GB801522A - Manufacture of pigment dispersions - Google Patents

Manufacture of pigment dispersions

Info

Publication number
GB801522A
GB801522A GB26321/54A GB2632154A GB801522A GB 801522 A GB801522 A GB 801522A GB 26321/54 A GB26321/54 A GB 26321/54A GB 2632154 A GB2632154 A GB 2632154A GB 801522 A GB801522 A GB 801522A
Authority
GB
United Kingdom
Prior art keywords
pigment
aqueous
acid
resin
mol
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB26321/54A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hoechst AG
Original Assignee
Hoechst AG
Farbwerke Hoechst AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hoechst AG, Farbwerke Hoechst AG filed Critical Hoechst AG
Publication of GB801522A publication Critical patent/GB801522A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09CTREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C3/00Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
    • C09C3/003Flushing

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Pigments, Carbon Blacks, Or Wood Stains (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Inks, Pencil-Leads, Or Crayons (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)

Abstract

Aqueous pigment (e.g. carbon black, azo-, phthalocyanine-, and other pigment dyes) dispersions are prepared by kneading a hydrous pigment or pigment-dye press cake with an acid resin in neutral or acid medium, the resin being kneadable at room temperature or being rendered kneadable by the application of heat, until a good blend is obtained, eliminating the separated water and treating the pigment dye preparation obtained by a change of phase, with an aqueous alkaline liquid, preferably aqueous ammonia. In an example an aqueous press cake of carbon black is kneaded with a polyacrylonitrile which has been 80 per cent hydrolysed, water is separated and the carbon black resin phase dissolved in aqueous ammonia. Other acidic natural or synthetic resins may be used, e.g. shellac, copolymers of vinyl esters with unsaturated acids, incompletely condensed alkyd resins or polyamides.ALSO:Aqueous pigment dispersions are prepared by kneading a hydrous pigment or pigment dye press cake with an acid resin in neutral or acid medium, the resin being kneadable at room temperature or being rendered kneadable by the application of heat, until a good blend is obtained, eliminating the separated water and treating the pigment dye preparation obtained by a change of phase, with an aqueous alkaline liquid, preferably aqueous ammonia. The term "acid resin" is defined as a resin having free carboxylic acid groups enabling it to be dissolved in alkali so that pigment dispersions may be obtained which contain only pigment dyestuff particles in the dispersed phase and in the dispersion medium a solution of a salt os the resin. Specified resins include copolymerf of vinyl acetate or propionate or chloride with acids such as maleic, fumaric, crotonic, acrylic, methacrylic or cinnamic acid; a copolymer of vinyl butyl ether and maleic anhydride; hydrolysis products of polymers containing ester, nitrile or acid anhydride groups; incompletely condensed resins of polybasic acids and polyhydric alcohols or polyamines; and shellac. Specified alkalies are sodium and potassium hydroxides and carbonates, sodium and ammonium bicarbonates, borax, ethylene diamine and di- or tri-ethanolamine. Any pigment insensitive to acids or alkalies may be used such as mono- or dis-azo, vat and phthalocyanine dyestuffs and carbon black (see Group III). In examples: (1) an aqueous press cake of Hansa Yellow G is kneaded with the resin obtained by condensing 1.2 mols. of phthalic acid with 1 mol. of hexane-triol-(1 : 3 : 5), water is eliminated, the pigment-resin phase is kneaded further with aqueous ammonia and then water is added to give an aqueous dispersion; (2) as in (1) using Indanthrene Red Violet RH and a mixture of the resins obtained by copolymerizing crotonic acid with vinylacetate and propionate; (3) as in (1) using the azo dyestuff 1-amino-2-methyl-4-chlorobenzene --> 1 - (21:31 - hydroxynaphthoylamino) - 2 - methyl - 4 - chlorobenzene, a copolymer of vinyl acetate and crotonic acid and aqueous sodium hydroxide; (4) as in (1) using the azo dyestuff 4-nitro-2-aminotoluene --> 1 - (21:31 - hydroxynaphtholyamino) - 4 - chlorobenzene, shellac and aqueous borax, sodium hydroxide, sodium carbonate, sodium bicarbonate, ammonium carbonate, ammonium bicarbonate or ammonia; (5) as in (1) using the disazo dyestuff 3:31-dichlorobenzidine (1 mol.) --> acetoacetanilide (2 mols.), a copolymer of vinyl butyl ether and maleic anhydride and aqueous sodium carbonate or sodium hydroxide; (6) as in (1) using copper phthalocyanine, the esterification product of 1 mol. of methanol with the copolymer of 1 mol. of maleic anhydride and 1 mol. of vinyl butyl ether and ammonia or ammonium carbonate; (7) as in (1) using tetradecachloro-copper phthalocyanine, a copolymer of 7 mols. of ethyl acrylate and 3 mols. of acrylic acid and potassium carbonate or hydroxide; (8) as in (1) using carbon black, a polyacrylonitrile which has been 80 per cent hydrolysed and ammonia; (9) as in (1) using the azo dyestuff 2-chloro-4-nitroaniline --> 2-naphthol, the condensation product of 1:2 mols. of phthalic anhydride and 1 mol. of hexanetriol-(1 : 3 : 5).ALSO:Aqueous pigment dispersions are prepared by kneading a hydrous pigment or pigment dye press cake with an acid resin in neutral or acid medium, the resin being kneadable at room temperature or being rendered kneadable by the application of heat, until a good blend is obtained, eliminating the separated water and treating the pigment dye preparation obtained by a change of phase, with an aqueous alkaline liquid, preferably aqueous ammonia. The term "acid resin" is defined as a resin having free carboxylic acid groups enabling it to be dissolved in alkali so that pigment dispersions may be obtained which contain only pigment dyestuff particles in the dispersed phase and in the dispersion medium a solution of a salt of the resin. Specified resins include copolymers of vinyl acetate or propionate or chloride with acids such as maleic, fumaric, crotonic, acrylic, methacrylic or cinnamic acid; a copolymer of vinyl butyl ether and maleic anhydride; hydrolysis products of polymers containing ester, nitrile or acid anhydride groups; incompletely condensed resins of polybasic acids and polyhydric alcohols or polyamines; and shellac. Specified alkalies are sodium and potassium hydroxides and carbonates, sodium and ammonium bicarbonates, borax, ethylene diamine and di- or tri-ethanolamine. Any pigment insensitive to acids or alkalies may be used such as mono- or dis-azo, vat and phthalocyanine dyestuffs and carbon black (see Group III). In examples: (1) an aqueous press cake of Hansa Yellow G is kneaded with the resin obtained by condensing 1.2 mols. of phthalic acid with 1 mol. of hexane-triol-(1 : 3 : 5), water is eliminated, the pigment-resin phase is kneaded further with aqueous ammonia and then water is added to give an aqueous dispersion; (2) as in (1) using Indanthrene Red Violet RH and a mixture of the resins obtained by copolymerizing crotonic acid with vinylacetate and propionate; (3) as in (1) using the azo dyestuff 1-amino-2-methyl-4-chlorobenzene --> 1 - (21 : 31 - hydroxynaphthoylamino) - 2-methyl-4-chlorobenzene, a copolymer of vinyl acetate and crotonic acid and aqueous sodium hydroxide; (4) as in (1) using the azo dyestuff 4 - nitro - 2 - aminotoluene --> 1 - (21 : 31-hydroxynaphthoylamino) - 4 - chlorobenzene, shellac and aqueous borax, sodium hydroxide, sodium carbonate, sodium or carbonate, ammonium carbonate, ammonium bicarbonate or ammonia; (5) as in (1) using the disazo dyestuff 3 : 31 - dichlorobenzidine (1 mol.) \sQ acetoacetanilide (2 mols.), a copolymer of vinyl butyl ether and maleic anhydride and aqueous sodium carbonate or sodium hydroxide; (6) as in (1) using copper phthalocyanine, the product of esterification of 1 mol. of methanol with the copolymer of 1 mol. of maleic anhydride and 1 mol. of vinyl butyl ether and ammonia or ammonium carbonate; (7) as in (1) using tetradecachlora-copper phthalocyanine, a copolymer of 7 mols. of ethyl acrylate and 3 mols. of acrylic acid and potassium carbonate or hydroxide; (9) as in (1) using the azo dyestuff 2-chloro - 4 - nitroaniline --> 2 - naphthol, the condensation product of 1 : 2 mols. of phthalic anhydride and 1 mol. of hexane-triol-(1 : 3 : 5).
GB26321/54A 1953-09-12 1954-09-10 Manufacture of pigment dispersions Expired GB801522A (en)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
DE329729X 1953-09-12
DEF12824A DE1013374B (en) 1953-09-12 1953-09-12 Process for the production of aqueous pigment dispersions
DE801522X 1953-09-12
DE1113317X 1953-09-12

