GB766813A - Improvements in the bonding of polythene to metals - Google Patents

Improvements in the bonding of polythene to metals

Info

Publication number
GB766813A
GB766813A GB6472/54A GB647254A GB766813A GB 766813 A GB766813 A GB 766813A GB 6472/54 A GB6472/54 A GB 6472/54A GB 647254 A GB647254 A GB 647254A GB 766813 A GB766813 A GB 766813A
Authority
GB
United Kingdom
Prior art keywords
polythene
metal
main body
thin coating
oxidized
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB6472/54A
Inventor
Edward Richard Stanley Jones
Wilson Reddish
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Imperial Chemical Industries Ltd
Original Assignee
Imperial Chemical Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Imperial Chemical Industries Ltd filed Critical Imperial Chemical Industries Ltd
Priority to GB6472/54A priority Critical patent/GB766813A/en
Priority to GB33221/55A priority patent/GB815482A/en
Publication of GB766813A publication Critical patent/GB766813A/en
Expired legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C65/00—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
    • B29C65/02—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C63/00—Lining or sheathing, i.e. applying preformed layers or sheathings of plastics; Apparatus therefor
    • B29C63/48—Preparation of the surfaces
    • B29C63/486—Preparation of the surfaces of metal surfaces
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00—General aspects of processes or apparatus for joining preformed parts
    • B29C66/01—General aspects dealing with the joint area or with the area to be joined
    • B29C66/02—Preparation of the material, in the area to be joined, prior to joining or welding
    • B29C66/024—Thermal pre-treatments
    • B29C66/0242—Heating, or preheating, e.g. drying
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00—General aspects of processes or apparatus for joining preformed parts
    • B29C66/70—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material
    • B29C66/71—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the composition of the plastics material of the parts to be joined
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00—General aspects of processes or apparatus for joining preformed parts
    • B29C66/70—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material
    • B29C66/74—Joining plastics material to non-plastics material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00—Layered products comprising a layer of metal
    • B32B15/04—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B15/08—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D123/00—Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers
    • C09D123/02—Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
    • C09D123/04—Homopolymers or copolymers of ethene
    • C09D123/06—Polyethene
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B17/00—Insulators or insulating bodies characterised by their form
    • H01B17/005—Insulators structurally associated with built-in electrical equipment
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B17/00—Insulators or insulating bodies characterised by their form
    • H01B17/42—Means for obtaining improved distribution of voltage; Protection against arc discharges
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
    • H01B3/002—Inhomogeneous material in general
    • H01B3/004—Inhomogeneous material in general with conductive additives or conductive layers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00—General aspects of processes or apparatus for joining preformed parts
    • B29C66/01—General aspects dealing with the joint area or with the area to be joined
    • B29C66/02—Preparation of the material, in the area to be joined, prior to joining or welding
    • B29C66/022—Mechanical pre-treatments, e.g. reshaping
    • B29C66/0224—Mechanical pre-treatments, e.g. reshaping with removal of material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00—General aspects of processes or apparatus for joining preformed parts
    • B29C66/01—General aspects dealing with the joint area or with the area to be joined
    • B29C66/02—Preparation of the material, in the area to be joined, prior to joining or welding
    • B29C66/026—Chemical pre-treatments
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00—General aspects of processes or apparatus for joining preformed parts
    • B29C66/70—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material
    • B29C66/74—Joining plastics material to non-plastics material
    • B29C66/742—Joining plastics material to non-plastics material to metals or their alloys
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2023/00—Use of polyalkenes or derivatives thereof as moulding material
    • B29K2023/04—Polymers of ethylene
    • B29K2023/06—PE, i.e. polyethylene
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2705/00—Use of metals, their alloys or their compounds, for preformed parts, e.g. for inserts
    • B29K2705/08—Transition metals
    • B29K2705/10—Copper

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Thermal Sciences (AREA)
  • Power Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Laminated Bodies (AREA)
  • Insulating Bodies (AREA)
  • Paints Or Removers (AREA)

