GB785765A - Method of refining hydrocarbons or hydrocarbon fractions by catalytic hydrogenation - Google Patents

Method of refining hydrocarbons or hydrocarbon fractions by catalytic hydrogenation

Info

Publication number
GB785765A
GB785765A GB698355A GB698355A GB785765A GB 785765 A GB785765 A GB 785765A GB 698355 A GB698355 A GB 698355A GB 698355 A GB698355 A GB 698355A GB 785765 A GB785765 A GB 785765A
Authority
GB
United Kingdom
Prior art keywords
gas
alumina
treatment
hydrocarbons
washing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB698355A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
GEA Group AG
Original Assignee
Metallgesellschaft AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Metallgesellschaft AG filed Critical Metallgesellschaft AG
Publication of GB785765A publication Critical patent/GB785765A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
    • C10G45/04—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G49/00—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00
    • C10G49/18—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00 in the presence of hydrogen-generating compounds, e.g. ammonia, water, hydrogen sulfide

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

Hydrocarbons are refined by treatment, under a pressure of 5-100 atmos. and a temperature of over 300 DEG C., with a gas containing carbon monoxide and hydrogen in the presence of a sulphur-resistant catalyst having a basis of cobalt and/or molybdenum compounds and alumina, and of 5-50 per cent of water vapour by volume of the fresh gas entering the hydrogenation zone. The gas may be coke oven gas, coal gas, low-temperature carbonization gas, pressure gasification gas, oil refinery gas or water gas. The catalysts may be one containing cobalt oxide or sulphite, molybdic acid and alumina, or one containing aluminium oxide, molybdic acid, cobalt hydroxide and graphite. Hydrocarbon fractions referred to are gasoline, benzene, and a mixture, obtained from the gasification of gas, coal, consisting of gasoline and an oil, boiling up to 210 DEG C. The treated hydrocarbons may be washed with caustic alkali followed by washing with dilute sulphuric acid and/or treatment with bleaching earth, alumina, silica gel or activated charcoal; this treatment may be carried out in the presence of a gas containing hydrogen and/or of water vapour. Alternatively, the treated hydrocarbons may be fractionated. Refined product in the residual gas may be recovered by adsorption with activated charcoal, cooling, or washing out with washing oil. The residual gas may be recycled.
GB698355A 1954-11-25 1955-03-09 Method of refining hydrocarbons or hydrocarbon fractions by catalytic hydrogenation Expired GB785765A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DEM25278A DE1002904B (en) 1954-11-25 1954-11-25 Process for refining hydrocarbons or hydrocarbon fractions by means of hydrogenating catalytic treatment

Publications (1)

Publication Number Publication Date
GB785765A true GB785765A (en) 1957-11-06

Family

ID=7299501

Family Applications (1)

Application Number Title Priority Date Filing Date
GB698355A Expired GB785765A (en) 1954-11-25 1955-03-09 Method of refining hydrocarbons or hydrocarbon fractions by catalytic hydrogenation

Country Status (2)

Country Link
DE (1) DE1002904B (en)
GB (1) GB785765A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2021086762A1 (en) * 2019-10-31 2021-05-06 Saudi Arabian Oil Company Enhanced hydroprocessing process with ammonia and carbon dioxide recovery

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1132276B (en) * 1957-03-15 1962-06-28 Exxon Research Engineering Co Process for the production of heat-resistant jet fuels
DE1109816B (en) * 1957-11-16 1961-06-29 Metallgesellschaft Ag Process for the catalytic hydrogenative refining of hydrocarbons
NL280336A (en) * 1958-06-03

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB308297A (en) * 1928-03-21 1930-06-10 Standard Oil Dev Co An improved manufacture of petroleum products of the type known as "white oils"
US1981305A (en) * 1929-08-10 1934-11-20 Union Oil Co Process and apparatus for the catalytic treatment of petroleum
GB345378A (en) * 1930-01-08 1931-03-26 Frank Sherratt Improvements in, or relating to, dinner wagons or the like
NL41060C (en) * 1933-01-13

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2021086762A1 (en) * 2019-10-31 2021-05-06 Saudi Arabian Oil Company Enhanced hydroprocessing process with ammonia and carbon dioxide recovery

Also Published As

Publication number Publication date
DE1002904B (en) 1957-02-21

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