GB783045A - Catalyst for the polymerisation of air-drying unsaturated polyester resins - Google Patents

Catalyst for the polymerisation of air-drying unsaturated polyester resins

Info

Publication number
GB783045A
GB783045A GB3585755A GB3585755A GB783045A GB 783045 A GB783045 A GB 783045A GB 3585755 A GB3585755 A GB 3585755A GB 3585755 A GB3585755 A GB 3585755A GB 783045 A GB783045 A GB 783045A
Authority
GB
United Kingdom
Prior art keywords
derived
dicyclopentadiene
carbon monoxide
per cent
polyhydric alcohols
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB3585755A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Huels AG
Original Assignee
Chemische Werke Huels AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Chemische Werke Huels AG filed Critical Chemische Werke Huels AG
Publication of GB783045A publication Critical patent/GB783045A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F283/00Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
    • C08F283/01Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to unsaturated polyesters

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Paints Or Removers (AREA)
  • Macromonomer-Based Addition Polymer (AREA)
  • Polyesters Or Polycarbonates (AREA)

Abstract

Unsaturated polyesters derived from polyhydric alcohols having condensed ring systems with endomethylene groups, are copolymerized with 20 to 50 per cent of a vinyl compound, e.g. styrene, by the use of 3 to 6 per cent of cumene hydroperoxide preferably dissolved in a hydrocarbon. The polyhydric alcohols may be derived from Diels-Alder adducts of cyclopentadiene or from dicyclopentadiene, e.g. by treatment with carbon monoxide and hydrogen followed by hydrogenation. Polymerization accelerators such as cobalt naphthenate or octoate, zirconium octoate or tertiary amines, and dyestuffs, fillers and pigments may be included. In the example the polyester is derived from fumaric acid, phthalic anhydride and a diol obtained from dicyclopentadiene, carbon monoxide and hydrogen, by esterification in the presence of trichlorethyl phosphorous acid ester and hydroquinone. The compositions are air drying and gelatinize very quickly when applied as lacquers on wood, metal or glass, but have improved pot-life. Specification 766,666 is referred to.
GB3585755A 1955-11-22 1955-12-14 Catalyst for the polymerisation of air-drying unsaturated polyester resins Expired GB783045A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DEC12145A DE1035291B (en) 1955-11-22 1955-11-22 Catalyst for the hardening of air-drying paints based on unsaturated polyester resins

Publications (1)

Publication Number Publication Date
GB783045A true GB783045A (en) 1957-09-18

Family

ID=7015145

Family Applications (1)

Application Number Title Priority Date Filing Date
GB3585755A Expired GB783045A (en) 1955-11-22 1955-12-14 Catalyst for the polymerisation of air-drying unsaturated polyester resins

Country Status (3)

Country Link
DE (1) DE1035291B (en)
FR (1) FR1156266A (en)
GB (1) GB783045A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106810832A (en) * 2016-12-26 2017-06-09 沈阳化工大学 Modified polyethylene terephthalate of isomerism containing condensed cyclic structure crosslinking agent and preparation method thereof
CN115975482A (en) * 2023-02-14 2023-04-18 广东百川化工有限公司 Sanding-free unsaturated polyester wood primer as well as preparation method and use method thereof

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106810832A (en) * 2016-12-26 2017-06-09 沈阳化工大学 Modified polyethylene terephthalate of isomerism containing condensed cyclic structure crosslinking agent and preparation method thereof
CN115975482A (en) * 2023-02-14 2023-04-18 广东百川化工有限公司 Sanding-free unsaturated polyester wood primer as well as preparation method and use method thereof
CN115975482B (en) * 2023-02-14 2023-10-03 广东百川化工有限公司 Polishing-free unsaturated polyester woodenware primer and preparation method and using method thereof

Also Published As

Publication number Publication date
FR1156266A (en) 1958-05-14
DE1035291B (en) 1958-07-31

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