GB796285A - Stabilisation of polyethylenes against oxidative degradation - Google Patents
Stabilisation of polyethylenes against oxidative degradationInfo
- Publication number
- GB796285A GB796285A GB30994/54A GB3099454A GB796285A GB 796285 A GB796285 A GB 796285A GB 30994/54 A GB30994/54 A GB 30994/54A GB 3099454 A GB3099454 A GB 3099454A GB 796285 A GB796285 A GB 796285A
- Authority
- GB
- United Kingdom
- Prior art keywords
- methyl
- sulphides
- polyethylene
- butyl
- butylphenol
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- -1 polyethylenes Polymers 0.000 title abstract 6
- 229920000573 polyethylene Polymers 0.000 title abstract 5
- 239000004698 Polyethylene Substances 0.000 title abstract 4
- 238000010525 oxidative degradation reaction Methods 0.000 title 1
- 230000006641 stabilisation Effects 0.000 title 1
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 abstract 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 abstract 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 abstract 3
- 150000003568 thioethers Chemical class 0.000 abstract 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 abstract 2
- 125000000217 alkyl group Chemical group 0.000 abstract 2
- 239000003381 stabilizer Substances 0.000 abstract 2
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 abstract 2
- MGSRCZKZVOBKFT-UHFFFAOYSA-N thymol Chemical compound CC(C)C1=CC=C(C)C=C1O MGSRCZKZVOBKFT-UHFFFAOYSA-N 0.000 abstract 2
- XOUQAVYLRNOXDO-UHFFFAOYSA-N 2-tert-butyl-5-methylphenol Chemical compound CC1=CC=C(C(C)(C)C)C(O)=C1 XOUQAVYLRNOXDO-UHFFFAOYSA-N 0.000 abstract 1
- TUAMRELNJMMDMT-UHFFFAOYSA-N 3,5-xylenol Chemical compound CC1=CC(C)=CC(O)=C1 TUAMRELNJMMDMT-UHFFFAOYSA-N 0.000 abstract 1
- UDKXBTXJJRJURD-UHFFFAOYSA-N 3-dodecyl-2-methylphenol Chemical compound CCCCCCCCCCCCC1=CC=CC(O)=C1C UDKXBTXJJRJURD-UHFFFAOYSA-N 0.000 abstract 1
- OSDLLIBGSJNGJE-UHFFFAOYSA-N 4-chloro-3,5-dimethylphenol Chemical compound CC1=CC(O)=CC(C)=C1Cl OSDLLIBGSJNGJE-UHFFFAOYSA-N 0.000 abstract 1
- JKINPMFPGULFQY-UHFFFAOYSA-N 4-tert-butyl-3-methylphenol Chemical compound CC1=CC(O)=CC=C1C(C)(C)C JKINPMFPGULFQY-UHFFFAOYSA-N 0.000 abstract 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 abstract 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 abstract 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 abstract 1
- 239000005844 Thymol Substances 0.000 abstract 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 abstract 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- RECUKUPTGUEGMW-UHFFFAOYSA-N carvacrol Chemical compound CC(C)C1=CC=C(C)C(O)=C1 RECUKUPTGUEGMW-UHFFFAOYSA-N 0.000 abstract 1
- HHTWOMMSBMNRKP-UHFFFAOYSA-N carvacrol Natural products CC(=C)C1=CC=C(C)C(O)=C1 HHTWOMMSBMNRKP-UHFFFAOYSA-N 0.000 abstract 1
- 235000007746 carvacrol Nutrition 0.000 abstract 1
- UOCJDOLVGGIYIQ-PBFPGSCMSA-N cefatrizine Chemical group S([C@@H]1[C@@H](C(N1C=1C(O)=O)=O)NC(=O)[C@H](N)C=2C=CC(O)=CC=2)CC=1CSC=1C=NNN=1 UOCJDOLVGGIYIQ-PBFPGSCMSA-N 0.000 abstract 1
- 125000001309 chloro group Chemical group Cl* 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 238000004132 cross linking Methods 0.000 abstract 1
- SNRUBQQJIBEYMU-UHFFFAOYSA-N dodecane Chemical group CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 abstract 1
- 239000000975 dye Substances 0.000 abstract 1
- 229920001038 ethylene copolymer Polymers 0.000 abstract 1
- 239000000945 filler Substances 0.000 abstract 1
- WYXXLXHHWYNKJF-UHFFFAOYSA-N isocarvacrol Natural products CC(C)C1=CC=C(O)C(C)=C1 WYXXLXHHWYNKJF-UHFFFAOYSA-N 0.000 abstract 1
- 125000001972 isopentyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])C([H])([H])* 0.000 abstract 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 abstract 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 abstract 1
- 238000003801 milling Methods 0.000 abstract 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 abstract 1
- 239000003960 organic solvent Substances 0.000 abstract 1
- 230000001590 oxidative effect Effects 0.000 abstract 1
- 150000002989 phenols Chemical class 0.000 abstract 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 abstract 1
- 239000000049 pigment Substances 0.000 abstract 1
- 125000001424 substituent group Chemical group 0.000 abstract 1
- FWMUJAIKEJWSSY-UHFFFAOYSA-N sulfur dichloride Chemical compound ClSCl FWMUJAIKEJWSSY-UHFFFAOYSA-N 0.000 abstract 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 abstract 1
- 229960000790 thymol Drugs 0.000 abstract 1
- 239000008096 xylene Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
- C08K5/37—Thiols
- C08K5/372—Sulfides, e.g. R-(S)x-R'
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/04—Carbon
