GB751750A - Process of producing acrylic acid and its esters and nitrile - Google Patents
Process of producing acrylic acid and its esters and nitrileInfo
- Publication number
- GB751750A GB751750A GB30801/53A GB3080153A GB751750A GB 751750 A GB751750 A GB 751750A GB 30801/53 A GB30801/53 A GB 30801/53A GB 3080153 A GB3080153 A GB 3080153A GB 751750 A GB751750 A GB 751750A
- Authority
- GB
- United Kingdom
- Prior art keywords
- lactate
- acrylic acid
- lactic acid
- graphite
- esters
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/347—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups
- C07C51/377—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups by splitting-off hydrogen or functional groups; by hydrogenolysis of functional groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/30—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group
- C07C67/317—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by splitting-off hydrogen or functional groups; by hydrogenolysis of functional groups
- C07C67/327—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by splitting-off hydrogen or functional groups; by hydrogenolysis of functional groups by elimination of functional groups containing oxygen only in singly bound form
Abstract
Acrylic acid, its nitrile and esters are produced by bringing lactic acid, ammonium lactate or a lactic acid ester respectively into contact at an elevated temperature, with a dehydration catalyst containing at least one phosphate or sulphate of an alkali metal or alkaline earth metal or of zinc. The preferred temperatures are in the range 200 DEG to 600 DEG C. In the examples: (a) methyl acrylate is prepared from methyl lactate; (b) ethyl acrylate from ethyl lactate; (c) butyl acrylate from butyl lactate; (d) acrylic acid from lactic acid, and (e) acrylonitrile from ammonium lactate using catalysts of the type described above.ALSO:Dehydration catalysts for the production of acrylic acid, acrylic acid esters and acrylonitrile from lactic acid, lactic acid esters and ammonium lactate respectively, contain at least one phosphate or sulphate of an alkali metal or alkaline earth metal or of zinc. In the examples methyl lactate is dehydrated to methyl acrylate using as catalyst (a) CaHPO4 and (NH4)2 PO4 on graphite; (b) MgSO4 and Na2HPO4 on graphite; (c) NaH2PO4H2O and Na2HPO4 on graphite; (d) NaH2PO4H2O and H3PO4\t on graphite and (e) NaH2PO4H2O, Na2WO4 and H3PO4 on carbon pellets.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US751750XA | 1952-11-06 | 1952-11-06 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB751750A true GB751750A (en) | 1956-07-04 |
Family
ID=22124040
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB30801/53A Expired GB751750A (en) | 1952-11-06 | 1953-11-06 | Process of producing acrylic acid and its esters and nitrile |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB751750A (en) |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1118193B (en) * | 1957-09-17 | 1961-11-30 | Knapsack Ag | Process for the production of methacrylic acid esters by catalytic elimination of water from ª ‡ -oxyisobutyric acid esters |
DE1211153B (en) * | 1957-10-29 | 1966-02-24 | Escambia Chem Corp | Process for the preparation of methacrylic acid and / or their esters by reacting the steams of alpha-oxyisobutyric acid or their esters |
WO2005095320A1 (en) * | 2004-04-02 | 2005-10-13 | Ciba Specialty Chemicals Water Treatments Limited | Preparation of acrylic acid derivatives from alpha or beta-hydroxy carboxylic acids |
CN100584822C (en) * | 2004-04-02 | 2010-01-27 | 西巴特殊化学水处理有限公司 | Preparation of acrylic acid derivatives from alpha or beta-hydroxy carboxylic acids |
CN102775294A (en) * | 2012-08-06 | 2012-11-14 | 西华师范大学 | Method for preparing acrylic acid through lactic acid dehydration by use of phosphate-pyrophosphate composite catalyst of alkaline-earth metal |
US9029596B2 (en) | 2010-12-28 | 2015-05-12 | Nippon Shokubai Co., Ltd. | Methods for producing acrylic acid and/or ester thereof and polymer of the acrylic acid and/or ester thereof |
-
1953
- 1953-11-06 GB GB30801/53A patent/GB751750A/en not_active Expired
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1118193B (en) * | 1957-09-17 | 1961-11-30 | Knapsack Ag | Process for the production of methacrylic acid esters by catalytic elimination of water from ª ‡ -oxyisobutyric acid esters |
DE1211153B (en) * | 1957-10-29 | 1966-02-24 | Escambia Chem Corp | Process for the preparation of methacrylic acid and / or their esters by reacting the steams of alpha-oxyisobutyric acid or their esters |
WO2005095320A1 (en) * | 2004-04-02 | 2005-10-13 | Ciba Specialty Chemicals Water Treatments Limited | Preparation of acrylic acid derivatives from alpha or beta-hydroxy carboxylic acids |
US7538247B2 (en) | 2004-04-02 | 2009-05-26 | Ciba Specialty Chemicals Corporation | Preparation of acrylic acid derivatives from α- or β-hydroxy carboxylic acids |
CN100584822C (en) * | 2004-04-02 | 2010-01-27 | 西巴特殊化学水处理有限公司 | Preparation of acrylic acid derivatives from alpha or beta-hydroxy carboxylic acids |
US9029596B2 (en) | 2010-12-28 | 2015-05-12 | Nippon Shokubai Co., Ltd. | Methods for producing acrylic acid and/or ester thereof and polymer of the acrylic acid and/or ester thereof |
CN102775294A (en) * | 2012-08-06 | 2012-11-14 | 西华师范大学 | Method for preparing acrylic acid through lactic acid dehydration by use of phosphate-pyrophosphate composite catalyst of alkaline-earth metal |
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