Abstract

Polythene is united to a metal surface by forming a thin coating of polythene on the metal surface, oxidizing it by baking above its melting point, and then bonding the main body of the polythene, by heat, to the thin coating of oxidized polythene. Several thin layers of polythene, oxidized to successively decreasing extents, may be used. The thin coating of polythene may contain an oxidation catalyst, e.g. ditertiary butyl peroxide, tertiary butyl hydroperoxide, and certain metal salts, e.g. ferric linoleate, cobalt naphthenate, zinc chloride or other zinc salts, or it may be formed from polythene which has previously been partially oxidized. It is preferably applied as a solution from which the solvent is then evaporated, but may also be applied by dipping in a polythene dispersion and evaporating the liquid at a temperature above the melting point of polythene, by dipping in molten polythene, by coating with polythene powder which is then fused by flamespraying or by covering the surface with a self-supporting film of polythene which is subsequently melted. The main body of polythene may be applied by extrusion, e.g. in wire covering; by compression, injection or extrusion moulding, by calendering, by casting or by any other method in which the main body of polythene is in the softened or molten state. The invention may be applied to electric cables, insulators, bushings and glands, e.g. for submarine cables, for the production of electrical components in which metal inserts are normally secured to a moulded insulant by mechanical means, e.g. electrical plugs and sockets, and for non-electrical uses such as the union of polythene and metal pipes, the attachment of handles to domestic articles or the replacement of rubber by polythene bushes. Metals and other materials to be bonded to polythene may first be plated with copper, to which polythene adheres strongly when applied by the method of the invention. The invention may be used to bond sheets of polythene to metal foil. Electrical condensers may be made by applying a thin coating of polythene to each side of metal foil, baking the foil to oxidize the polythene, assembling several layers of the foil with intervening layers of polythene film, and bonding the assembly by heat.ALSO:Polythene is united to a metal surface by forming a thin coating of polythene on the metal surface, oxidizing it by baking above its melting point, and then bending the main body of the polythene, by heat, to the thin coating of oxidized polythene. Several thin layers of polythene, oxidized to successively decreasing extents, may be used. The thin coating of polythene may contain an oxidation catalyst, e.g. ditertiary butyl peroxide, tertiary butyl hydroperoxide, and certain metal salts, e.g. ferric linoleate, cobalt naphthenate, zinc chloride or other zinc salts, or it may be formed from polythene which has previously been partially oxidized. It is preferably applied as a solution from which the solvent is then evaporated, but may also be applied by dipping in a polythene dispersion and evaporating the liquid at a temperature above the melting point of polythene, by dipping in molten polythene, by coating with polythene powder which is then fused by flame-spraying or by covering the surface with a self-supporting film of polythene which is subsequently melted. The main body of polythene may be applied by extrusion, e.g. in wire covering, by compression, injection or extrusion moulding, by calendering, by casting or by any other method in which the main body of polythene is in the softened or molten state. The invention may be applied to electric cables, insulators, bushings and glands, e.g. for submarine cables, for the production of electrical components in which metal inserts are normally secured to a moulded insulant by mechanical means, e.g. electrical plugs and sockets, and for non-electrical uses such as the union of polythene and metal pipes, the attachment of handles to domestic articles or the replacement of rubber by polythene bushes. Metals and other materials to be bonded to polythene may first be plated with copper, to which polythene adheres strongly when applied by the method of the invention.
GB6472/54A 1954-03-05 1954-03-05 Improvements in the bonding of polythene to metals Expired GB766813A (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
GB6472/54A GB766813A (en) 1954-03-05 1954-03-05 Improvements in the bonding of polythene to metals
GB33221/55A GB815482A (en) 1954-03-05 1955-11-21 Improvements in the production of articles and structures

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB6472/54A GB766813A (en) 1954-03-05 1954-03-05 Improvements in the bonding of polythene to metals

Publications (1)

Publication Number Publication Date
GB766813A true GB766813A (en) 1957-01-23

Family

ID=9815098

Family Applications (2)

Application Number Title Priority Date Filing Date
GB6472/54A Expired GB766813A (en) 1954-03-05 1954-03-05 Improvements in the bonding of polythene to metals
GB33221/55A Expired GB815482A (en) 1954-03-05 1955-11-21 Improvements in the production of articles and structures

Family Applications After (1)

Application Number Title Priority Date Filing Date
GB33221/55A Expired GB815482A (en) 1954-03-05 1955-11-21 Improvements in the production of articles and structures

Country Status (1)

Country Link
GB (2) GB766813A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2216166A (en) * 1988-02-18 1989-10-04 Central Glass Co Ltd Method of fitting plate member with supportive or protective member of molded resin.

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2728909A1 (en) * 1994-12-29 1996-07-05 Atochem Elf Sa Prodn. of polyolefin coating on substrate
DE69515279T2 (en) * 1994-12-29 2000-09-21 Atochem Elf Sa Process for the production of polyolefin coatings, substrates coated therewith, and use in contact with agitated powders

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2216166A (en) * 1988-02-18 1989-10-04 Central Glass Co Ltd Method of fitting plate member with supportive or protective member of molded resin.
GB2216166B (en) * 1988-02-18 1992-02-19 Central Glass Co Ltd Method of fitting plate member with supportive or protective member of moulded resin

Also Published As

Publication number Publication date
GB815482A (en) 1959-06-24

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