GB744534A - Improved lubricating oil additive compositions - Google Patents
Improved lubricating oil additive compositionsInfo
- Publication number
- GB744534A GB744534A GB620/53A GB62053A GB744534A GB 744534 A GB744534 A GB 744534A GB 620/53 A GB620/53 A GB 620/53A GB 62053 A GB62053 A GB 62053A GB 744534 A GB744534 A GB 744534A
- Authority
- GB
- United Kingdom
- Prior art keywords
- alkyl
- sulphide
- sulphides
- sulphonates
- phenol
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M159/00—Lubricating compositions characterised by the additive being of unknown or incompletely defined constitution
- C10M159/12—Reaction products
- C10M159/20—Reaction mixtures having an excess of neutralising base, e.g. so-called overbasic or highly basic products
- C10M159/24—Reaction mixtures having an excess of neutralising base, e.g. so-called overbasic or highly basic products containing sulfonic radicals
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/40—Fatty vegetable or animal oils
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/40—Fatty vegetable or animal oils
- C10M2207/404—Fatty vegetable or animal oils obtained from genetically modified species
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
- C10M2219/044—Sulfonic acids, Derivatives thereof, e.g. neutral salts
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
- C10M2219/046—Overbasedsulfonic acid salts
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/08—Thiols; Sulfides; Polysulfides; Mercaptals
- C10M2219/082—Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms
- C10M2219/086—Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms containing sulfur atoms bound to carbon atoms of six-membered aromatic rings
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/08—Thiols; Sulfides; Polysulfides; Mercaptals
- C10M2219/082—Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms
- C10M2219/087—Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Derivatives thereof, e.g. sulfurised phenols
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/08—Thiols; Sulfides; Polysulfides; Mercaptals
- C10M2219/082—Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms
- C10M2219/087—Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Derivatives thereof, e.g. sulfurised phenols
- C10M2219/089—Overbased salts
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2010/00—Metal present as such or in compounds
- C10N2010/02—Groups 1 or 11
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2010/00—Metal present as such or in compounds
- C10N2010/04—Groups 2 or 12
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2010/00—Metal present as such or in compounds
- C10N2010/06—Groups 3 or 13
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2010/00—Metal present as such or in compounds
- C10N2010/08—Groups 4 or 14
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2010/00—Metal present as such or in compounds
- C10N2010/14—Group 7
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2010/00—Metal present as such or in compounds
- C10N2010/16—Groups 8, 9, or 10
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Lubricants (AREA)
Abstract
Lubricating oil additive compositions are obtained by forming a mixture of an oil-soluble metal aromatic hydrocarbon sulphonate and an alkyl phenol sulphide or alkyl thiophenol sulphide, and contacting this mixture with at least one basic metal neutralizing agent in an amount in excess of that required to neutralize the alkyl phenol sulphide or alkyl thiophenol sulphide to impart substantial alkalinity to the mixture. The alkyl phenol sulphide may have the formula: <FORM:0744534/IV(a)/1> where R is at least one alkyl group, x is an integer from 1 to 4, and y is an integer from 1 to 6, and the alkyl phenol sulphide or alkyl thiophenol sulphide may have the formula: <FORM:0744534/IV(a)/2> where R and x are as above (R preferably being alkyl of 4-24 carbon atoms), and x is oxygen or sulphur. The nuclei in the above formul may be substituted, e.g. by alkyl, cycloalkyl, aralkyl, aryl, carboxyl, hydroxyl, alkoxy, aryloxy, sulphhydryl, nitro, ester, keto, amino, aldehydo, chlormethyl, aminomethyl, alkyl thiomethyl, alkyl xanthomethyl, metal substituted carboxyl, sulpho, hydroxyl, or mercapto, and halogen. Alkyl phenol sulphides listed include alkyl naphthol sulphides and sulphides having an acyclic radical on one side of the sulphur atom. The hydrocarbon sulphonates may be obtained by sulphonating alkyl benzenes, alkyl naphthalenes, alkyl anthracenes, or alkyl picenes, or by sulphonating lubricating oil base stocks to produce mahogany acids. Mono- or polyvalent metal sulphonates may be prepared, e.g. sulphonates of the alkaline earths. Neutralizing agents specified are oxides, hydroxides, carbides, or alkoxides of calcium, barium, magnesium, nickel, cobalt, tin, lead, zinc, copper, cadmium, manganese, iron, aluminium, sodium, potassium, or lithium. Neutralization may be carried out at 60-220 DEG C. The additive composition may be used with hydrocarbon lubricants, or with polyether or polyester type