GB793050A - Oil-soluble metal containing compositions and process for making same - Google Patents
Oil-soluble metal containing compositions and process for making sameInfo
- Publication number
- GB793050A GB793050A GB10608/55A GB1060855A GB793050A GB 793050 A GB793050 A GB 793050A GB 10608/55 A GB10608/55 A GB 10608/55A GB 1060855 A GB1060855 A GB 1060855A GB 793050 A GB793050 A GB 793050A
- Authority
- GB
- United Kingdom
- Prior art keywords
- metal
- compound
- carbon dioxide
- groups
- compounds
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M159/00—Lubricating compositions characterised by the additive being of unknown or incompletely defined constitution
- C10M159/12—Reaction products
- C10M159/20—Reaction mixtures having an excess of neutralising base, e.g. so-called overbasic or highly basic products
- C10M159/22—Reaction mixtures having an excess of neutralising base, e.g. so-called overbasic or highly basic products containing phenol radicals
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C37/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring
- C07C37/64—Preparation of O-metal compounds with O-metal group bound to a carbon atom belonging to a six-membered aromatic ring
- C07C37/66—Preparation of O-metal compounds with O-metal group bound to a carbon atom belonging to a six-membered aromatic ring by conversion of hydroxy groups to O-metal groups
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/06—Metal compounds
- C10M2201/062—Oxides; Hydroxides; Carbonates or bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/02—Hydroxy compounds
- C10M2207/023—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/02—Hydroxy compounds
- C10M2207/023—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings
- C10M2207/025—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings with condensed rings
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/02—Hydroxy compounds
- C10M2207/023—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings
- C10M2207/027—Neutral salts thereof
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/02—Hydroxy compounds
- C10M2207/023—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings
- C10M2207/028—Overbased salts thereof
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/04—Ethers; Acetals; Ortho-esters; Ortho-carbonates
- C10M2207/046—Hydroxy ethers
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2211/00—Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions
- C10M2211/04—Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions containing carbon, hydrogen, halogen, and oxygen
- C10M2211/042—Alcohols; Ethers; Aldehydes; Ketones
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2211/00—Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions
- C10M2211/06—Perfluorinated compounds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/20—Containing nitrogen-to-oxygen bonds
- C10M2215/202—Containing nitrogen-to-oxygen bonds containing nitro groups
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
- C10M2219/044—Sulfonic acids, Derivatives thereof, e.g. neutral salts
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
- C10M2219/046—Overbasedsulfonic acid salts
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2010/00—Metal present as such or in compounds
- C10N2010/02—Groups 1 or 11
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2010/00—Metal present as such or in compounds
- C10N2010/04—Groups 2 or 12
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Lubricants (AREA)
Abstract
The invention comprises oil-soluble compositions of metal with hydroxyaromatic compounds, having a metal ratio of greater than 2 obtainable by heating a fluid mass containing an alkylated hydroxyaromatic compound and at least 2 equivalents of a basic inorganic compound of a metal of Groups I and II of the Periodic Table per equivalent of aromatic compound, to drive off substantially all free water which may be present, and treating the product with CO2 until its titratable basicity is substantially reduced. Preferred aromatic compounds are those containing an alkyl group of at least 6 carbon atoms, e.g. 2-methylamyl-4 diisobutyl, tetrapropyl, octadecyl and polyisobutyl, although cycloalkyl groups, e.g. cyclohexyl and methylcyclohexyl groups, may be present. Substituents such as halogen atoms and nitro and alkoxy groups may be present in the aromatic compound. Basic metal compounds mentioned are oxides, hydroxides, carbonates, bicarbonates sulphides and hydrosulphides. Alkali and alkaline earth metal compounds are preferred. Water is added to the reaction mixtures to fluidize the metal compound. Heating with CO2 usually takes place at above 