Mebhyltaurinen oder andere Seifenersatzstoffe verwenden.In the above procedure, you can use soap in place of also fatty alcohol sulfonates, alkali salts obtained by oxydaxion of paraffins Fatty acids, from mebhyltaurines acylated by higher fatty acid residues or others Use soap substitutes.
Claims (1)
Priority Applications (7)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEH153150D DE739417C (en) | 1937-10-03 | 1937-10-03 | Laundry detergents containing powdered per-compounds |
| CH207197D CH207197A (en) | 1937-10-03 | 1938-08-18 | Mixture containing per compounds which can be used as washing, cleaning, bleaching and rinsing agents. |
| NL89436A NL57004C (en) | 1937-10-03 | 1938-08-22 | |
| GB24954/38A GB518576A (en) | 1937-10-03 | 1938-08-24 | Improvements in or relating to the manufacture of washing, cleansing, bleaching and rinsing agents |
| FR842831D FR842831A (en) | 1937-10-03 | 1938-08-31 | Washing, cleaning, bleaching and rinsing products containing percompounds |
| BE430021D BE430021A (en) | 1937-10-03 | 1938-09-03 | |
| US232359A US2308992A (en) | 1937-10-03 | 1938-09-29 | Method for producing washing, cleansing, bleaching, and rinsing agents containing percompounds |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEH153150D DE739417C (en) | 1937-10-03 | 1937-10-03 | Laundry detergents containing powdered per-compounds |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE739417C true DE739417C (en) | 1943-09-25 |
Family
ID=5793580
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DEH153150D Expired DE739417C (en) | 1937-10-03 | 1937-10-03 | Laundry detergents containing powdered per-compounds |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US2308992A (en) |
| BE (1) | BE430021A (en) |
| CH (1) | CH207197A (en) |
| DE (1) | DE739417C (en) |
| FR (1) | FR842831A (en) |
| GB (1) | GB518576A (en) |
| NL (1) | NL57004C (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1103500B (en) * | 1959-02-28 | 1961-03-30 | Miag Muehlenbau & Ind Gmbh | Method and device for adding perborate to washing powder consisting of hollow cones |
| WO2007079803A1 (en) * | 2005-12-29 | 2007-07-19 | Henkel Kommanditgesellschaft Auf Aktien | Improved method for producing washing or cleaning agents |
Families Citing this family (35)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2579944A (en) * | 1945-04-09 | 1951-12-25 | Colgate Palmolive Peet Co | Process and apparatus for coating particulate material |
| US2706178A (en) * | 1951-02-10 | 1955-04-12 | Du Pont | Preparation of hydrated perborate products |
| US2809150A (en) * | 1951-02-26 | 1957-10-08 | Procter & Gamble | Bromate-perhydrate fixing composition |
| BE536668A (en) * | 1953-03-12 | |||
| DE968415C (en) * | 1953-07-03 | 1958-02-13 | Procter & Gamble | Soapy washing powder with little tendency to form lumps |
| US2795556A (en) * | 1954-07-26 | 1957-06-11 | Theobald Ind | Composition providing available chlorine and process of making same |
| DE1058675B (en) * | 1955-03-03 | 1959-06-04 | Kurt Lindner Dr | Self-acting cleaning, washing and washing aids |
| BE546607A (en) * | 1955-04-08 | |||
| US2901435A (en) * | 1955-04-18 | 1959-08-25 | Olin Mathieson | Spray drying calcium hypochlorite slurry |
| US3257324A (en) * | 1955-04-20 | 1966-06-21 | Colgate Palmolive Co | Solid bleach composition and method of making and using same |
| NL110775C (en) * | 1955-06-11 | |||
| DE1062381B (en) * | 1955-12-16 | 1959-07-30 | Kurt Lindner Dr | Self-acting cleaning, washing and washing aids |