lubricants, or those produced by polymerization of olefines or hydrogenation of animal, vegetable, or fish oils. Examples describe blends of calcium petroleum sulphonates and calcium or barium tert-octyl phenol sulphides.ALSO:Lubricating oil additive compositions are obtained by forming a mixture of an oil-soluble metal aromatic hydrocarbon sulphonate and an alkyl phenol sulphide or alkyl thiophenol sulphide, and contacting this mixture with at least one basic metal neutralizing agent in an amount in excess of that required to neutralize the alkyl phenol sulphide or alkyl thiophenol sulphide to impart substantial alkalinity to the mixture. The alkyl phenol sulphide may have the formula:- <FORM:0744534/III/1> where R is at least one alkyl group, x is an integer from 1 to 4, and Y is an integer from 1 to 6, and the alkyl phenol sulphide or alkyl thiophenol sulphide may have the formula:- <FORM:0744534/III/2> where R and x are as above (preferably R is alkyl of 4-24 carbon atoms), and x is oxygen or sulphur. The nuclei in the above formulae may be substituted, e.g. by alkyl, cycloalkyl, aralkyl, aryl, carboxyl, hydroxyl, alkoxy, aryloxy, sulphhydryl, nitro, ester, keto, amino, aldehyde, chlormethyl, aminomethyl, alkyl thiomethyl, alkyl xanthomethyl, metal substituted carboxyl, sulpho, hydroxyl, or mercapto and halogen. Alkyl phenol sulphides listed include alkyl naphthol sulphides and sulphides having an acyclic radical on one side of the sulphur atom. The hydrocarbon sulphonates may be obtained by sulphonating alkyl benzenes, alkyl naphthalenes, alkyl anthracenes or alkyl picenes, or by sulphonating lubricating oil base stocks to produce mahogany acids. Mono- or polyvalent metal sulphonates may be prepared, e.g. sulphonates of the alkaline earths. Neutralizing agents specified are oxides, hydroxides, carbides, or alkoxides of calcium, barium, magnesium, nickel, cobalt, tin, lead, zinc, copper, cadmium, manganese, iron, aluminium, sodium, potassium, or lithium. Neutralization may be carried out at 60-220 DEG C. The additive compositions may be used with hydrocarbon lubricants, or with polyether or polyester type lubricants, or those produced by polymerization of olefines or hydrogenation of animal, vegetable, or fish oils. Examples describe blends of calcium petroleum sulphonates and calcium or barium tert-octyl phenol sulphides.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US744534XA | 1952-02-01 | 1952-02-01 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB744534A true GB744534A (en) | 1956-02-08 |
Family
ID=22119637
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB620/53A Expired GB744534A (en) | 1952-02-01 | 1953-01-08 | Improved lubricating oil additive compositions |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB744534A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1278053B (en) * | 1962-05-15 | 1968-09-19 | California Research Corp | Process for the preparation of basic alkaline earth alkylthiophenolates |
DE2436564A1 (en) * | 1973-09-07 | 1975-04-24 | Exxon Research Engineering Co | LUBRICATING OIL CONDITIONS |
-
1953
- 1953-01-08 GB GB620/53A patent/GB744534A/en not_active Expired
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1278053B (en) * | 1962-05-15 | 1968-09-19 | California Research Corp | Process for the preparation of basic alkaline earth alkylthiophenolates |
DE2436564A1 (en) * | 1973-09-07 | 1975-04-24 | Exxon Research Engineering Co | LUBRICATING OIL CONDITIONS |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US2501731A (en) | Modified lubricating oil | |
US3178368A (en) | Process for basic sulfurized metal phenates | |
US2418894A (en) | Compounded lubricating oil | |
GB594960A (en) | Compounded lubricating oil | |
US3755176A (en) | Sulfur-containing carboxylic acids as corrosion inhibitors | |
GB1469289A (en) | Detergent additives | |
GB718714A (en) | Lubricating oil compositions | |
GB1044810A (en) | Organic phosphinodithioate-amine reaction products | |
US2362624A (en) | Lubricant | |
US3480550A (en) | Lubricant containing mixture of low and high molecular weight sulfonates | |
GB1599288A (en) | Sulphurized olefins and their use as lubricant additives | |
GB748137A (en) | Improvements in or relating to lubricating oil compositions | |
GB744534A (en) | Improved lubricating oil additive compositions | |
GB774084A (en) | Amate-dicarboxylate-thickened grease | |
GB642410A (en) | Lubricating grease composition | |
US2483505A (en) | Compounded lubricating oil | |
GB561801A (en) | Improvements in lubricating compositions | |
US2358305A (en) | Lubricating composition | |
US2567023A (en) | Process of preparing a polyvalent metal soap | |
US2350959A (en) | Lubricating oil and additive therefor | |
GB776455A (en) | Additive compositions for lubricating oils and lubricating compositions containing them | |
US2465902A (en) | Stabilized liquid petroleum hydrocarbon | |
US3591496A (en) | Overbased additives | |
GB723133A (en) | Oxidation-inhibited, silver non-corrosive lubricants | |
GB713423A (en) | Improvements in or relating to lubricating compositions |