GB770089A - Production of amylose films - Google Patents
Production of amylose filmsInfo
- Publication number
- GB770089A GB770089A GB11580/55A GB1158055A GB770089A GB 770089 A GB770089 A GB 770089A GB 11580/55 A GB11580/55 A GB 11580/55A GB 1158055 A GB1158055 A GB 1158055A GB 770089 A GB770089 A GB 770089A
- Authority
- GB
- United Kingdom
- Prior art keywords
- per cent
- amylose
- temperature
- solution
- film
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23B—PRESERVING, e.g. BY CANNING, MEAT, FISH, EGGS, FRUIT, VEGETABLES, EDIBLE SEEDS; CHEMICAL RIPENING OF FRUIT OR VEGETABLES; THE PRESERVED, RIPENED, OR CANNED PRODUCTS
- A23B4/00—General methods for preserving meat, sausages, fish or fish products
- A23B4/10—Coating with a protective layer; Compositions or apparatus therefor
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23P—SHAPING OR WORKING OF FOODSTUFFS, NOT FULLY COVERED BY A SINGLE OTHER SUBCLASS
- A23P30/00—Shaping or working of foodstuffs characterised by the process or apparatus
- A23P30/10—Moulding
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L3/00—Compositions of starch, amylose or amylopectin or of their derivatives or degradation products
- C08L3/02—Starch; Degradation products thereof, e.g. dextrin
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2303/00—Characterised by the use of starch, amylose or amylopectin or of their derivatives or degradation products
- C08J2303/02—Starch; Degradation products thereof, e.g. dextrin
Abstract
Strong, pliable and transparent amylose films are produced by dissolving at least 5 per cent by weight of a starch carbohydrate, containing at least 50 per cent by weight of amylose, in water at a temperature of at least 120 DEG C. and preferably 140-165 DEG C., cooling the solution to below its boiling point, casting a film from the resulting clear solution on a support having a temperature higher than the gelation temperature of the solution, and afterwards drying and cooling the film on the support and stripping it from the support. The concentration of the amylose solution may be up to about 25 per cent and is preferably 10-20 per cent. The amylose may have an average molecular weight of about 120,000 and is preferably dispersed in water having a pH of about 7, to which up to 0.2 per cent of sodium sulphite may be added. The dispersion may be heated in an autoclave or by passing it through heated tubes for 5-8 minutes, prolonged heating at an unnecessarily high temperature being avoided to minimize degradation of the amylose. The casting temperature is preferably sufficiently high to evaporate part of the water before the solution gels. The drying air may have a temperature of 90-110 DEG C., provided it has a high relative humidity, e.g. between 40 and 80 per cent, at the end of the drying process and during cooling. The amylose should preferably be free from contaminants, e.g. magnesium sulphate introduced during the preparation of the amylose from starch, but should preferably contain 10-20 per cent of amylopectin. A plasticizer such as glycerol or sorbitol may also be present. In the example, an aqueous slurry containing 15 per cent by weight of amylose, 0.05 per cent of sodium sulphite and 5 per cent of glycerol is heated to 160 DEG C. in about 2 minutes and kept at that temperature for about 4 minutes by passing it through heated tubes. The resulting clear solution is cooled to about 95 DEG C., filtered at 95 DEG C., cast on to an endless travelling belt of chromium-plated steel having a temperature of about 85 DEG C. and dried in hot air having a temperature of 100 DEG C. and a relative humidity of about 65 per cent. The film is then cooled while still on the belt in air having a temperature of about 22 DEG C. and a relative humidity of about 100 per cent, and is finally stripped from the belt. The amylose film is suitable for application in the food industries, due to its digestibility.ALSO:Strong, pliable and transparent amylose films are produced by dissolving at least 5 per cent by weight of a starch carbohydrate, containing at least 50 per cent by weight of amylose, in water at a temperature of at least 120 DEG C. and preferably 140 DEG -165 DEG C., cooling the solution to below its boiling point, casting a film from the resulting clear solution on a support having a temperature higher than the gelation temperature of the solution, and afterwards drying and cooling the film on the support and stripping it from the support. The concentration of the amylose solution