GB799750A - Method for making cellular materials - Google Patents
Method for making cellular materialsInfo
- Publication number
- GB799750A GB799750A GB37625/56A GB3762556A GB799750A GB 799750 A GB799750 A GB 799750A GB 37625/56 A GB37625/56 A GB 37625/56A GB 3762556 A GB3762556 A GB 3762556A GB 799750 A GB799750 A GB 799750A
- Authority
- GB
- United Kingdom
- Prior art keywords
- phthalate
- plastisol
- borohydride
- vinyl chloride
- copolymer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/06—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent
- C08J9/065—Hydrides or carbides
Landscapes
- Chemical & Material Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Cellular vinyl chloride resins are made by expanding a plastisol by reacting therein water and a borohydride of sodium, potassium, rubidium or caesium (whereby hydrogen is liberated), and heating the expanded plastisol to gel and fuse it. The plastisol is a dispersion of a homopolymer of vinyl chloride, a copolymer of vinyl chloride (e.g. with vinylidene chloride, vinyl acetate or ethyl maleate) or a mixture of homopolymer and copolymer (e.g. a mixture of polyvinyl chloride and a vinyl chloride/vinylidene chloride copolymer), dispersed in a liquid plasticizer (e.g. dioctyl phthalate, diisoctyl phthalate, isooctyl isodecyl phthalate, octyl butyl phthalate, butyl decyl phthalate, didecyl phthalate, dioctyl adipate, tricresyl phosphate, trioctyl phosphate or acetyl tributyl citrate) and if desired additives such as stabilizers, fillers or colourants. Reaction between the borohydride and water is effected by lowering the pH and/or by heating. The borohydride may be added to the plastisol as such or in the form of an aqueous solution or dispersed in a plasticizer. Alternatively, separate plastisol components may be formed one containing the borohydride and the other the water and the two plastisols mixed in a mould.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US799750XA | 1955-12-19 | 1955-12-19 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB799750A true GB799750A (en) | 1958-08-13 |
Family
ID=22153994
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB37625/56A Expired GB799750A (en) | 1955-12-19 | 1956-12-10 | Method for making cellular materials |
Country Status (2)
Country | Link |
---|---|
FR (1) | FR1168994A (en) |
GB (1) | GB799750A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0107064A1 (en) * | 1982-09-28 | 1984-05-02 | The B.F. GOODRICH Company | Process for making low density chlorinated polyvinyl chloride foam |
-
1956
- 1956-12-10 GB GB37625/56A patent/GB799750A/en not_active Expired
- 1956-12-19 FR FR1168994D patent/FR1168994A/en not_active Expired
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0107064A1 (en) * | 1982-09-28 | 1984-05-02 | The B.F. GOODRICH Company | Process for making low density chlorinated polyvinyl chloride foam |
Also Published As
Publication number | Publication date |
---|---|
FR1168994A (en) | 1958-12-19 |
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