GB758156A - Fluorocarbon compounds - Google Patents

Fluorocarbon compounds

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Publication number
GB758156A
GB758156A GB20842/54A GB2084254A GB758156A GB 758156 A GB758156 A GB 758156A GB 20842/54 A GB20842/54 A GB 20842/54A GB 2084254 A GB2084254 A GB 2084254A GB 758156 A GB758156 A GB 758156A
Authority
GB
United Kingdom
Prior art keywords
conversion
hydroxide
products
reduction
referred
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB20842/54A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
3M Co
Original Assignee
Minnesota Mining and Manufacturing Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Minnesota Mining and Manufacturing Co filed Critical Minnesota Mining and Manufacturing Co
Publication of GB758156A publication Critical patent/GB758156A/en
Expired legal-status Critical Current

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  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

The invention comprises 1 : 1-dihydroperfluoroalkyl - trialkyl ammonium halide or hydroxide having the formula <FORM:0758156/IV(a)/1> the alkyl groups having 1-5 C atoms, the same or different, n being 3-9 and X, halogen or hydroxyl. The products may be prepared by conversion of a fluorocarbon acid chloride to disubstituted amide, reduction to tertiaryamine, conversion of this to quaternary salt by addition, and conversion to hydroxide, if desired, with silver oxide. An example is given of the preparation of N : N-diethylperfluorobutyramide from the corresponding acid chloride, its reduction with LiAlH4, to the tertiary N : N - diethyl - (1 : 1 - dihydroperfluorobutylamine, and the conversion of this to quaternary salt with methyl iodide, and to hydroxide therefrom. The trifluoroacetate salt is referred to. The products are surface-active, being oleophobic and hydrophobic. Specification 686,678 is referred to.
GB20842/54A 1953-07-17 1954-07-16 Fluorocarbon compounds Expired GB758156A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US758156XA 1953-07-17 1953-07-17

Publications (1)

Publication Number Publication Date
GB758156A true GB758156A (en) 1956-10-03

Family

ID=22128157

Family Applications (1)

Application Number Title Priority Date Filing Date
GB20842/54A Expired GB758156A (en) 1953-07-17 1954-07-16 Fluorocarbon compounds

Country Status (1)

Country Link
GB (1) GB758156A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3194840A (en) * 1961-12-18 1965-07-13 Procter & Gamble N, n-diloweralkyl, 1, 1-dihydrogen perfluoroalkyl amine oxides
US3952060A (en) 1973-11-22 1976-04-20 Ciba-Geigy Ag Perfluorinated amino compounds and process for their manufacture
US4126633A (en) * 1973-09-12 1978-11-21 Pennwalt Corporation Fluorinated aliphatic sulfides
EP0149172A1 (en) * 1983-12-29 1985-07-24 Hoechst Aktiengesellschaft Fluorinated quaternary ammonium compounds, processes for their preparation and their use as drag reducing agents

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3194840A (en) * 1961-12-18 1965-07-13 Procter & Gamble N, n-diloweralkyl, 1, 1-dihydrogen perfluoroalkyl amine oxides
US4126633A (en) * 1973-09-12 1978-11-21 Pennwalt Corporation Fluorinated aliphatic sulfides
US3952060A (en) 1973-11-22 1976-04-20 Ciba-Geigy Ag Perfluorinated amino compounds and process for their manufacture
EP0149172A1 (en) * 1983-12-29 1985-07-24 Hoechst Aktiengesellschaft Fluorinated quaternary ammonium compounds, processes for their preparation and their use as drag reducing agents

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