Publications (1)

Publication Number Publication Date
GB801522A true GB801522A (en) 1958-09-17

Family

ID=61198495

Family Applications (1)

Application Number Title Priority Date Filing Date
GB26321/54A Expired GB801522A (en) 1953-09-12 1954-09-10 Manufacture of pigment dispersions

Country Status (5)

Country Link
BE (1) BE535049A (en)
CH (1) CH329729A (en)
DE (1) DE1013374B (en)
FR (1) FR1113317A (en)
GB (1) GB801522A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4729796A (en) * 1980-10-21 1988-03-08 Hoechst Aktiengesellschaft Process for preparing pigment granules from aqueous suspension of pigment and alkaline solution of resin

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR853209A (en) * 1938-04-19 1940-03-13 Improvements in the preparation of paste pigments for the manufacture of cellulosic and synthetic paints and enamels
BE450384A (en) * 1942-05-13
US2543211A (en) * 1947-02-28 1951-02-27 Ohio Commw Eng Co Aqueous dispersion of a pigmented alkyd resin

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4729796A (en) * 1980-10-21 1988-03-08 Hoechst Aktiengesellschaft Process for preparing pigment granules from aqueous suspension of pigment and alkaline solution of resin

Also Published As

Publication number Publication date
BE535049A (en) 1955-07-22
FR1113317A (en) 1956-03-28
CH329729A (en) 1958-05-15
DE1013374B (en) 1957-08-08

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