100 DEG C. The neutralization number of the product should be less than about 10. The amount of CO2 used is in excess of 25 per cent by weight of that of the metal phenate being treated. The products are dispersants for mineral lubricating oils (see Group III. In illustrative examples, products are obtained by heating at temperatures varying from 150 DEG to 170 DEG C. in the presence of carbon dioxide and optionally a mineral oil as a diluent, fluid masses obtained from polyisobutyl- or dieicosyl-phenol, or an alkylation product of hydroquinone with polyisobutene, or octyl-b -naphthol, with the addition of water and barium oxide or sodium or lithium hydroxide or mixtures of barium oxide with sodium or potassium hydroxide.ALSO:Oil-soluble combinations of metal with hydroxyaromatic compounds, having a metal ratio of more than 2 and obtainable by heating a fluid mass containing an alkylated hydroxyaromatic compound and at least 2 equivalents of a basic inorganic compound of a metal of Groups I and II of the Periodic Table per equivalent of aromatic compound, to drive off substantially all free water which may be present, and treating the product with carbon dioxide until its titrable basicity is substantially reduced, are added to mineral lubricating oils to serve as dispersants. The neutralization number of the phenolic product should be less than about 10. The preparation of the additive may be effected in a mineral oil diluent. Preferred aromatic compounds are those containing an alkyl group of at least 6 carbon atoms, e.g. 2-methylamyl-4, diisobutyl, tetrapropyl, octadecyl and polyisobutyl groups, although cycloalkyl groups, e.g. cyclohexyl and methylcyclohexyl groups, may be present. The aromatic compounds may contain substituents such as halogen atoms and nitro and alkoxy groups. Basic metal compounds mentioned are oxides, hydroxides, carbonates, bicarbonates, sulphides and hydrosulphides. Alkali and alkaline earth metal compounds are preferred. Water is added to the reaction mixture to fluidize the metal compound. Treatment with carbon dioxide usually takes place at above about 100 DEG C. The amount of carbon dioxide used is in excess of 25 per cent by weight of that of the metal phenate being treated. The dispersants may be used in lubricating oils alone or with other additives such as metal mahogany sulphonates, especially a carbon dioxide-treated basic sulphonate obtained by heating a normal metal sulphonate with a basic metal compound and treating the product with carbon dioxide. In examples products are obtained by heating at temperatures varying from 150-170 DEG C. in the presence of carbon dioxide and optionally a mineral oil as diluent, fluid masses obtained by adding water to polyisobutyl- or di-eicosylphenol, or an alkylation product of hydroquinone with polyisobutene, or octyl-b -naphthol, admixed with barium oxide or sodium or lithium hydroxide or mixtures of barium oxide with sodium or potassium hydroxide.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US793050XA | 1954-07-08 | 1954-07-08 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB793050A true GB793050A (en) | 1958-04-09 |
Family
ID=22149682
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB10608/55A Expired GB793050A (en) | 1954-07-08 | 1955-04-13 | Oil-soluble metal containing compositions and process for making same |
Country Status (2)
Country | Link |
---|---|
FR (1) | FR1138739A (en) |
GB (1) | GB793050A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2009086140A2 (en) * | 2007-12-28 | 2009-07-09 | Chevron Oronite Company Llc | Low temperature performance lubricating oil detergents and method of making the same |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB921124A (en) * | 1959-12-15 | 1963-03-13 | Exxon Research Engineering Co | Process for preparing petroleum oil additives |
-
1955
- 1955-04-13 GB GB10608/55A patent/GB793050A/en not_active Expired
- 1955-05-06 FR FR1138739D patent/FR1138739A/en not_active Expired
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2009086140A2 (en) * | 2007-12-28 | 2009-07-09 | Chevron Oronite Company Llc | Low temperature performance lubricating oil detergents and method of making the same |
WO2009086140A3 (en) * | 2007-12-28 | 2009-09-03 | Chevron Oronite Company Llc | Low temperature performance lubricating oil detergents and method of making the same |
US8993499B2 (en) | 2007-12-28 | 2015-03-31 | Chevron Oronite Company Llc | Low temperature performance lubricating oil detergents and method of making the same |
Also Published As
Publication number | Publication date |
---|---|
FR1138739A (en) | 1957-06-19 |
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