GB354696A - Manufacture of pigments in high state of dispersion - Google Patents
Manufacture of pigments in high state of dispersionInfo
- Publication number
- GB354696A GB354696A GB4201/30A GB420130A GB354696A GB 354696 A GB354696 A GB 354696A GB 4201/30 A GB4201/30 A GB 4201/30A GB 420130 A GB420130 A GB 420130A GB 354696 A GB354696 A GB 354696A
- Authority
- GB
- United Kingdom
- Prior art keywords
- aqueous solution
- cellulose
- aqueous
- pigments
- solution
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
Abstract
Pigments in a highly dispersed state are formed by producing the pigment in the presence of an aqueous solution of a cellulose derivative which coagulates when heated. Suitable cellulose derivatives are methyl celluloses, aqueous solutions of which coagulate between 50 and 80 DEG C. and some ethyl celluloses which are soluble in ice-water but which coagulate at room temperature. The pigments may be made by double decomposition with metal salt solutions, by coupling diazo-compounds with suitable components, by oxidizing bases which form pigments or by oxidizing leuco-compounds. The flocks of coloured coagulated cellulose derivatives may be washed and dried and used to produce coloured varnishes by solution in solvents such as alcohols or hydrocarbons with or without usual varnish constituents. Aqueous pastes of the coloured cellulose derivative may be mixed with non-aqueous solutions of cellulose derivatives. In examples: (1) Ferric ammonium sulphate in aqueous solution is precipitated with potassium ferrocyanide in the presence of a 5 per cent aqueous solution of methyl cellulose. The blue solution is coagulated by heat, and the coagulum washed with water until free from salts. (2) A similar process is effected, interaction occurring between aqueous solutions of cadmium sulphate and ammonium sulphydrate to produce the pigment. (3) An aqueous solution of sodium chromate and methyl cellulose is mixed with an aqueous solution of lead nitrate and methyl cellulose. The yellow solution is coagulated by heating and the coagulum washed with hot water. The coagulum may be heated and used liquid as an "aquarell" colour or as a printing colour. It may be worked up with softening agents, resins, solutions of cellulose esters or ethers, &c. to form varnishes.ALSO:Pigments in a highly dispersed state are formed by producing the pigment in the presence of an aqueous solution of a cellulose derivative which coagulates when heated. Suitable cellulose derivatives are methyl celluloses, aqueous solutions of which coagulate between 50 DEG and 80 DEG C. and some ethyl celluloses which are soluble in ice-water but which coagulate at room temperature. The pigments may be made by double decomposition with metal salt solutions, by coupling diazo-compounds with suitable components, by oxidizing bases which form pigments or by oxidizing leuco-compounds. The flocks of coloured coagulated cellulose derivatives may be washed and dried and used to produce coloured varnishes by solution in solvents such as alcohols or hydrocarbons with or without usual varnish constituents. Aqueous pastes of the coloured cellulose derivative may be mixed with non-aqueous solutions of cellulose derivatives. In example (1) Ferric ammonium sulphate in aqueous solution is precipitated with potassium ferrocyanide in the presence of a 5 per cent aqueous solution of methyl cellulose. The blue solution is coagulated by heat and the coagulum washed with water until free from salts. (2) A similar process is effected, interaction occurring between aqeuous solutions of cadmium sulphate and ammonium sulphydrate to produce the pigment. (3) An aqueous solution of sodium chromate and methyl cellulose is mixed with a aqueous solution of lead nitrate and methyl cellulose. The yellow solution is coagulated by heating and the coagulum washed with hot water. The coagulum may be heated and used liquid as an "aquarell" colour.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE354696X | 1929-02-07 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB354696A true GB354696A (en) | 1931-08-13 |
Family
ID=6289771
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB4201/30A Expired GB354696A (en) | 1929-02-07 | 1930-02-07 | Manufacture of pigments in high state of dispersion |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB354696A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE875798C (en) * | 1950-08-01 | 1953-05-07 | Henkel & Cie Gmbh | Color preparation separately |
US2701211A (en) * | 1949-03-17 | 1955-02-01 | British Celanese | Process for production of pigmented film-forming materials |
-
1930
- 1930-02-07 GB GB4201/30A patent/GB354696A/en not_active Expired
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2701211A (en) * | 1949-03-17 | 1955-02-01 | British Celanese | Process for production of pigmented film-forming materials |
DE875798C (en) * | 1950-08-01 | 1953-05-07 | Henkel & Cie Gmbh | Color preparation separately |
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