may be up to about 25 per cent and is preferably 10-20 per cent. The amylose may have an average molecular weight of about 120,000, and is preferably dispersed in water having a pH of about 7, to which up to 0,2 per cent of sodium sulphite may be added. The dispersion may be heated in an autoclave or by passing it through heated tubes for 5-8 minutes, prolonged heating at an unnecessarily high temperature being avoided to minimize degradation of the amylose. The casting temperature is preferably sufficiently high to evaporate part of the water before the solution gels. The drying air may have a temperature of 90 DEG -110 DEG C., provided it has a high relative humidity, e.g. between 40 and 80 per cent, at the end of the drying process and during cooling. The amylose should preferably be free from contaminants, e.g. magnesium sulphate introduced during the preparation of the amylose from starch, but should preferably contain 10-20 per cent of amylopectin. A plasticizer such as glycerol or sorbitol may also be present. In the example, an aqueous slurry containing 15 per cent by weight of amylose, 0,05 of sodium sulphite and 5 per cent of glycerol is heated to 160 DEG C. in about 2 minutes and kept at that temperature for about 4 minutes by passing it through heated tubes. The resulting clear solution is cooled to about 95 DEG C., filtered at 95 DEG C., cast on to an endless travelling belt of chromium-plated steel having a temperature of about 85 DEG C, and dried in hot air having a temperature of 100 DEG C. and a relative humidity of about 65 per cent. The film is then cooled while still on the belt in air having a temperature of about 22 DEG C. and a relative humidity of about 100 per cent, and is finally stripped from the belt. The amylose film is suitable for application in the food industries, due to its digestibility.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
NL770089X | 1954-04-22 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB770089A true GB770089A (en) | 1957-03-13 |
Family
ID=19827873
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB11580/55A Expired GB770089A (en) | 1954-04-22 | 1955-04-21 | Production of amylose films |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB770089A (en) |
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3127393A (en) * | 1964-03-31 | Reaction of amide and triazine substi- | ||
US3130081A (en) * | 1960-12-23 | 1964-04-21 | Nat Starch Chem Corp | Limited stability amylose dispersions and method of preparation |
US3312641A (en) * | 1963-06-19 | 1967-04-04 | Staley Mfg Co A E | Polyvinyl alcohol plasticized amylose compositions |
DE1292838B (en) * | 1958-01-29 | 1969-04-17 | Vaessen Schoemaker Holding Bv | Process for the production of aqueous amylose solutions |
US4490526A (en) * | 1983-05-05 | 1984-12-25 | Dynamit Nobel Ag | Method for the modification of starch in the presence of solvents |
US4985082A (en) * | 1987-11-20 | 1991-01-15 | Lafayette Applied Chemistry, Inc. | Microporous granular starch matrix compositions |
US5445678A (en) * | 1991-05-29 | 1995-08-29 | Whistler; Roy L. | Subgranular crystalline starch as fat substitute |
US5651828A (en) * | 1994-09-30 | 1997-07-29 | Lafayette Applied Chemistry, Inc. | Fat substitute for processed foods |
-
1955
- 1955-04-21 GB GB11580/55A patent/GB770089A/en not_active Expired
Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3127393A (en) * | 1964-03-31 | Reaction of amide and triazine substi- | ||
DE1292838B (en) * | 1958-01-29 | 1969-04-17 | Vaessen Schoemaker Holding Bv | Process for the production of aqueous amylose solutions |
US3130081A (en) * | 1960-12-23 | 1964-04-21 | Nat Starch Chem Corp | Limited stability amylose dispersions and method of preparation |
US3312641A (en) * | 1963-06-19 | 1967-04-04 | Staley Mfg Co A E | Polyvinyl alcohol plasticized amylose compositions |
US4490526A (en) * | 1983-05-05 | 1984-12-25 | Dynamit Nobel Ag | Method for the modification of starch in the presence of solvents |
US4985082A (en) * | 1987-11-20 | 1991-01-15 | Lafayette Applied Chemistry, Inc. | Microporous granular starch matrix compositions |
US5445678A (en) * | 1991-05-29 | 1995-08-29 | Whistler; Roy L. | Subgranular crystalline starch as fat substitute |
US5580390A (en) * | 1991-05-29 | 1996-12-03 | Whistler; Roy L. | Subgranular crystalline starch as fat substitute |
US5651828A (en) * | 1994-09-30 | 1997-07-29 | Lafayette Applied Chemistry, Inc. | Fat substitute for processed foods |
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