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
- C08K5/37—Thiols
- C08K5/375—Thiols containing six-membered aromatic rings
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Organic Insulating Materials (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US796285XA | 1953-10-27 | 1953-10-27 | |
| US836664XA | 1956-11-29 | 1956-11-29 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB796285A true GB796285A (en) | 1958-06-11 |
Family
ID=26762230
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB30994/54A Expired GB796285A (en) | 1953-10-27 | 1954-10-27 | Stabilisation of polyethylenes against oxidative degradation |
| GB36818/57A Expired GB836664A (en) | 1953-10-27 | 1957-11-26 | Stabilized hydrocarbon polymeric materials |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB36818/57A Expired GB836664A (en) | 1953-10-27 | 1957-11-26 | Stabilized hydrocarbon polymeric materials |
Country Status (5)
| Country | Link |
|---|---|
| BE (1) | BE561883A (enrdf_load_stackoverflow) |
| DE (1) | DE1118449B (enrdf_load_stackoverflow) |
| FR (1) | FR1184009A (enrdf_load_stackoverflow) |
| GB (2) | GB796285A (enrdf_load_stackoverflow) |
| NL (1) | NL221491A (enrdf_load_stackoverflow) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3020258A (en) * | 1959-08-31 | 1962-02-06 | Phillips Petroleum Co | Odor inhibitors for olefin polymers |
| US3028363A (en) * | 1959-08-31 | 1962-04-03 | Phillips Petroleum Co | Odor inhibitors for olefin polymers |
| US3069384A (en) * | 1958-03-12 | 1962-12-18 | Ethyl Corp | Sulfur-containing phenolic compounds |
| US3070569A (en) * | 1959-10-08 | 1962-12-25 | Thiokol Chemical Corp | Stabilizing polyethylene with carbon, a polymeric phenol sulfide, and an organic reducing agent |
| US3086960A (en) * | 1960-04-22 | 1963-04-23 | Goodyear Tire & Rubber | Compositions of polyamides and sulfides of dialkylated phenols |
| DE1158250B (de) * | 1959-04-06 | 1963-11-28 | Du Pont | Stabilisierte Polypropylen-Formmassen |
| US3252911A (en) * | 1960-04-01 | 1966-05-24 | Ethyl Corp | Organic materials stabilized with thiophenolic antioxidant compounds |
| GB2119386A (en) * | 1982-04-02 | 1983-11-16 | Konishiroku Photo Ind | Optical element and plastic composition for optical use |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2971940A (en) * | 1959-03-20 | 1961-02-14 | Ferro Corp | Nickel phenolate stabilized polypropylene |
| DE1111382B (de) * | 1959-05-02 | 1961-07-20 | Basf Ag | Stabilisierte Formmasse aus Polyolefinen |
| US3726928A (en) * | 1969-11-24 | 1973-04-10 | Ferro Corp | 2,2{40 -thiobis(4,6-di-tert.-butylresourcinol) |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB496966A (en) * | 1936-07-25 | 1938-12-09 | Standard Oil Dev Co | An improved manufacture of stabilised hydrocarbon polymers |
| US2727879A (en) * | 1951-12-11 | 1955-12-20 | Du Pont | Stabilized ethylene polymer compositions |
-
0
- BE BE561883D patent/BE561883A/xx unknown
- NL NL221491D patent/NL221491A/xx unknown
-
1954
- 1954-10-27 GB GB30994/54A patent/GB796285A/en not_active Expired
-
1957
- 1957-10-07 FR FR1184009D patent/FR1184009A/fr not_active Expired
- 1957-10-14 DE DEW22036A patent/DE1118449B/de active Pending
- 1957-11-26 GB GB36818/57A patent/GB836664A/en not_active Expired
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3069384A (en) * | 1958-03-12 | 1962-12-18 | Ethyl Corp | Sulfur-containing phenolic compounds |
| DE1158250B (de) * | 1959-04-06 | 1963-11-28 | Du Pont | Stabilisierte Polypropylen-Formmassen |
| US3020258A (en) * | 1959-08-31 | 1962-02-06 | Phillips Petroleum Co | Odor inhibitors for olefin polymers |
| US3028363A (en) * | 1959-08-31 | 1962-04-03 | Phillips Petroleum Co | Odor inhibitors for olefin polymers |
| US3070569A (en) * | 1959-10-08 | 1962-12-25 | Thiokol Chemical Corp | Stabilizing polyethylene with carbon, a polymeric phenol sulfide, and an organic reducing agent |
| US3252911A (en) * | 1960-04-01 | 1966-05-24 | Ethyl Corp | Organic materials stabilized with thiophenolic antioxidant compounds |
| US3086960A (en) * | 1960-04-22 | 1963-04-23 | Goodyear Tire & Rubber | Compositions of polyamides and sulfides of dialkylated phenols |
| GB2119386A (en) * | 1982-04-02 | 1983-11-16 | Konishiroku Photo Ind | Optical element and plastic composition for optical use |
Also Published As
| Publication number | Publication date |
|---|---|
| BE561883A (enrdf_load_stackoverflow) | |
| DE1118449B (de) | 1961-11-30 |
| FR1184009A (fr) | 1959-07-16 |
| NL221491A (enrdf_load_stackoverflow) | |
| GB836664A (en) | 1960-06-09 |
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