| US2925390A (en) * | 1955-12-20 | 1960-02-16 | Monsanto Chemicals | Process for control of product density of spray-dried detergent compositions |
| NL205102A (en) * | 1956-01-23 | |||
| US2897154A (en) * | 1956-07-30 | 1959-07-28 | Purex Corp Ltd | Bleaching and disinfecting compositions |
| US3093590A (en) * | 1956-08-08 | 1963-06-11 | Purex Corp Ltd | Trichlorocyanuric acid bleach with spray-dried base |
| CH361272A (en) * | 1956-11-09 | 1962-04-15 | Degussa | Method of crumbling perborate |
| US2863835A (en) * | 1957-10-08 | 1958-12-09 | Theobald Ind | Perborate composition |
| US3042622A (en) * | 1957-11-01 | 1962-07-03 | Colgate Palmolive Co | Abrasive cleaning composition |
| US3042621A (en) * | 1957-11-01 | 1962-07-03 | Colgate Palmolive Co | Detergent composition |
| BE597383A (en) * | 1959-11-24 | |||
| US3008904A (en) * | 1959-12-29 | 1961-11-14 | Jr Benjamin M Johnson | Processing of radioactive waste |
| US3421842A (en) * | 1965-09-30 | 1969-01-14 | Fmc Corp | Process for producing effervescent perborate compounds |
| US3441388A (en) * | 1965-12-14 | 1969-04-29 | Fmc Corp | Effervescent compounds and process for producing same |
| ZA670520B (en) * | 1966-02-26 | |||
| AU413469B2 (en) * | 1966-03-09 | 1971-05-24 | Knapsack Ag | Process forthe manufacture of detergent compositions |
| US3819526A (en) * | 1970-12-23 | 1974-06-25 | Philadelphia Quartz Co | Coated detergent compositions |
| US4002524A (en) * | 1971-09-10 | 1977-01-11 | Aktieselskabet Niro Atomizer | Method and apparatus for evaporating liquid |
| US4105827A (en) * | 1973-04-20 | 1978-08-08 | Interox | Particulate peroxygen compounds coated with sodium sesquicarbonate or Na2 SO4 mNa2 CO3 |
| DE2349211C3 (en) * | 1973-10-01 | 1979-06-21 | Metallgesellschaft Ag, 6000 Frankfurt | Process for drying and simultaneous agglomeration of metal salts |
| JPS53960B2 (en) * | 1974-03-23 | 1978-01-13 | ||
| DE2431529C2 (en) * | 1974-07-01 | 1982-11-18 | Henkel KGaA, 4000 Düsseldorf | Process for the production of spray-dried detergents containing nonionic surfactants |
| US4042174A (en) * | 1976-06-21 | 1977-08-16 | Vaughn Alvie G | Nozzle adapter |
| DE3833648A1 (en) * | 1988-10-04 | 1990-04-05 | Henkel Kgaa | METHOD FOR PRODUCING PARTICLE-DETERGENT DETERGENTS |
| IT1295226B1 (en) * | 1997-10-14 | 1999-05-04 | Magneti Marelli Spa | PLANT FOR THE PRODUCTION OF PRESSED OR INJECTION-PRINTED PRODUCTS USING SALT CORE. |
-
1937
- 1937-10-03 DE DEH153150D patent/DE739417C/en not_active Expired
-
1938
- 1938-08-18 CH CH207197D patent/CH207197A/en unknown
- 1938-08-22 NL NL89436A patent/NL57004C/xx active
- 1938-08-24 GB GB24954/38A patent/GB518576A/en not_active Expired
- 1938-08-31 FR FR842831D patent/FR842831A/en not_active Expired
- 1938-09-03 BE BE430021D patent/BE430021A/xx unknown
- 1938-09-29 US US232359A patent/US2308992A/en not_active Expired - Lifetime
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1103500B (en) * | 1959-02-28 | 1961-03-30 | Miag Muehlenbau & Ind Gmbh | Method and device for adding perborate to washing powder consisting of hollow cones |
| WO2007079803A1 (en) * | 2005-12-29 | 2007-07-19 | Henkel Kommanditgesellschaft Auf Aktien | Improved method for producing washing or cleaning agents |
Also Published As
| Publication number | Publication date |
|---|---|
| US2308992A (en) | 1943-01-19 |
| FR842831A (en) | 1939-06-20 |
| NL57004C (en) | 1944-10-16 |
| BE430021A (en) | 1938-10-31 |
| GB518576A (en) | 1940-03-01 |
| CH207197A (en) | 1939-10-15 |
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